AbstractAbout AuthorsReferences
The results of studies to obtain a modifying additive based on production anthropogenic waste and research in its influence on the structure and properties of cement concretes are presented. As a basis for the production of the additive, the use of pre-processed powdered highly dispersed technical sulfur is proposed. The influence of the sulfur thermoplastic additive on the structure of the cement stone when volumetric heating of the modified samples was studied. Flexural and compression strengths, as well as the corrosion resistance of the modified formulations were determined. It is demonstrated that the use of thermoplastic additive makes it possible to create favorable conditions for the formation of the optimal structure of crystalline hydrates with simultaneous effect of internal impregation, which leads to an improvement in physical, mechanical and operational characteristics. A variant of possible treatment of the dispersed phase surface on the basis of powdered sulfur for the subsequent uniform distribution of the additive particles in the composite volume is also proposed. It is shown that the production of sulfur as a by-product of oil refining significantly exceeds consumption, and the development of new ways of additional use of the production waste is an actual direction.
A.N. GUMENIUK1, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
I.S. POLYANSKIKH2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
G.N. PERVUSHIN2, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.F. GORDINA2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
G.I. YAKOVLEV2, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
D.R. KHAZEEV2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
I.S. POLYANSKIKH2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
G.N. PERVUSHIN2, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.F. GORDINA2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
G.I. YAKOVLEV2, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
D.R. KHAZEEV2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
1 Udmurtregiongaz LLC (357, Kommunarov Street, Izhevsk, 426008, Russian Federation)
2 Kalashnikov Izhevsk State Technical University (7, Studencheskaya Street, Izhevsk, 426069, Russian Federation)
1. Bobylev Yu.N. World oil market: main trends in 2018 Ekonomicheskoe razvitie Rossii. 2019. Vol. 26. No. 1, pp. 10–13. (In Russian).
2. Bobylev Yu.N. The oil sector: the main trends of 2018–2019. Ekonomicheskoe razvitie Rossii. 2019. Vol. 26. No. 3, pp. 13–17. (In Russian).
3. Nagibin G.E., Nazirov R.A., Dobrosmyslov S.S., Fedorova E.N., Zadov V.E., Shevchenko V.A. Binders based on technical sulfur and ash and slag waste. Vyazhushchie na osnove tekhnicheskoi sery i zoloshlakovykh otkhodov Zhurnal Sibirskogo federal’nogo universiteta. Seriya: Tekhnika i tekhnologii. 2013. Vol. 6. No. 6, pp. 689–698. (In Russian).
4. Doshlov O.I., Kalapov I.A. The method of disposal of industrial waste - technical sulfur, using it for road construction. The current state and prospects for improving the environment and life safety of the Baikal region “White Nights 2016”: a collection of articles of the International Scientific and Technical Conference: in 2 volumes. 2016, pp. 281–288. (In Russian).
5. Lichman N.V., Kukharenko L.V., Nikitin I.V. The use of technical sulfur and mining and metallurgical wastes in hydraulic engineering construction. Stroitel’nye Materialy [Construction materials]. 2005. No. 7, pp. 10–13. (In Russian).
6. Lipina A.V. Research of innovative technological methods for utilization of sulfur-containing waste and technical sulfur. Uspekhi sovremennoi nauki i obrazovaniya. 2016. No. 2, pp. 73–76. (In Russian).
7. Doshlov O.I., Kalapov I.A. New road bitumens based on organic binder, modified with technical sulfur and polymer additives. Vestnik Irkutskogo gosudarstvennogo tekhnicheskogo universiteta. 2015. No. 11 (106), pp. 107–111. (In Russian).
8. Gumenyuk A.N., Shevchenko F.E., Zhukov A.N. Universal composition for the modification of building materials on the basis of technical sulfur. In the collection: Innovation Exhibition – 2018 (spring session). Compendium of the XXV Republican exhibitionsession of student innovation projects. 2018, pp. 25–29. (In Russian).
9. N’yat Tkhyui Z.L., Epishkin N.A., Balabanov V.B., Baryshok V.P. High-strength and cold-resistant concretes using technical sulfur. Izvestiya vuzov. Investitsii. Stroitel’stvo. Nedvizhimost’. 2018. Vol. 8. No. 3 (26), pp. 122–129. (In Russian).
10. Gumenyuk A.N., Yakovlev G.I., Polyanskikh I.S., Gordina A.F., Grakhov V.P. Thermoplastic additive of technogenic origin for concrete and mortars. Intellektual’nye sistemy v proizvodstve. 2019. Vol. 17. No. 1, pp. 126–130. (In Russian).
