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Lime Slaking Technology

Number of journal: 12-2019
Autors:

Nesterov A.V.
Oskorbin  A.A.

DOI: https://doi.org/10.31659/0585-430X-2019-777-12-8-12
УДК: 666.324.3

 

AbstractAbout AuthorsReferences
The technological aspects of lime extinguishing in bladed two and three-section devices are considered. The main characteristics of the devices for extinguishing lime are given - performance, water consumption, electricity, quantity and composition of waste gases. Presented the scheme and characteristics of the mobile hydrator, the performance of 1 t/hour. Options for extinguishing ground and crushed lime are presented. It is shown that when the crushed lime is extinguished of low quality, it is possible to improve the quality of hydrateed lime by removing unextinguished grains on the rumble, whiz or air classifier. A comparative analysis of the various lime extinguishing schemes was carried out: extinguishing of ground lime, extinguishing crushed lime with a rumble and a mill, extinguishing crushed lime with an air classifier. Thus, when lime is extinguished in the blade, it is possible to obtain hydrated lime of the 1st and 2nd grade from both ground and crushed burnt lime. With crushed lime, it is possible to improve the quality of hydrateed lime, but the extinguishing scheme is complicated and formed up to 20% of solid waste.
A.V. NESTEROV , Candidate of Sciences (Engineering), General Director (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.A. OSKORBIN, Technical Director

OOO “KIANIT” (1, Yuriya Gagarina Avenue, Saint Petersburg, 196105, Russian Federation)

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For citation: Nesterov A.V., Oskorbin  A.A. Lime slaking technology. Stroitel’nye Materialy [Construction Materials]. 2019. No. 12, pp. 8–12. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-777-12-8-12

Features of the Calculation of Free Energy of the Surface Based on the Model for Interfacial Interaction of Owens–Wendt–Rabel–Kaelble

Number of journal: 11-2019
Autors:

Danilov V.E.
Korolev E.V.
Ayzenshtadt A.M.
Strokova V.V.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-66-72
УДК: 519.711.3

 

AbstractAbout AuthorsReferences
In building materials science to obtain a general model of the developed material, methods of mathematical planning of the experiment are often used. The key objective here is to reduce the alternatives, that is, the reasonable choice of material components. For composite materials, as complex technical systems, the manifestation of the integrative property, providing non-additive effect of the properties of the components on the properties of the composite due to the structure formation at the interface, is characteristics. In this regard, it is rational to use the data on the surface tension of the material (the free energy of the surface of the material area unit ) as an integral criterion of compatibility of components. This specified informational parameter is determined by a non-destructive way, for example, is calculated by the model of the interfacial interaction of the Owens–Wendt–Rabel–Kaelble on the basis of experimentally determined static contact angles of wetting of the test material surface with working liquids. However, currently the scientific community raises questions about the eligibility of these angles for calculation in connection with the ambiguous interpretation of the equilibrium state of the system formed by powdery materials. Therefore, the aim of this work is the demonstration of how the duration of the establishment of mechanical equilibrium in the system of the working fluid – the surface of the solid body studied and the choice of method of measurement can affect the value of the static contact angle of wetting, calculated on the basis of their surface tension. Recommendations for the preparation of press-samples from fine powders and time periods of measurement of the edge angles by working liquids of high and low viscosity are proposed. A proof of the competence of the use of static contact angles for the selected working fluids (decane, ethylene glycol, glycerin, water), subject to the recommendations on the time periods of measurement to be determined in preliminary experiments with the use of the analyzed surface of the test samples has been got.
V.E. DANILOV1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
E.V. KOROLEV2, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.M. AYZENSHTADT1, Doctor of Sciences (Chemistry), (This email address is being protected from spambots. You need JavaScript enabled to view it.)
V.V. STROKOVA3, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 Northern (Arctic) Federal University named after M.V. Lomonosov (17, Severnaya Dvina Embankment, Arkhangelsk, 163002, Russian Federation)
2 National Recearch Moscow State University of Civil Engineering (26, Yaroslavskoye Highway, Moscow, 129337, Russian Federation)
3 Belgorod State Technological University named after V.G. Shoukhov (46, Kostyukova Street, Belgorod, 308012, Russian Federation)

