AbstractAbout AuthorsReferences
As part of creating a comfortable and safe environment, constructing energy-efficient residential and industrial buildings and structures that meet modern requirements and standards, the development of the production of environmentally friendly renewable and new individual energy sources is becoming especially relevant. In this regard, there is a need to increase the energy capacity of electrochemical cells. Research has been carried out on the metallized conductive materials creation based on rolled carbon non-woven material “Busofit” with the sequential application of metal coatings of titanium and silver using ion-plasma sputtering and electric pulse dispersion methods. It has been shown that surface layer metallization of the electrode material with titanium can improve the electrochemical cell characteristics. Additional silver film deposition leads to further cell performance improvement. It has been confirmed that the multilayer structure interfacial resistance between the carbon and the current collector has a significant effect on the conductivity of the electrochemical cell and the stability of its operation. The contact area increase of the electrode with the electrolyte leads to an increase in the rate processes occurring on the electrode surface and in the near-electrode space, which opens up prospects for increasing the energy intensity of the electrochemical system. A significant capacity increase of a water-based capacitor structure is achieved by the formation of a nanostructured dielectric layer of potassium titanate in the interelectrode space. It has been confirmed that the cell voltage cycling helps to stabilize the processes occurring in the surface layer of the electrode material at the interface and determining the range of mechanisms for transmitting electrical energy, which makes it possible to achieve higher energy intensity of the samples. Improvement of technological solutions in the field of ion-plasma technologies and the use of new perspective nanostructured materials creates the prerequisites for the creation of advanced automation and energy supply systems with a higher resource, which expands the possibilities of their use in various construction projects.
T.V. REVENOK1, Candidate of Sciences (Chemistry), Assistant Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.);
V.V. SLEPTSOV2, Doctor of Sciences (Engineering), Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
A.O. DITELEVA2, Senior Lecturer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
V.V. SLEPTSOV2, Doctor of Sciences (Engineering), Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
A.O. DITELEVA2, Senior Lecturer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
1 National Research Moscow State University of Civil Engineering (26, Yaroslavskoye Highway, Moscow, 129337, Russian Federation)
2 Moscow Aviation Institute (National Research University) (4, Volokolamskoe Highway, Moscow, 125993, Russian Federation)
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https://doi.org/10.3390/nano13010105
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21. Sleptsov V.V., Kozhitov L.V., Muratov D.G., Popkova A.V., Savkin A.V., Diteleva A.O., Kozlov A.P. Thin film vacuum technologies for a production of highly-capacitive electrolytic capacitors. IOP Publishing: Journal of Physics: Conference Series. 2019. Vol. 1313. 012051. https://doi.org/10.1088/1742-6596/1313/1/012051
22. Varezhnikov A.S., Fedorov F.S., Burmistrov I.N., Plugin I.A., Sommer M., Lashkov A.V., Gorokhovsky A.V., Nasibulin A.G., Kuznetsov D.V., Gorshenkov M.V., Sysoev V.V. The room-temperature chemiresistive properties of potassium titanate whiskers versus organic vapors. Nanomaterials. 2017. Vol. 7. No. 12. 455. https://doi.org/10.3390/nano7120455
23. Yan J., Li S., Lan B., Wu Y., Lee P.S. Rational design of nanostructured electrode materials toward multifunctional supercapacitors. Advanced Functional Materials. 2020. Vol. 30. 1902564. https://doi.org/10.1002/adfm.201902564
https://doi.org/10.1016/j.futures.2016.04.007
2. Kreps B.H. The rising costs of fossil-fuel extraction: An energy crisis that will not go away. American Journal of Economics and Sociology. 2020. Vol. 79, pp. 695–717. https://doi.org/10.1111/ajes.12336
3. Weitzel T., Glock C.H. Energy management for stationary electric energy storage systems: A systematic literature review. European Journal of Operational Research. 2018. Vol. 264, pp. 582–606. https://doi.org/10.1016/j.ejor.2017.06.052
4. Ананьева Е.С., Коршунова Н.Н. Умный дом как новый тип жилья // Строительные материалы и изделия. 2020. Т. 3. № 1. С. 83–88.
4. Ananyeva E.S., Korshunova N.N. Smart home as a new type of housing. Ananyeva E.S., Korshunova N.N. Smart home as a new type of housing. Stroitel’nyye materialy i izdeliya. 2020. Vol. 3. No. 1, pp. 83–88. (In Russian).