11. Bazhenov Y.M. Betonopolimery [Concrete Polymers]. Moscow: Stroyizdat. 1983. 472 p.
12. Paturoev V.V. Polimerbetony [Polymer concrete] Moscow: Stroyizdat. 1987. 286 p.
13. Mohamed Sassi, Ashwani K. Gupta Sulphur recovery from acid gas using the claus process and high temperature air combustion technology. American Journal of Environmental Sciences. 2008. No. 5, pp. 502–511. DOI: 10.3844/ajessp.2008.502.511
14. Chaudhuri R. G., Paria S. Synthesis of sulfur nanoparticles in aqueous surfactant solutions. Journal of Colloid and Interface Science. 2010. Vol. 343 (2), pp. 439–446. doi: 10.1016/j.jcis.2009.12.004
15. Voronkov M.G., Vyazankin N.S., Deryagina E.N., Nakhmanovich A.S., Usov V.A. Reaktsii sery s organicheskimi soedineniyami [Reactions of sulfur with organic compounds]. Novosibirsk: Nauka. 1979. 352 p.
16. Polyasnkikh I.S., Yakovlev G.I., Gordina A.F., Gumeniuk A.N., Drohitka R., Urhanova L.A. Compositions based on industrial sulfur sol for gypsum materials. 20. Internationale Baustofftagung. Weimar, 2018, pp. 133–146.
17. Korolev E.V., Andreeva O.O., Proshin A.P. Method for determining the mutual solubility of substances in multicomponent systems. Modern problems of building materials science. The Seventh Academic Readings of the RAACS. Belgorod. 2001, pp. 269–273. (In Russian).
18. Khozin V.G., Abdrakhmanova L.А., Nizamov R.К. Common concentration pattern of effects of construction materials nanomodification. Stroitel’nye Materialy [Construction Materials]. 2015. No. 2, pp. 25–33.
19. Hela R., Bodnarova L., Jarolim T., Labaj M. Carbon nanotubes dispersion, concentration, and amount of ultrasound energy required. Stroitel’nye Materialy [Construction Materials]. 2017. No. 1–2, pp. 4–9. DOI: https://doi.org/10.31659/0585-430X-2017-745-1-2-4-9. (In Russian).
20. Stark J., Wicht B. Concrete Durability / Translation from German. RIA Quintet. 1-th ed. 2004. 295 р.
21. Brian B. Hope, Maguid S. Nashidt. Sulphurimpregnated concrete materials. Ontario. 1998, pp. 29–36.
22. Korolev E.V., Proshin A.P., Filippov G.A., Boltyshev S.A., Koroleva O.V., Makarov O.V. Radiatsionnozashchitnye i korrozionno-stoikie sernye stroitel’nye materialy [Radiation protection and corrosion-resistant sulfur building materials]. Moscow: Paleotip. 2004. 464 p.
2. Bobylev Yu.N. The oil sector: the main trends of 2018–2019. Ekonomicheskoe razvitie Rossii. 2019. Vol. 26. No. 3, pp. 13–17. (In Russian).
3. Nagibin G.E., Nazirov R.A., Dobrosmyslov S.S., Fedorova E.N., Zadov V.E., Shevchenko V.A. Binders based on technical sulfur and ash and slag waste. Vyazhushchie na osnove tekhnicheskoi sery i zoloshlakovykh otkhodov Zhurnal Sibirskogo federal’nogo universiteta. Seriya: Tekhnika i tekhnologii. 2013. Vol. 6. No. 6, pp. 689–698. (In Russian).
4. Doshlov O.I., Kalapov I.A. The method of disposal of industrial waste - technical sulfur, using it for road construction. The current state and prospects for improving the environment and life safety of the Baikal region “White Nights 2016”: a collection of articles of the International Scientific and Technical Conference: in 2 volumes. 2016, pp. 281–288. (In Russian).
5. Lichman N.V., Kukharenko L.V., Nikitin I.V. The use of technical sulfur and mining and metallurgical wastes in hydraulic engineering construction. Stroitel’nye Materialy [Construction materials]. 2005. No. 7, pp. 10–13. (In Russian).
6. Lipina A.V. Research of innovative technological methods for utilization of sulfur-containing waste and technical sulfur. Uspekhi sovremennoi nauki i obrazovaniya. 2016. No. 2, pp. 73–76. (In Russian).