1. Bazhenov Yu.M., Gar’kina I.A., Danilov A.M., Korolev E.V. Sistemnyi analiz v stroitel’nom materialovedenii [System analysis in building materials science]. Moscow: MGSU. 2012. 432 p.
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3. Korolev E.V., Bazhenov Yu.M., Al’bakasov A.I. Radiatsionno-zashchitnye i khimicheski stoikie sernye stroitel’nye materialy [Radiation-protective and chemical-resistant sulfur construction materials]. Penza, Orenburg: IPK OGU. 2010. 364 p.
4. Chernyshov E.M. Modern building materials science: the evolution of methodologies and the fundamental nature of scientific knowledge. Materials of the international scientific-practical conference-seminar. Volgo-grad: VGASU. 2004, pp. 20–25. (In Russian).
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6. Kharitonov A.M. Development of methods for optimizing the composition of multicomponent building composites. Fundamental’nye issledovaniya. 2015. No. 11–3, pp. 520–523. (In Russian).
7. Danilov V.E., Aizenshtadt A.M., Frolova M.A., Tutygin A.S. Change in surface energy – a criterion for optimizing the composition of a cementless composite binder. Materialovedenie. 2018. No. 2, pp. 39–44. (In Russian).
8. Korolev E.V., Grishina A.N., Pustovgar A.P. Surface tension in structure formation of materials. Significance, calculation, and application. Stroitel’nye Materialy [Construction materials]. 2017. No. 1–2, pp. 104–108. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2017-745-1-2-104-108.
9. Danilov V.E., Strokova V.V., Aizenshtadt A.M. The role of dispersion and polarization effects in the formation of a wood-mineral composite based on finely dispersed components. Fizika i khimiya obrabotki materialov. 2018. No. 4, pp. 50–56. (In Russian).
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For citation: Danilov V.E., Korolev E.V., Ayzenshtadt A.M., Strokova V.V. Features of the calculation of free energy of the surface based on the model for interfacial interaction of Owens–Wendt–Rabel–Kaelble. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 66–72. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-66-72

Possibilities for predicting the coefficient of thermal expansion of materials based on polyvinyl chloride

Number of journal: 11-2019
Autors:

Askadskii A.A.
Wang C.
Kurskaya E.A.
Kondrashchenko V.I.
Zhdanova T.V.
Matseevich T.A.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-57-65
УДК: 678.743.22

 

AbstractAbout AuthorsReferences
The analysis of the prediction of the coefficient of thermal expansion of materials based on polyvinyl chloride is carried out. The relevance of such a prediction is due to the fact that polyvinyl chloride is one of the main polymers used to develop building materials based on polymers. The problem of reducing the coefficient of thermal expansion of polyvinyl chloride by creating blends with heat-resistant polymers with high glass transition temperatures is considered. Among these polymers are polyimides, polyesters, polyether ketones, polysulfides, polyphenylene oxides. The prediction is made using the compatibility criterion developed at the INEOS RAS. The criterion contains such characteristics as the Hildebrand solubility parameter, surface energy, and molar volume of the repeating unit of polymer. Based on this criterion, a decrease in the coefficient of thermal expansion of 52% is shown. The introduction of a mineral filler in the form of calcite in the composition of the mixtures also contributes to a decrease in the CLTE. Experiments and calculations were carried out for wood-polymer composites produced by the domestic company. The value of CLTE when filling with bamboo wood is realized decreases to a greater extent than when filling with coniferous wood.
A.A. ASKADSKII1, 2, Doctor of Sciences (Chemistry) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
C. WANG3, Graduate Student (This email address is being protected from spambots. You need JavaScript enabled to view it.)
E.A. KURSKAYA1, Candidate of Sciences (Chemistry) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
V.I. KONDRASHCHENKO3, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
T.V. ZHDANOVA2, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
T.A. MATSEEVICH2, Doctor of Sciences (Physics and Mathematics) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS) (28, Vavilova Street, Moscow, 119991, Russian Federation)
2 National Research Moscow State University of Civil Engineering (26, Yaroslavskoe Highway, Moscow, 129337, Russian Federation)
3 Russian University of Transport (9, Build. 9, Obraztsova Street, 127994, Moscow, Russian Federation)

