Properties and Structure of Anhydrite Binder of Ergachinsky Deposit in the Presence of Phosphate Activators and Aleurolite

Number of journal: 10-2019
Autors:

Tokarev Yu.V.
Ageev A.V.
Volkov M.A.
Kuzmina N.V.
Yakovlev G.I.

DOI: https://doi.org/10.31659/0585-430X-2019-775-10-46-52
УДК: 691.553

 

AbstractAbout AuthorsReferences
The results of studies of physical and mechanical properties and structure of the binder based on natural anhydrite in the presence of chemical and mineral additives are presented. The data were obtained by mechanical testing, differential scanning calorimetry, infrared spectral analysis, scanning electron microscopy and laser granulometry. For the first time, the efficiency of using phosphates of sodium and ammonium as activators of hardening of anhydrite binder is shown. Strength characteristics are increased from 2.5 to 4 times compared to the control composition, depending on the type of additive. The efficiency of using aleurolite – aluminosilicate rock of sedimentary origin as a mineral additive has been established. The use of an additive in an amount from 0 to 5% leads to an increase in strength to 40%, which is caused by the action of aleurolite particles as crystallization centers, on the surface of which crystallohydrates of gypsum dihydrate are formed. In this case, the additive is directly involved in the formation of the structure, which is confirmed by the results of infrared spectral analysis. The introduction of burnt aleurolite separately is impractical, but when combined introduction with lime strength characteristics are increased to 45% due to additional compaction by new hydration products formed by the interaction of metacaolin and lime.
Yu.V. TOKAREV, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.V. AGEEV, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.)
M.A. VOLKOV, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.)
N.V. KUZMINA, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
G.I. YAKOVLEV, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

Kalashnikov Izhevsk State Technical University (7, Studencheskaya Street, Izhevsk, 426069, Russian Federation)

1. Sergeeva N.A., Sycheva L.I. The influence of the structure of the anhydrite component on the properties of multiphase gypsum binders. Uspekhi v khimii i khimicheskoy tekhnologii. 2017. Vol. 31. No. 3 (184), pp. 102–104. (In Russian).
2. Sergeeva N.A., Sycheva L.I. The effect of additives on the properties of anhydrite binder. Uspekhi v khimii i khimicheskoy tekhnologii. 2017. Vol. 32. No. 2 (198), pp. 158–160. (In Russian).
3. Anikanova L.A., Volkova О.V., Kudyakov A.I., Kurmangalieva A.I. Mechanically activated composite fluoroanhydrite binder. Stroitel’nye Materialy [Construction Materials]. 2019. No. 1–2, pp. 36–42. DOI: https://doi.org/10.31659/0585-430X-2019-767-1-2-36-42 (In Russian).
4. Klimenko V.G. The role of double salts based on sulfates of Na+, K+, Ca2+, NH4+ in the technology of producing anhydrite binders. Vestnik Belgorodskogo gosudarstvennogo tekhnologicheskogo universiteta im. V.G. Shukhova. 2017. No. 12, pp. 119–125. (In Russian).
5. Altykis M.G., Khaliullin M.I., Rakhimov R.Z., Morozov V.P., Bakhtin A.I. To the question of the mechanism of structural transformations of gypsum binders based on CaSO4 anhydrite in the process of hardening. Izvestiya vuzov. Stroitel’stvo. 1996. No. 12, pp. 57–61. (In Russian).
6. Garkavi M.S., Artamonov A.V., Kolodyazhnaya E.V., Burianov A.F. Composite anhydrite-slag binder of centrifugal-impact grinding. Stroitel’nye Materialy [Construction Materials]. 2014. No. 7, pp. 16–18. (In Russian).
7. Garkavi M.S., Artamonov A.V., Kolodezhnaya E.V., Nefedev A.P., Khudovekova E.A., Buryanov A.F., Fisher H.-B. Activated fillers for gypsum and anhydrite mixes. Stroitel’nye Materialy [Construction Materials]. 2018. No. 8, pp. 14–17. DOI: https://doi.org/10.31659/0585-430X-2018-762-8-14-17 (In Russian).
8. Levashova A.K., Sycheva L.I. The influence of the nature of the plasticizer on the properties of anhydrite binder. Uspekhi v khimii i khimicheskoy tekhnologii. 2016. No. 7 (176). URL: https://cyberleninka.ru/article/n/vliyanie-prirody-plastifikatora-na-svoystva-angidritovogo-vyazhuschego (Date of access: 05/13/2019).
9. Tkachenko D.I. The influence of metallurgical dust on the properties and structure of anhydrite compositions. Resursoeffektivnyye tekhnologii v stroitel’nom komplekse regiona. 2017. No. 8, pp. 112–114. (In Russian).
10. Fomina E.V., Lesovik V.S., Fomin A.E., Absimetov M.V., Elistratkin M.Yu. Increasing the effectiveness of aerated concrete through the use of coal waste. Regional’naya arkhitektura i stroitel’stvo. 2018. No. 4  (37), pp. 38–47. (In Russian).
11. Urkhanova L.A., Antropova I.G. The use of ultrabasic aluminosilicate rocks of Buryatia in the technology of building materials. Vestnik VSGUTU. 2017. No. 1 (64), pp. 68–72. (In Russian).
12. Maria C.G. Juenger, Ruben Snellings, Susan A. Bernal. Supplementary cementitious materials: New sources, characterization, and performance insights. Cement and Concrete Research. 2019. Vol. 122, pp. 257–273.
13. Singh N.B., Middendorf B. Calcium sulphate hemihydrate hydration leading to gypsum crystallization. Progress in Crystal Growth and Characterization of Materials. 2007. Vol. 53, pp. 57–77.
14. Konovalov V.M., Glikin D.M., Solomatova S.S. The use of mudstones in the production of mixed cements. Sovremennyye problemy nauki i obrazovaniya. 2015. No. 2–2, p. 96. (In Russian).
15. Zinin E.V., Sycheva L.I. Gypsum-cement-pozzolanic binders based on gypsum and anhydrite. Uspekhi v khimii i khimicheskoy tekhnologii. 2017. Vol. 31. No. 3, pp. 37–39. (In Russian).

For citation: Tokarev Yu.V., Ageev A.V., Volkov M.A., Kuzmina N.V., Yakovlev G.I. Properties and structure of anhydrite binder of Ergachinsky deposit in the presence of phosphate activators and aleurolite. Stroitel’nye Materialy [Construction Materials]. 2019. No. 10, pp. 46–52. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-775-10-46-52


Print   Email