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Features of Hardening of Aluminosilicophosphate Binder in Cellular Concrete

Number of journal: 1-2-2024
Autors:

Abyzov V.A.,
Posadnova N.E.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-53-58
УДК: 666.973.6

 

AbstractAbout AuthorsReferences
Cellular phosphate concretes are used as an insulating material for some high-temperature aggregates due to their high temperature resistance, fire resistance and residual strength at the level of values after drying. The use of industrial waste in phosphate cellular concrete technology made it possible to improve some properties without reducing the application temperature. The paper shows that dispersed aluminosilicate waste from refractory production has sufficient activity (porization ability) to obtain a phosphate binder. The features of the hardening of an aluminosilicophosphate binder cured with dispersed metallic aluminum have been studied; the change in the phase composition of the cured binder after firing at different temperatures has been studied by differential thermal and X-ray phase analysis. It has been established that the developed aluminosilicophosphate binder makes it possible to obtain fireclay cellular concrete with an application temperature of up to 1400оC. A comparison of the changes in the phase composition for the developed aluminosilicophosphate composition and a pure aluminophosphate binder is performed. A shift in the temperature of the processes is noted in an upward direction for the aluminosilicophosphate binder, which is explained by the fact that silicon ions do not form independent phosphate compounds, but are embedded in the crystal lattice of aluminophosphates, changing their properties and shifting the intervals of phase transitions.
V.A. ABYZOV, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
N.E. POSADNOVA, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)

South Ural State University (National Research University) (76, Lenina Avenue, Chelyabinsk, 454080, Russian Federation)

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For citation: Abyzov V.A., Posadnova N.E. Features of hardening of aluminosilicophosphate binder in cellular concrete. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 53–58. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-53-58

Features of the Behavior of Highly Frost-Resistant Modified Concretes

Number of journal: 1-2-2024
Autors:

Shuldyakov K.V.,
Butakova M.D.,
Mordovtseva M.V.,
Zimakov K.I.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-49-52
УДК: 666.972.53

 

АннотацияОб авторахСписок литературы
One of the main criteria of construction is reliability and durability. Therefore, for the implementation of modern construction projects, especially in harsh operating conditions, cement composites with increased resistance to aggressive external cyclic influences are necessary. For the climatic conditions of the Russian Federation, special attention should be paid to ensuring the frost resistance of concrete. Thus, in accordance with GOST 31384–2017 “Protection of concrete and reinforced concrete structures from corrosion. General technical requirements”, for the lowest temperature and under the condition of alternating freezing and thawing of concrete in a saturated state, the frost resistance mark must be at least F2450. In addition, high mechanical characteristics of the materials used, including the modulus of elasticity, are required, for example, in the construction of infrastructure facilities in the Arctic zone of Russia. To ensure these characteristics, effective modifying additives must be introduced into the concrete mix. However, there is evidence in the literature that water-reducing additives of various genesis, with similar values of water reduction, have different effects on the structure of the formed cement stone. Therefore, in order to ensure high durability of concrete, this article will consider the relationship between the emerging structure of cement stone in concrete and its resistance parameters.
K.V. SHULDYAKOV, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
M.D. BUTAKOVA, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
M.V. MORDOVTSEVA, Graduate student (This email address is being protected from spambots. You need JavaScript enabled to view it.),
K.I. ZIMAKOV, Student (This email address is being protected from spambots. You need JavaScript enabled to view it.)