1. Moroz P.A., Askadskii Al.A., Matseyevich T.A., Solov’yeva Ye.V., Askadskii A.A. The use of secondary polymers for the production of wood-polymer composites. Plasticheskie massy. 2017. No. 9–10, pp. 56–61. (In Russian).
2. Matseevich T.A., Askadsky A.A. Mechanical properties of terrace boards based on polyethylene, polypropylene and polyvinyl chloride. Stroitel’stvo: nauka i obrazovanie. 2017. Vol. 7. Iss. 3 (24), pp. 48–59. (In Russian).
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5. Klesov A.A. Drevesno-polimernye kompozity / per. s angl. A. Chmelya. [Wood-polymer composites / Translate from English A. Chmelya]. Saint-Petrsburg: Scientific foundations and technologies. 2010. 736 p.
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9. Nizamov R.K. Polyvinyl chloride compositions for construction purposes with multifunctional fillers. Doct. Diss. (Engineering). Kazan. 2007. 369 p. (In Russian).
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13. Askadskii A.A., Matseevich T.A., Popova M.N. Vtorichnye polimernye materialy. Mekhanicheskie i bar’ernye svoistva, plastifikatsiya, smesi i nanokompozity. [Secondary polymeric materials. Mechanical and barrier properties, plasticization, mixtures and nanocomposites]. Moscow: ASV. 2017. 490 p.
14. Askadskii A.A. Computational Materials Science of Polymers. Cambridge: Cambridge International Science Publishing. 2003. 695 p.
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17. Bolobova A.V., Askadskii A.A., Kondrashchenko V.I., Rabinovich M.L. Teoreticheskie osnovy biotekhnologii drevesnykh kompozitov. Kniga II. Fermenty, modeli, protsessy. [Theoretical foundations of biotechnology of wood composites. Book II. Enzymes, models, processes]. Moscow: Nauka. 2002. 343 p.
18. Azeez M.A., Orege J.I. Bamboo, its chemical modification and products. Bamboo: Current and Future Prospects. 2018. pp. 25–48. DOI: 10.5772/intechopen.76359

For citation: Askadskii A.A., Wang C., Kurskaya E.A., Kondrashchenko V.I., Zhdanova T.V., Matseevich T.A. Possibilities for predicting the coefficient of thermal expansion of materials based on polyvinyl chloride.. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 57–65. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-57-65

Development of Self-Compacting, Self-Stressing Concrete for Pipe-Concrete Columns

Number of journal: 11-2019
Autors:

Troshkina E.A.
Khamidulina D.D.
Nekrasova S.A.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-50-54
УДК: 624.042

 

AbstractAbout AuthorsReferences
Due to the significant advantages of the structural, technological and economic nature of the pipe-concrete columns (PCC) have good prospects for wide application in the practice of construction. Pipe-concrete columns have high strength and rigidity with relatively small cross-sectional dimensions, economical, reliable in operation. However, their wide practical application constrains the difficulty of ensuring sufficient adhesion between the concrete core and the steel shell in places of transfer of loads to the column from the floors. The authors propose a method of improving the design of pipe-concrete column by use of self-compacting self-stressing concrete for concrete core, making it possible to increase the strength of contact between the concrete core and steel shell and to provide high-quality concreting of columns.
E.A. TROSHKINA, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
D.D. KHAMIDULINA, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
S.A. NEKRASOVA, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