5. Kabanov O.V., Panfilov S.A., Kuznetcova E.S., Egorushkina T.N., Ralin A.Y., Lyalin E.A., Sadunova A.G., Vasilevna M.A. Smart house: Apartment opportunities in the next decade. Procedia environmental science, engineering and management. 2022. Vol. 8. No. 4, pp. 939–945. EDN: EHMUON
6. Вольфкович Ю.М. Электрохимические суперконденсаторы (Обзор) // Электрохимия. 2021. Т. 57. № 4. С. 197–238. https://doi.org/10.31857/S0424857021040101 EDN: AWUGYP
6. Volfkovich Yu.M. Electrochemical supercapacitors (Review). Electrokhimiya. 2021. Vol. 57. No. 4, pp. 197–238. (In Russian). https://doi.org/10.31857/S0424857021040101 EDN: AWUGYP
7. Храменкова А.В., Изварин А.И., Финаева О.А., Мощенко В.В., Попов К.М. Гибридные материалы на основе углеродной ткани, модифицированной оксидами переходных металлов, и возможность их использования в качестве электродных материалов для суперконденсаторов // Журнал прикладной химии. 2022. Т. 95. № 4. С. 509–516. https://doi.org/10.31857/S0044461822040120
7. Khramenkova A.V., Izvarin A.I., Finaeva O.A., Moshchenko V.V., Popov K.M. Hybrid materials based on carbon fabric modified with transition metal oxides and the possibility of their use as electrode materials for supercapacitors. Journal of Applied Chemistry. 2022. Vol. 95. No. 4, pp. 509–516. (In Russian). https://doi.org/10.31857/S0044461822040120
8. Gurova O., Sysoev V., Lobiak E., Makarova A., Asanov I., Okotrub A., Kulik L., Bulusheva L. Enhancement of volumetric capacitance of binder-free single-walled carbon nanotube film via fluorination. Nanomateials. 2021. Vol. 11. 1135. https://doi.org/10.3390/nano11051135
9. Ding Y., Tang S., Han R., Zhang S, Pan G., Meng X. Iron oxides nanobelt arrays rooted in nanoporous surface of carbon tube textile as stretchable and robust electrodes for flexible supercapacitors with ultrahigh areal energy density and remarkable cycling-stability. Scientific Reports. 2020. Vol. 10. 11023. https://doi.org/10.1038/s41598-020-68032-z
10. Климонт А.А., Стаханова С.В., Семушкин К.А., Астахов М.В., Калашник А.Т., Галимзянов Р.Р., Кречетов И.С., Кунду М. Содержащие полианилин композиты на основе высокопористой углеродной ткани для гибких электродов-суперконденсаторов // Поверхность. Рентгеновские, синхротронные и нейтронные исследования. 2017. № 9. С. 44–51. https://doi.org/10.7868/S0207352817090074
10. Klimont A.A., Stakhanova S.V., Semushkin K.A., Astakhov M.V., Kalashnik A.T., Galimzyanov R.R., Krechetov I.S., Kundu M. Polyaniline-containing composites based on highly porous carbon fabric for flexible electrodes of supercapacitors. Poverkhnost’. Rentgenovskiye, sinkhrotronnyye i neytronnyye issledovaniya. 2017. No. 9, pp. 44–51. (In Russian). https://doi.org/10.7868/S0207352817090074
11. Wang Y., Li X., Wang Y., Liu Y., Bai Y., Liu R., Yuan G. High-performance flexible MnO2@carbonized cotton textile electrodes for enlarged operating potential window symmetrical supercapacitors. Electrochimica Acta. 2019. Vol. 299, pp. 12–18. https://doi.org/10.1016/j.electacta.2018.12.181
12. Hwang Y.G., Nulu V., Nulu A, Sohn K.Y. Hollow nanostructured NiO particles as an efficient electrode material for lithium-ion energy storage properties. RSC Advances. 2023. Vol. 13, pp. 22007–22016. https://doi.org/10.1039/d3ra03467d
13. Григорьева В.А., Бурашникова М.М. Изучение электрохимических свойств углеродных волокнистых материалов для отрицательного электрода гибридного суперконденсатора с кислотным электролитом // Электрохимическая энергетика. 2022. Т. 22. № 1. С. 21–34 https://doi.org/10.18500/1608-4039-2022-22-1-21-34 EDN: AFYHEY
13. Grigoryeva V.A., Burashnikova M.M. Study of the electrochemical properties of carbon fibrous materials for a negative electrode of a hybrid supercondenser with acid electrolyt. Electrochemical Energetics. 2022. Vol. 22. Iss. 1, pp. 21–34. (In Russian). https://doi.org/10.18500/1608-4039-2022-22-1-21-34 EDN: AFYHEY
14. Бережная А.Г., Чернявина В.В., Гаврикова С.О. Влияние состава электролита на удельную емкость устройств с углеродной тканью «Бусофит» Т-040 // Электрохимическая энергетика. 2020. Т. 20. № 1. С. 33–44. https://doi.org/10.18500/1608-4039-2020-20-1-33-44 EDN: LKVQLE
14. Berezhnaya A.G., Chernyavina V.V., Gavrikova S.O. The influence of electrolyte composition on the specific capacity of devices with carbon fabric “Busofit” T-040. Electrochemical Energetics. 2020. Vol. 20. Iss. 1, pp. 33–44. (In Russian). https://doi.org/10.18500/1608-4039-2020-20-1-33-44 EDN: LKVQLE
15. Dawoud H., Al Tahtamoun T., Bensalah N. Sputtered manganese oxide thin film on carbon nanotubes sheet as a flexible and binder-free electrode for supercapacitors. International Journal of Energy Research. 2019. Vol. 43 (2), pp. 1–10. https://doi.org/10.1002/er.4364
16. Parveen N., Ansari M.O., Ansari S.A., Kumar P. Supercapacitor electrode material. Nanomaterials. 2023. Vol. 13 (1). 105 (1–23).