South Ural State University (National Research University) (76, Lenina Avenue, Chelyabinsk, 454080, Russian Federation)

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Для цитирования: Shuldyakov K.V., Butakova M.D., Mordovtseva M.V., Zimakov K.I. Features of the behavior of highly frost-resistant modified concretes. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 49–52. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-49-52

Application of Blast Furnace Granulated Slag for Self-Healing Bio-Concretes

Number of journal: 1-2-2024
Autors:

Chernykh T.N.,
Gorbachevskikh K.A.,
Komel'kova M.V.,
Platkovskiy P.O.,
Kriushin M.V.,
Orlov A.A.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-42-48
УДК: 666.974

 

AbstractAbout AuthorsReferences
The properties of fine-grained concrete containing 20–80% granulated blast furnace slag and bacteria species Bacillus Subtilis have been studied. An assessment was made of changes in strength, self-healing of cracks using optical and electron microscopy and measuring the speed of ultrasound propagation perpendicular to the crack plane; composition and characteristics of the healing agent in cracks using X-ray analysis methods. Self-healing of cracks in concrete without bacteria occurred due to calcite deposition as a result of carbonation of portlandite during 50–65 cycles of humidification-drying, and in the presence of Bacillus Subtilis bacteria due to calcite deposition during their vital activity in 10–15 cycles. It is shown that the addition of granulated blast furnace slag slows down the crystallization of calcite, which forms a healing substance in the crack. It is assumed that the combined use of granulated blast furnace slag in dosages of 40–80% and Bacillus Subtilis bacteria in concrete structures operating under conditions of variable humidification can ensure the process of self-healing cracks and maintaining the strength of concrete in the long term due to simultaneous processes of strengthening the structure due to prolonged hydration of slag minerals and calcite deposition in cracks due to the vital activity of Bacillus Subtilis bacteria.
T.N. CHERNYKH, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
K.A. GORBACHEVSKIKH, Student (This email address is being protected from spambots. You need JavaScript enabled to view it.),
M.V. KOMEL'KOVA, Doctor of Sciences (Biology) (This email address is being protected from spambots. You need JavaScript enabled to view it.), P.O. PLATKOVSKIY, Research Assistant (This email address is being protected from spambots. You need JavaScript enabled to view it.), M.V. KRIUSHIN, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.), A.A. ORLOV, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)South Ural State University (National Research University) (76, Lenina Avenue, Chelyabinsk, 454080, Russian Federation)
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For citation: Chernykh T.N., Gorbachevskikh K.A., Komel'kova M.V., Platkovskiy P.O., Kriushin M.V., Orlov A.A. Application of blast furnace granulated slag for self-healing bio-concretes. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 42–48. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-42-48

Comparative Analysis of Asphalt Forming Processes Based on Finely Dispersed Expanded Clay Powders

Number of journal: 1-2-2024
Autors:

Kazaryan S.O.,
Borisenko Yu.G.,
Yagubov M.G.,
Shuhaib K.F.A.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-36-40
УДК: 691.16

 

AbstractAbout AuthorsReferences
The features of the structure formation of an asphalt binder modified with a highly dispersed expanded clay powder are investigated. The viscosity of the modified asphalt binder and the formation of an adsorption layer of bitumen on the surface of the particles of the mineral component at various degrees of filling in the temperature range of 100–180oC have been studied. The effect of the impact of expanded clay powder on the adsorption activity of bitumen, the adhesive strength of bitumen with a mineral filler and on the adhesion of an asphalt binder with a mineral filler is analyzed. It was revealed that the interaction of bitumen with highly dispersed expanded clay powder significantly increases the viscosity of the asphalt binder and increases the thickness of the bitumen film on the surface of mineral particles at all process temperatures compared with standard limestone mineral powder, which is determined by the processes of selective diffusion of low-molecular hydrocarbons into the particles of expanded clay powder occurring when combined with the binder. Modification of the asphalt binder with expanded clay powder significantly increases its adsorption activity and adhesion of bitumen to mineral aggregate and adhesive strength at the interface of the «filler–bitumen» phases. This is due not only to physical interaction, but also to the presence of an increased number of active surface adsorption centers of Lewis and Brensted on the surface of expanded clay particles, which indicates the formation of chemical bonds.
S.O. KAZARYAN, Senior Lecturer (This email address is being protected from spambots. You need JavaScript enabled to view it.),
Yu.G. BORISENKO, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
M.G. YAGUBOV, Graduate Student (This email address is being protected from spambots. You need JavaScript enabled to view it.),
K.F.A. SHUHAIB, Graduate Student (This email address is being protected from spambots. You need JavaScript enabled to view it.)