Nosov Magnitogorsk State Technical University (38, Lenin Avenue, Magnitogorsk, 455000, Russian Federation)

1. Garanzha I.M., Shchukina L.S. Self-compacting concrete as the basis of metal composite structures. Integration, partnership and innovation in construction science and education. Collection of international scientific conference proceedings. Moscow State University of Civil Engineering. 2017, pp. 244–251. (In Russian).
2. Penkina E.V., Plotnikov A.I. To the question of the use of concrete filled steel tube columns in multistoried and high-rise buildings. Scientific progress – creativity of young people. International Youth Scientific Conference on Natural Sciences and Technical Disciplines: proceedings and reports: in 3 parts. Yoshkar-Ola. Volga State Technological University. 2013, pp. 121–123. (In Russian).
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5. Krishan A.L., Krishan M.A., Sabirov R.R. Prospects for the use of concrete filled steel tube columns at construction sites in Russia. Bulletin of the Nosov Magnitogorsk State Technical University. 2014. No. 1 (45), pp. 137–140. (In Russian).
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8. Michel J. Gebman, Scott A. Ashford, Jose I. Restrepo. Axial force transfer mechanisms within cast-in-steel-shell piles. Final report submitted to the california department of transportation under contract No. 59A0337. Department of structural engineering university of California. San Diego La Jolla, California, 2006. 331 p.
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14. Khamidulina D.D., Nekrasova S.A. Fractals in the construction material science. IOP Conference Series: Materials Science and Engineering electronic edition. 2018. Р. 012026. DOI: 10.1088/1757-899X/451/1/012026

For citation: Troshkina E.A., Khamidulina D.D., Nekrasova S.A. Development of self-compacting, self-stressing concrete for pipe-concrete columns. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 50–54. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-50-54

The Use of Weak Bases When Constructing Main Roads

Number of journal: 11-2019
Autors:

Sokolov N.S.
Pavlov F.L.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-45-49
УДК: 625.74

 

AbstractAbout AuthorsReferences
The article is devoted to the problem of development of new economically unattractive territories for road construction. Often such areas have features in the form of weak bases that begin to build up. Ensuring the reliability and durability of the foundations of embankments of urban trunk roads is an important geotechnical task. To ensure the uninterrupted movement of urban transport, the issues of increasing their carrying capacity and stability are relevant. For this purpose it is possible to apply modern methods of reinforcement of a soil embankment, strengthening of the basis by a pile field of reinforced concrete piles, crushed stone piles. Each of the methods increases either stability or load-bearing capacity, so it is more expedient on the basis of technical and economic analysis to apply combined methods that give a win on several positions at once. On the basis of the research conducted, the conclusion is made about the rationality of a combination of gravel piles with reinforced embankment, whereby it is possible to use less robust geotextiles or increase the spacing of the reinforcement. This method is the most economical. Another combined option is the use of reinforced embankment together with concrete piles. This option is less attractive because of the high cost of the pile field arrangement.
N.S. SOKOLOV, Candidate of Sciences (Engineering), (This email address is being protected from spambots. You need JavaScript enabled to view it.)
F.L. PAVLOV, Engineer-Designer

Chuvash State University named after I.N. Ulianov (15, Moskovsky Prospect, Cheboksary, Chuvash Republic, 428015, Russian Federation)