https://doi.org/10.3390/nano13010105
17. Слепцов В.В., Кукушкин Д.Ю., Дителева А.О. Исследование и развитие вакуумных тонкопленочных нанотехнологий для создания электродных материалов для источников тока // Наукоемкие нанотехнологии. 2021. Т. 22. № 1. С. 65–76.
17. Sleptsov V.V., Kukushkin D.Yu., Diteleva A.O. Research and development of vacuum thin-film nanotechnologies for creating electrode materials for current sources Naukoyemkiye nanotekhnologii. 2021. Vol. 22. No. 1, pp. 65–76. (In Russian).
18. Слепцов В.В., Савкин А.В., Кукушкин Д.У., Дителева А.О. Исследование процесса осаждения нанокластеров металлов на поверхность пористых электродных материалов методом электрофореза // Нанотехнологии. Разработка, применение – XXI век. 2018. Т. 10. № 2. С. 28–32.
18. Sleptsov V.V., Savkin A.V., Kukushkin D.U., Diteleva A.O. Study of the process of deposition of metal nanoclusters on the surface of porous electrode materials by electrophoresis. Nanotekhnologii. Razrabotka, primeneniye – XXI vek. 2018. Vol. 10. No. 2, pp. 28–32. (In Russian).
19. Al-Mishnanah I.M.H., Al-Syadi A.M., Foul A. Evaluation of nanostructured electrode materials for high-performance supercapacitors using multiple-criteria decision-making approach. Electronic Research Archive. 2023. Vol. 31 (4), pp. 2286–2314. https://doi.org/10.3934/era.2023117
20. Bharti Kumar A., Ahmed G., Gupta M., Bocchetta P., Adalati R., Chandra R., Kumar Y. Theories and models of supercapacitors with recent advancements: impact and interpretations. IOP Publishing. Nano Express. 2021. No. 2. 022004. https://doi.org/10.1088/2632-959X/abf8c2
21. Sleptsov V.V., Kozhitov L.V., Muratov D.G., Popkova A.V., Savkin A.V., Diteleva A.O., Kozlov A.P. Thin film vacuum technologies for a production of highly-capacitive electrolytic capacitors. IOP Publishing: Journal of Physics: Conference Series. 2019. Vol. 1313. 012051. https://doi.org/10.1088/1742-6596/1313/1/012051
22. Varezhnikov A.S., Fedorov F.S., Burmistrov I.N., Plugin I.A., Sommer M., Lashkov A.V., Gorokhovsky A.V., Nasibulin A.G., Kuznetsov D.V., Gorshenkov M.V., Sysoev V.V. The room-temperature chemiresistive properties of potassium titanate whiskers versus organic vapors. Nanomaterials. 2017. Vol. 7. No. 12. 455. https://doi.org/10.3390/nano7120455
23. Yan J., Li S., Lan B., Wu Y., Lee P.S. Rational design of nanostructured electrode materials toward multifunctional supercapacitors. Advanced Functional Materials. 2020. Vol. 30. 1902564. https://doi.org/10.1002/adfm.201902564
For citation: Revenok T.V., Sleptsov V.V. Diteleva A.O. Research of electrode materials for the creation of multifunctional current sources with increased capacity as a components of the energy sector of an efficient urban environment. Stroitel'nye Materialy [Construction Materials]. 2024. No. 9, pp. 63–69. (In Russian). https://doi.org/10.31659/0585-430X-2024-828-9-63-69