North Caucasus Federal University (1, Pushkina Street, Stavropol, 355017, Russian Federation)

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For citation: Kazaryan S.O., Borisenko Yu.G., Yagubov M.G., Shuhaib K.F.A. Comparative analysis of asphalt forming processes based on finely dispersed expanded clay powders. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 36–40. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-36-40

Risks of Using Slag Aggregates in Concrete Products for Road Construction

Number of journal: 1-2-2024
Autors:

Kolomoitsev N.A.,
Makaeva A.A.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-29-35
УДК: 625.861

 

AbstractAbout AuthorsReferences
When GOST 17608 and GOST 6665 were republished, the authors prohibited the use of slag fillers, so manufacturers of products produced according to these standards have a problem: the use of only natural inert materials will lead to an increase in the cost of the final product. At the same time, however, this should lead to an improvement in the quality of manufactured products. But is it so? This article presents a comparative analysis of standards for fillers of natural origin and from metallurgical production waste in order to identify the reasons that do not allow the use of slag aggregates in concrete products for road construction. It was determined that most of the requirements for aggregates of both natural and man-made origin are the same, i.e. if the manufacturers observe and fulfill the requirements of the standards for slag aggregates, there should be no risk of reducing the quality of the final product. Then why the developers of GOST 17608 and GOST 6665, excluding from the list of aggregates for concrete materials according to GOST 3344–83 do not give an alternative in the form of aggregates according to GOST 5578–2019? The authors of the article have tried to reveal the answer to this question.
N.A. KOLOMOITSEV1, Technical Expert (This email address is being protected from spambots. You need JavaScript enabled to view it.);
A.A. MAKAEVA2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 AKKERMANN CEMENT LLC (5, Zapad Street, Orenburg, Orenburg region, 462360, Russia Federation)
2 Orenburg State University (13, Pobedy Avenue, Orenburg, 460018, Russia Federation)

1. Khokhryakov A.V., Tseytlin E.M. Waste generation of metallurgical enterprises of the Urals and their impact on the environment. Izvestia of Samara Scientific Center of the Russian Academy of Sciences. 2012. Vol. 14. No. 1–3, pp. 834–837. (In Russian).
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For citation: Kolomoitsev N.A., Makaeva A.A. Risks of using slag aggregates in concrete products for road construction. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 29–35. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-29-35

Technological Aspects of Ensuring the Quality of Protective Coatings of Building Metal Structures

Number of journal: 1-2-2024
Autors:

Pichugin A.P.,
Khritankov V.F.,
Pchelnikov A.V.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-22-28
УДК: 693.8:620.3

 

AbstractAbout AuthorsReferences
This article discusses issues related to the development of technological solutions designed to obtain protective paint and varnish coatings with high operational resistance for building metal structures. The developed technological map and scheme for creating nanostructured paint and varnish coatings on the surfaces of building metal structures are presented. These proposals complement the comprehensive approach to the development of protective paint and varnish coatings, consisting of methodological, technological and formulation solutions, and presented in other studies by the authors, which allows for its effective use in paint and varnish industry enterprises. The research results, based on the application of the developed solutions in laboratory and operational conditions, confirm the high efficiency of the developed integrated approach. Assessment of the quality of coatings in laboratory conditions showed that coating samples after 100 hours of thermal exposure retain high properties that meet the operating conditions of building metal structures. As part of production testing, it was established that the service life of nanostructured coatings increases by 1.5–2.6 times compared to traditional coatings. In this regard, the costs of repair and restoration of coatings are reduced, and their service life between repairs is increased. The introduction of the developed solutions into production will solve the problem of low operational durability of protective paint and varnish coatings of steel building metal structures operated under various influences.
A.P. PICHUGIN1,2, Doctor of Sciences (Engineering), Professor;
V.F. KHRITANKOV1, Doctor of Sciences (Engineering), Professor;
A.V. PCHELNIKOV2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 Novosibirsk State University of Architecture and Civil Engineering (113 Leningradskaya Street, Novosibirsk, 630008, Russian Federation)
2 Novosibirsk State Agricultural University (160, Dobroliubova Street, Novosibirsk, 630039, Russian Federation)