1. Ilyichev V.A., Mangushev R.A., Nikiforova N.S. Experience in the development of the underground space of Russian megacities. Osnovaniya, fundamenty i mekhanika gruntov. 2012. No. 2, pp. 17–20. (In Russian).
2. Ulitsky V.M., Shashkin A.G., Shashkin K.G. Geotekhnicheskoe soprovozhdenie razvitiya gorodov [Geotechnical maintenance of development of the cities]. Saint Petersburg: Georekonstruktsia. 2010. 551 p.
3. Ter-Martirosyan Z. G. Mehanika gruntov [Mechanic of soil]. M.: ASV. 2009. 550 р.
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5. Mangushev R. A., Gurski A.V.Assessment of the impact of sheet pile indentation on additional precipitation of neighboring buildings. Geotechnica. 2016. No. 2, pp. 2–7. (In Russian).
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8. Ter-Martirosyan Z.G., Ter-Martirosyan A.Z., Sobolev E.S. Analysis of data of geotechnical monitoring of the slabby bases of the big area. Geotekhnika. 2012. No. 4, рp. 28–34. (In Russian).
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For citation: Sokolov N.S., Pavlov F.L. The use of weak bases when constructing main roads. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 45–49. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-45-49

Results of the Study of the Causes of Destruction of Concrete Pavement of a Sea Pier on the Coast of the Sea of Japan

Number of journal: 11-2019
Autors:

Vavreniuk S.V.
Efimenko Yu.V.
Vavreniuk V.G.
Farafonov A.E.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-37-41
УДК: 621.78.019.8

 

AbstractAbout AuthorsReferences
Results of the study at aimed at identifying the causes of the destruction of the concrete coating of the sea pier on the West Coast of the Japan Sea are presented. It is shown how intense the processes of salt and atmospheric corrosion of concrete, as well as leaching of cement hydration products from concrete with high permeability of concrete (W<4) and low density (water absorption of 9.3–9.5%). The fact of the lack of proper compaction and maintenance of the concrete coating during the execution of concrete works, which led to high porosity (19%) of concrete and incomplete hydration of cement, has been established. And, as a result, there was intense atmospheric (carbonate) and salt (magnesium-sulfate) corrosion, accompanied by frost destruction. It was determined that the maximum amount of marine corrosion products in the form of brucite (up to 2–4%), chlorine ion (up to 2–3%) and Friedel salt (up to 3%) in the concrete coating is contained in areas adjacent to lines of the sea. In process of moving away from the sea coast, the amount of bruсite and chloride-ion in the concrete of the coating decreases. Moreover, in a number of samples, the content of bruсite Mg(OH)2 in concrete increases in proportion to the amount of chloride ion.
S.V. VAVRENIUK, Doctor of Sciences (Engineering), Corresponding Member of RAACS
Yu.V. EFIMENKO, Candidate of Sciences (Engineering)
V.G. VAVRENIUK, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.E. FARAFONOV, Engineer

Branch of FGBU “TSNIIP of Russian Minstroy”, Ministry of Construction, Housing and Utilities of the Russian Federation Far-Eastern Research, Design and Technological Institute of Construction (Branch of FGBU “TSNIIP of Russian Minstroy”, DalNIIS) (14, Borodinskaya Street, Vladivostok, 690033, Russian Federation)

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For citation: Vavreniuk S.V., Efimenko Yu.V., Vavreniuk V.G., Farafonov A.E. Results of the study of the causes of destruction of concrete pavement of a sea pier on the coast of the Sea of Japan. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 37–41. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-37-41

Industry of Nonmetallic Building Materials. Prospection

Number of journal: 11-2019
Autors:

Butkevich G.R.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-32-36
УДК: 622

 

AbstractAbout AuthorsReferences
The article presents an analysis of the current state of the industry of nonmetallic building materials. Its differences from other mining industries are presented. The main difference is a large number of quarries. The well-known forecasts of industrial development as an axiom accept that the modern model of civilization cannot exist without the use of nonmetallic building materials in increasing volumes. The forecast of the development directions of industry technology is hampered by the lack of consumer requirements for changing product quality characteristics due to the improvement of construction technologies. The directions in which one can expect the application of new technical solutions in the domestic industry are named. In the control system - the introduction of robotic technology. When mining separately granular rocks – floating clamshell-type machine and rower-drag scraper. Self-propelled and mobile (modular) crushing and screening complexes will receive mass adoption in the coming years. The displacement of the drilling and blasting method of destruction of rock by mechanical methods depends on the tightening of environmental requirements. The need to improve mining legislation is noted. Examples of career-based innovative technical solutions in foreign countries are given.
G.R. BUTKEVICH, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.), Independent Expert
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For citation: Butkevich G.R. Industry of nonmetallic building materials. Prospection. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 32–36. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-32-36