7. Doshlov O.I., Kalapov I.A. New road bitumens based on organic binder, modified with technical sulfur and polymer additives. Vestnik Irkutskogo gosudarstvennogo tekhnicheskogo universiteta. 2015. No. 11 (106), pp. 107–111. (In Russian).
8. Gumenyuk A.N., Shevchenko F.E., Zhukov A.N. Universal composition for the modification of building materials on the basis of technical sulfur. In the collection: Innovation Exhibition – 2018 (spring session). Compendium of the XXV Republican exhibitionsession of student innovation projects. 2018, pp. 25–29. (In Russian).
9. N’yat Tkhyui Z.L., Epishkin N.A., Balabanov V.B., Baryshok V.P. High-strength and cold-resistant concretes using technical sulfur. Izvestiya vuzov. Investitsii. Stroitel’stvo. Nedvizhimost’. 2018. Vol. 8. No. 3 (26), pp. 122–129. (In Russian).
10. Gumenyuk A.N., Yakovlev G.I., Polyanskikh I.S., Gordina A.F., Grakhov V.P. Thermoplastic additive of technogenic origin for concrete and mortars. Intellektual’nye sistemy v proizvodstve. 2019. Vol. 17. No. 1, pp. 126–130. (In Russian).
11. Bazhenov Y.M. Betonopolimery [Concrete Polymers]. Moscow: Stroyizdat. 1983. 472 p.
12. Paturoev V.V. Polimerbetony [Polymer concrete] Moscow: Stroyizdat. 1987. 286 p.
13. Mohamed Sassi, Ashwani K. Gupta Sulphur recovery from acid gas using the claus process and high temperature air combustion technology. American Journal of Environmental Sciences. 2008. No. 5, pp. 502–511. DOI: 10.3844/ajessp.2008.502.511
14. Chaudhuri R. G., Paria S. Synthesis of sulfur nanoparticles in aqueous surfactant solutions. Journal of Colloid and Interface Science. 2010. Vol. 343 (2), pp. 439–446. doi: 10.1016/j.jcis.2009.12.004
15. Voronkov M.G., Vyazankin N.S., Deryagina E.N., Nakhmanovich A.S., Usov V.A. Reaktsii sery s organicheskimi soedineniyami [Reactions of sulfur with organic compounds]. Novosibirsk: Nauka. 1979. 352 p.
16. Polyasnkikh I.S., Yakovlev G.I., Gordina A.F., Gumeniuk A.N., Drohitka R., Urhanova L.A. Compositions based on industrial sulfur sol for gypsum materials. 20. Internationale Baustofftagung. Weimar, 2018, pp. 133–146.
17. Korolev E.V., Andreeva O.O., Proshin A.P. Method for determining the mutual solubility of substances in multicomponent systems. Modern problems of building materials science. The Seventh Academic Readings of the RAACS. Belgorod. 2001, pp. 269–273. (In Russian).
18. Khozin V.G., Abdrakhmanova L.А., Nizamov R.К. Common concentration pattern of effects of construction materials nanomodification. Stroitel’nye Materialy [Construction Materials]. 2015. No. 2, pp. 25–33.
19. Hela R., Bodnarova L., Jarolim T., Labaj M. Carbon nanotubes dispersion, concentration, and amount of ultrasound energy required. Stroitel’nye Materialy [Construction Materials]. 2017. No. 1–2, pp. 4–9. DOI: https://doi.org/10.31659/0585-430X-2017-745-1-2-4-9. (In Russian).
20. Stark J., Wicht B. Concrete Durability / Translation from German. RIA Quintet. 1-th ed. 2004. 295 р.
21. Brian B. Hope, Maguid S. Nashidt. Sulphurimpregnated concrete materials. Ontario. 1998, pp. 29–36.
22. Korolev E.V., Proshin A.P., Filippov G.A., Boltyshev S.A., Koroleva O.V., Makarov O.V. Radiatsionnozashchitnye i korrozionno-stoikie sernye stroitel’nye materialy [Radiation protection and corrosion-resistant sulfur building materials]. Moscow: Paleotip. 2004. 464 p.
For citation: Gumeniuk A.N., Polyanskikh I.S., Pervushin G.N., Gordina A.F., Yakovlev G.I., Khazeev D.R. Structuring additive based on production waste for mineral binders. Stroitel’nye Materialy [Construction Materials]. 2019. No. 7, pp. 41–46. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-772-7-41-46