1. Eremin K.I. Osobennosti ehkspluatacii metallicheskikh konstrukciy promyshlennykh zdaniy [Peculiarities of operation of metal structures of industrial buildings]. Moscow: MISS-MGSU, 2012. 248 p.
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3. Pichugin A.P., Banul V.V., Pchelnikov A.V. Ehffektivnaya polimernaya zashchita metallicheskikh obektov agropromyshlennogo kompleksa [Effective polymer protection of metal objects in the agro-industrial complex]. Novosibirsk: Russian Academy of Natural Sciences. 2022. 125 p.
4. Pichugin A.P., Pchelnikov A.V., Khritankov V.F., Tulyaganov A.K. Evaluation of the effectiveness of the use of nano-additives in protective coatings. Stroitel’nye Materialy [Construction Materials]. 2023. No. 3, pp. 20–26. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2023-811-3-20-26
5. Khozin V.G., Abdrakhmanova L.A., Nizamov R.K. General concentration pattern of effects of nanomodification of building materials. Stroitel’nye Materialy [Construction Materials]. 2015. No. 2, pp. 25–33. (In Russian).
6. Nelubova V.V., Kuzmin E.O., Strokova V.V.Structure and properties of nanodispersed silica synthesized by the sol-gel method. Stroitel’nye Materialy [Construction Materials]. 2022. No. 12, pp. 38–44. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2022-809-12-38-44
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9. Loganina V.I., Frolov M.V., Mazhitov E.B. Influence of protective and decorative coatings based on sol-silicate paints on the moisture regime of external walls of buildings. Construction and Geotechnics. 2021. Vol. 12. No. 4, pp. 103–114. (In Russian). DOI: 10.15593/2224-9826/2021.4.08
10. Loganina V.I., Sergeeva K.A. Evaluation of superhydrophobic properties of coatings based on acrylic resin. Regional’naya arkhitektura i stroitel’stvo. 2020. No. 1, pp. 98–103. (In Russian).
11. Mokrova M.V., Matveeva L.Yu., Letenko D.G., Strogonov Yu.A. Nanomodified thermal insulating gas gypsum: composition, properties, structure. Izvestiya of higher educational institutions. Construction. 2022. No. 3, pp. 25–32. (In Russian).
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For citation: Pichugin A.P., Khritankov V.F., Pchelnikov A.V. Technological aspects of ensuring the quality of protective coatings of building metal structures. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 22–28. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-22-28

Changing the Technological Properties and Strength Characteristics of Highly Mobile Concrete by Introducing a Complex Modifier

Number of journal: 1-2-2024
Autors:

Il'ina L.V.,
Berdov G.I.,
Vishnyakov N.S.,
Tsekar D.A.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-15-21
УДК: 666.9.031

 

AbstractAbout AuthorsReferences
The article considers the effect of a complex modifier consisting of a superplasticizer and cement crystallohydrates on the properties of cement dough, a highly mobile concrete mixture and heavy concrete obtained by hardening the mixture under normal conditions over a different period of time. As an additive of the superplasticizer, Relamix-PK was studied, administered in an amount of 0.6–0.8 wt. % of cement consumption. The authors investigated finely dispersed hydrated cement as additional crystallization centers. With the introduction of this complex modifier, the delamination of a highly mobile concrete mixture decreases (water separation – by 2 times, water separation – by 3.8 times). There is a significant acceleration of hardening in the initial periods of concrete hardening. Thus, in relation to the additive–free composition, the strength of concrete, which hardened for 1 day under normal conditions, increased 3.5 times, 3 days – 2.5 times, 28 days – 2 times. At the same time, it should be noted that when cement crystallohydrates are added, the hardening process is accelerated more in the initial terms of strength gain. The greatest strengthening effect was obtained by adding a complex modifier consisting of 0.8% plasticizer and 2% hydrated cement.
L.V. IL'INA, Doctor of Sciences (Engineering), Professor, Advisor to the RAASN (This email address is being protected from spambots. You need JavaScript enabled to view it.),
G.I. BERDOV, of Sciences (Engineering), Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
N.S. VISHNYAKOV, Graduate Student (This email address is being protected from spambots. You need JavaScript enabled to view it.),
D.A. TSEKAR, Graduate Student (This email address is being protected from spambots. You need JavaScript enabled to view it.)