Structural and Morphological Analysis of Bituminous Binder Modified with Colloidal Additive

Number of journal: 11-2019
Autors:

Rudakov E.O.
Urkhanova L.A.
Shadrinov N.V.
Borisova A.A.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-26-29
УДК: 691.168

 

AbstractAbout AuthorsReferences
A structural and morphological analysis of a bituminous binder modified with a colloidal additive using the atomic force microscopy method is presented. A colloidal additive – a product of collagen dissolution-is synthesized by extraction in an acid solvent. The introduction of the colloidal additive in the bitumen binder makes it possible to adjust its properties such as the softening temperature (by the method of Ring and ball), the depth of penetration of the needle, the apparent viscosity. Stone-mastic asphalt concrete based on bitumen modified with colloidal additive has increased physical and mechanical characteristics. To study the changes in the microstructural organization of bitumens modified with colloidal additive, images of the relief and phase contrast of the surface of samples of bitumen binder with the addition of collagen-containing additive were obtained. The influence of colloidal additive on the change of the microstructure of the bitumen binder, on which the change of the basic properties of bitumen depends, is revealed.
E.O. RUDAKOV1, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
L.A. URKHANOVA1, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
N.V. SHADRINOV2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.A. BORISOVA2, Candidate of Sciences (Engineering)

1 East Siberia state university of technology and management (40v, Kluchevskaya Street, Ulan-Ude, 670013, Russian Federation)
2 Institute of Problems of Oil and Gas of the Siberian Branch of the Russian Academy of Sciences (20, Avtodorozhnaya Street, Yakutsk, 677000, Russian Federation)

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10. Rudakov E.O., Urhanova L.A., Shalbuev D.V. Asphalt concrete and crushed-stone and mastic asphalt concrete with application of colloidal additives. Vestnik Vostochno-Sibirskogo gosudarstvennogo universiteta technologiy i upravleniya. 2015. No. 6 (57), pp. 38–42. (In Russian).
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For citation: Rudakov E.O., Urkhanova L.A., Shadrinov N.V., Borisova A.A. Structural and morphological analysis of bituminous binder modified with colloidal additive. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 26–29. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-26-29

Synthesis of Nanoproushers Amorphous Silicon Dioxide for the Construction Industry

Number of journal: 11-2019
Autors:

Selyaev V.P.
Neverov V.A.
Nurlybaev R.E.
Selyaev P.V.
Kechutkina E.L.
Liyaskin O.V.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-15-25
УДК: 624:539.2

 

AbstractAbout AuthorsReferences
Silica fume is a strategic multi-purpose raw material resource for the construction industry of the Russian Federation. The possibility of synthesis of microsilica on the basis of opal-cristobalite rocks is shown. It has been established that on the basis of diatomites from deposits of the middle Volga region of the Russian Federation and the Aktyubinsk region of the Republic of Kazakhstan, it is possible to obtain synthetic silica fume of high “purity” with silica content above 99%, particle size 20–200 nm, bulk density below 200 kg/m3. As a result of experimental studies carried out with the use of modern instruments and equipment, and analyzing the elemental composition, the structure of diatomites and the structural features of the surface of particles of disperse systems have established: synthesized silica fume is represented by the opal mineral; has an amorphous structure with porosity up to 95%; The surface of the particles of synthesized silica contains mainly silanol groups, adsorbed water, and is characterized by high heterogeneity with the fractal dimension of scattering inhomogeneities Ds=2.64. An analytical (polynomial) model of the dependence of the particle size, the “purity” of the synthesized silicon dioxide on the concentration, temperature, and the ratio L:S of a colloidal solution in the synthesis process was obtained. The possibility of using synthesized silicon dioxide for the production of: vacuum insulation panels (with a thermal conductivity of 0.002–0.02 W/m·K); high-strength cement composites (strength over 100 MPa on the seventh day); uviol glasses.
V.P. SELYAEV1, Doctor of Sciences (Engineering), Academician of RAACS (This email address is being protected from spambots. You need JavaScript enabled to view it.)
V.A. NEVEROV1, Candidate of Sciences (Physics and Mathematics) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
R.E. NURLYBAEV2, PhD (This email address is being protected from spambots. You need JavaScript enabled to view it.)
P.V. SELYAEV1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
E.L. KECHUTKINA1, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
O.V. LIYASKIN1, Post-graduate student (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 National Research N.P. Ogarev Mordovia State University (68, Bolshevistskaya Street, Saransk, Republic of Mordovia, 430005, Russian Federation)
2 Satbayev University (Kazakh National Research Technical University named after K.I. Satpayev) (office 13, 22, Satpayeva Street, Almaty, 050013, Republic of Kazakhstan)