Novosibirsk State University of Architecture and Civil Engineering (113, Leningradskaya Street, Novosibirsk, 630008, Russian Federation)

1. Rubin O.D., Ilyin Yu.A., Shevkin A.L., Evdokimova I.V. Creation of cast concrete mixtures using domestically produced additives. Gidrotekhnicheskoye stroitel’stvo. 2024. No. 1, pp. 12–17. (In Russian).
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3. Kastornykh L.I., Kaklyugin A.V., Gikalo M.A., Trishchenko I.V. Features of the composition of concrete mixes for concrete pumping technology. Stroitel’nye Materialy [Construction Materials]. 2020. No. 3, pp. 4–11. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2020-779-3-4-11
4. Yamada K., Kim C.B., Ichitsubo K., Ichikawa M. Combined effect of cement characteristics on the perfofmance of superplasticizers. An investigation in real cement plants. Proceedings of 8-th CANMET/ACI International Conference on Superplasticizers and Other Chemical Admixtures in Concrete. Sorrento, Italy. 2006. Vol. 1, pp. 159–174.
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8. Lotov V.A., Sarkisov Yu.S., Gorlenko N.P., Zubkova O.A. Thermokinetic studies in the «cement-microsilica-superplasticizer-water» system. Tekhnika i tekhnologiya silikatov. 2021. Vol. 28. No, 2, pp. 42–49. (In Russian).
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For citation: Il'ina L.V., Berdov G.I., Vishnyakov N.S., Tsekar D.A. Сhanging the technological properties and strength characteristics of highly mobile concrete by intro-ducing a complex modifier. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 15–21. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-15-21

Mechanical-Chemical Activation of Cement-Sand Stone for Reuse in Construction

Number of journal: 1-2-2024
Autors:

Simonov P.A.,
Storozhenko G.I.,
Rakov M.A.,
Manzyrykchy H.B.

DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-9-14
УДК: 691.4:553.61

 

AbstractAbout AuthorsReferences
In modern construction concrete recycling is one of the promising directions of utilization of multi-tonnage concrete and reinforced concrete waste. Most often concrete crushing products are reused as coarse and fine aggregate. It is shown in the paper that reuse of the dusty fraction of cement-sand stone as an active colloidal additive obtained by its alkaline mechanical-chemical activation allows to partially replace cement in commercial concrete and hydraulically hardening compositions without loss of their strength. This paper presents the results of the effect of colloidal admixture on technological and physical-mechanical properties of concrete mixture.
P.A. SIMONOV1, Candidate of Sciences (Chemistry) (This email address is being protected from spambots. You need JavaScript enabled to view it.);
G.I. STOROZHENKO2, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
M.A. RAKOV2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.);
H.B. MANZYRYKCHY3, Junior Researcher (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 Novosibirsk State University (2, Pirogova Street, Novosibirsk, 630090, Russian Federation)
2 Novosibirsk State University of Architecture and Civil Engineering (SIBSTRIN) (113, Leningradskaya Street, Novosibirsk, 630008, Russian Federation)
3 Tuvinian Institute for Exploration of Natural Resources of Siberian Branch of RAS (117 A, Internacional’naja Street, Kyzyl, 667007, Republic of Tyva, Russian Federation)

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For citation: Simonov P.A., Storozhenko G.I., Rakov M.A., Manzyrykchy H.B. Mechanical-chemical activation of cement-sand stone for reuse in construction. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 9–14. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-9-14

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