1. Selyaev V.P., Selyaev P.V. Fiziko-khimicheskiye osnovy mekhaniki razrusheniya tsementnykh kompozitov [Physical and chemical fundamentals of mechanics of destruction of cement composites ]. Saransk: Publishing house of the Mordovian university. 2018. 220 p.
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24. Selyaev V.P., Sedova A.A., Kupriyashkina L.I., Osipov A.K. Optimization of the technological regimes of sol-gel production by the method of high-purity silica fume with nanoscale-level particles. Izvestiya vysshikh uchebnykh zavedeniy. Stroitel’stvo. 2018. No. 2 (710), pp. 5–13. (In Russian).
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For citation: Selyaev V.P., Neverov V.A., Nurlybaev R.E., Selyaev P.V., Kechutkina E.L., Liyaskin O.V. Synthesis of nanoproushers amorphous silicon dioxide for the construction industry. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 15–25. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-15-25

Concept and Bases of Technologies of Nano-Modification of Building Composites Structures. Part 7. Final: Actual Generalization

Number of journal: 11-2019
Autors:

Chernyshov E.M.
Artamonova O.V.

DOI: https://doi.org/10.31659/0585-430X-2019-776-11-3-14
УДК: 666.972.16:539.2

 

AbstractAbout AuthorsReferences
The final part of a series of publications devoted to the problem of nanotechnologies of building composites with inorganic hydration-synthesis, hydrothermal-synthesis, thermal-synthesis hardening systems determining the possibility of obtaining lime, cement, silicate, ceramic materials with new properties is presented. The motives of preparing the series of publications are discussed, the analysis of the concepts and scientific basis of the solution of problems of the nano-modification technologies of structures of hardening systems of mentioned building composites is made. In the framework of the theory of the evolutionary route of solid-phase state formation, conceptual models of the regularities of such formation, control factors are identified and an arsenal of “nano” for nano-modification technologies is proposed. The theoretical and practical significance of the research results is assessed. In this regard, examples of their effective implementation in engineering construction and technological activities and educational practice are given.
E.M. CHERNYSHOV, Doctor of Sciences (Engineering), Academician of RAAСS (This email address is being protected from spambots. You need JavaScript enabled to view it.)
O.V. ARTAMONOVA, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

Voronezh State University of Architecture and Civil Engineering (84, 20-let Oktyabrya Street, Voronezh, 394006, Russian Federation)

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For citation: Chernyshov E.M., Artamonova O.V. Concept and bases of technologies of nano-modification of building composites structures. Part 7. Final: Actual Generalization. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 3–14. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-3-14

On the Issue of Chemical Corrosion and Durability of Brick Masonry

Number of journal: 10-2019
Autors:

Kotlyar V.D.
Nebezhko N.I.
Terekhina Yu.V.
Kotlyar A.V.

DOI: https://doi.org/10.31659/0585-430X-2019-775-10-78-84
УДК: 691.421

 

AbstractAbout AuthorsReferences
Topical issues related to the durability and chemical corrosion of masonry at modern construction sites are discussed. Controversial issues presented in the articles by D.Yu. Zheldakov, according to the results of his research of chemical corrosion and durability of brick masonry are considered. The substantiation of resistance of ceramic brick to chemical corrosion, and also that for our climate the main property defining durability of products is frost resistance is made. A critical analysis of the brick-work destruction mechanism proposed by the author is presented, where the basis is the reaction between calcium hydroxide and silicon and aluminum oxides with the formation of wollastonite and mono-calcium aluminate. The inconsistency of the conclusions made by the author that he has developed a mechanism for the destruction of bricks in the “brick-cement-sand mortar” system at positive temperatures is shown. The method proposed by the author for calculating the ultimate durability of the structural material with respect to the strength parameter taking into account chemical corrosion processes, as well as the author’s main conclusion that when using multi-layer enclosing structures, their durability must not be determined for each material, but only taking into account the chemical destruction processes under the mutual influence of all materials is questioned.
V.D. KOTLYAR1, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
N.I. NEBEZHKO2, Engineer
Yu.V. TEREKHINA1, Engineer
A.V. KOTLYAR1, Candidate of Sciences (Engineering)

1 Don State Technical University (1, Gagarin Square, Rostov-on-Don, 344000, Russian Federation)
2 Individual Entrepreneur (108, Prosveshcheniya Street, Novocherkassk, 344000, Russian Federation)

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For citation: Kotlyar V.D., Nebezhko N.I., Terekhina Yu.V., Kotlyar A.V. On the issue of chemical corrosion and durability of brick masonry. Stroitel’nye Materialy [Construction Materials]. 2019. No. 10, pp. 78–84. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-775-10-78-84

Clinkerless Binders Based on Peat Ash

Number of journal: 10-2019
Autors:

Rusina V.V.
Shestakova Yu.A.

DOI: https://doi.org/10.31659/0585-430X-2019-775-10-70-74
УДК: 666.963.4

 

AbstractAbout AuthorsReferences
The possibility of using peat ash as the main component of ash-alkaline binder is considered. The properties of ash produced at the CHP (heat and power plant) when combusting the peat have been studied. A comprehensive study conducted using electron microscopic, x-ray phase and chemical analyses, established that peat ash consists of small particles, which are mainly in an amorphous form. It is shown that the chemical composition of the material under study is an acidic aluminosilicate raw material. Peat ash is not hydrated by water and does not harden on its own. The introduction of an alkaline component (liquid glass) is proposed for the manifestation of the binding properties by ash. The necessity of modifying industrial liquid glass from a silicate block by introducing an additional amount of alkali NaOH into its composition and a short boiling has been established. It is concluded that the combined use of peat ash and modified liquid glass from a silicate block makes it possible to obtain an ash-alkaline binder with an activity of more than 20 MPa. It is noted that the main indicators of the properties of the ash-alkali binder depend on the amount of alkali introduced into the liquid glass, the density of the liquid glass and its flow rate in the binder system. On the basis of experimental data the conclusion about expediency of the use of peat ash as a part of ash-alkaline binder is made. The possibility of using peat ash was confirmed by the results of gamma-spectral analysis for determining the specific effective activity of natural radionuclides. The efficiency of using peat ash in the production of clinkerless binders is shown.
V.V. RUSINA, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
Yu.A. SHESTAKOVA, Master (This email address is being protected from spambots. You need JavaScript enabled to view it.)

Kostroma State Agricultural Academy (34, Training camp, Karavaevo, Kostroma Region, 156530, Russian Federation)

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For citation: Rusina V.V., Shestakova Yu.A. Clinkerless binders based on peat ash. Stroitel’nye Materialy [Construction Materials]. 2019. No. 10, pp. 70–74. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-775-10-70-74

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