AbstractAbout AuthorsReferences
Studies of the resistance of concretes based on alkali-alkaline earth binders to carbonation are of significant scientific and practical interest in connection with the development of technologies for reducing the carbon footprint in building materials science. These technologies make it possible to ensure the disposal of industrial waste in construction and reduce the use of Portland cement. The article presents the results of a study of the features of the accelerated carbonation of concrete based on dust removal from the mineral wool production cupola at a carbon dioxide concentration of 10% vol. d. Samples with a water-cement ratio of 0.45, 0.55, 0.60 were tested. An aqueous solution of caustic soda with a concentration of 6 mol/l was used as an alkaline activator. It is established that the carbonation rate of the samples has a damping character and is expressed as a power function of the carbonization depth over time. The results of changes in compressive strength before and after carbonation are presented, showing an increase in residual compressive strength due to the use of a low-base binder. The main product of accelerated carbonation is nahcolite.
P.A. FEDOROV, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
Ufa State Petroleum Technological University (1, Kosmonavtov Sreet, Ufa, 450064, Russian Federation)
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4. Salamanova M.Sh., Ismailova Z.Kh. Industrial experience in the implementation of clinker-free binders of alkaline activation. Vestnik of Dagestan State Technical University. Technical Sciences. 2021. Vol. 48. No. 3, pp. 106–116. (In Russian). https://doi.org/10.21822/2073-6185-2021-48-3-106-116
5. Luo Z., Yang X., Ji H., Zhang C. Carbonation model and prediction of polyvinyl alcohol fiber concrete with fiber length and content effects. International Journal of Concrete Structures and Materials. 2022. Vol. 16. No. 1. https://doi.org/10.1186/s40069-022-00503-1
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10. Novgorodskiy V.I. Osnovy dolgovechnosti zhelezobetonnyh konstrukcij [Basics of durability of reinforced concrete structures]. Moscow: Sputnik+ Publishing House. 2015. 362 p.
11. Longhi M.A., Rodríguez E.D., Walkley B., Zhang Z., Kirchheim A.P. Metakaolin-based geopolymers: Relation between formulation, physicochemical properties and efflorescence formation. Composites Part B: Engineering. 2020. Vol. 182. 107671. https://doi.org/10.1016/j.compositesb.2019.107671
12. Beltrame N.Ap.M., Dias R.L., Witzke F.B., Medeiros-Junior R.A. Effect of carbonation curing on the physical, mechanical, and microstructural properties of metakaolin-based geopolymer concrete. Construction and Building Materials. 2023. Vol. 406. 133403. https://doi.org/10.1016/j.conbuildmat.2023.133403
13. Pasupathy K., Sanjayan J., Rajeev P. Evaluation of alkalinity changes and carbonation of geopolymer concrete exposed to wetting and drying. Journal of Building Engineering. 2021. Vol. 35. 102029. https://doi.org/10.1016/j.jobe.2020.102029
14. Bernal S.A., Provis J.L., Brice D.G., Kilcullen A., Duxson P., Van Deventer J.S.J. Accelerated carbonation testing of alkali-activated binders significantly underestimates service life: The role of pore solution chemistry. Cement and Concrete Research. 2012. Vol. 42. No. 10, pp. 1317–1326. https://doi.org/10.1016/j.cemconres.2012.07.002
15. Khan M.S.H., Castel A., Noushini A. Carbonation of a low-calcium fly ash geopolymer concrete. Magazine of Concrete Research. 2017. Vol. 69. No. 1, pp. 24–34. https://doi.org/10.1680/jmacr.15.00486
16. Fedorov P., Sinitsin D. Alkali-Activated Binder Based on Cupola Dust of Mineral Wool Production with Mechanical Activation. Buildings. 2022. Vol. 12. No. 10. 1565. https://doi.org/10.3390/buildings12101565
17. Хвастунов В.Л., Калашников В.И. Минерально-шлаковые вяжущие и бетоны на их основе. Цементы, бетоны, строительные растворы и сухие смеси. Ч. II: Справочник. СПб.: НПО «Про-фессионал», 2009. C. 118–150.
17. Khvastunov V.L., Kalashnikov V.I. Mineral’no-shlakovye vyazhushchie i betony na ikh osnove. Tsementy, betony, stroitel’nye rastvory i sukhie smesi. Chast’ II: Spravochnik. [Mineral-slag binders and concretes based on them. Cements, concretes, mortars and dry mixtures. Part II: Handbook]. St. Petersburg: NPO «Professional». 2009, pp. 118–150.
18. Глуховский В.Д., Пахомов В.А. Шлакощелочные цементы и бетоны. Киев: Будiвельник, 1978. 184 с.
18. Glukhovskiy V.D., Pakhomov V.A. Shlakoshhelochnye cementy i betony [Slag-alkaline cements and concretes]. Kyiv: Budivelnik, 1978. 184 p.
19. Розенталь Н.К. Коррозионная стойкость цементных бетонов низкой и особо низкой проницаемости. М.: ФГУП ЦПП, 2006. 520 с.
19. Rosenthal N.K. Korrozionnaya stoikost’ tsementnykh betonov nizkoi i osobo nizkoi pronitsaemosti [Corrosion resistance of cement concretes of low and especially low permeability]. Moscow: Federal State Unitary Enterprise TsPP. 2006. 520 p.
20. Алексеев С.Н., Розенталь Н.К. Коррозионная стойкость железобетонных конструкций в агрессивной промышленной среде. М.: Стройиздат, 1976. 205 с.
20. Alekseev S.N., Rosenthal N.K. Korrozionnaya stoikost’ zhelezobetonnykh konstruktsii v agressivnoi promyshlennoi srede [Corrosion resistance of reinforced concrete structures in an aggressive industrial environment]. Moscow: Stroyizdat. 1976. 205 p.
21. Новгородский В.И., Гусева М.М., Мерзляков В.Н. Условия защиты арматуры в бетоне на основе шлакосиликатного вяжущего // Бетон и железобетон. 1976. № 3. C. 21–22.
21. Novgorodsky V.I., Guseva M.M., Merzlyakov V.N. Conditions for the protection of reinforcement in concrete based on slag silicate binder. Beton i zhelezobeton. 1976. No. 3, pp. 21–22. (In Russian).
22. Nguyen T.N., Phung Q.T., Frederickx L., Jacques D., Dauzeres A., Elsen J., Pontikes Y. Microstructural evolution and its impact on the mechanical strength of typical alkali-activated slag subjected to accelerated carbonation. Developments in the Built Environment. 2024. Vol. 19. 100519.
https://doi.org/10.1016/j.dibe.2024.100519
23. Hossain M.M., Karim M.R., Elahi M.M.A., Islam M.N., Zain M.F.M. Long-term durability properties of alkali-activated binders containing slag, fly ash, palm oil fuel ash and rice husk ash. Construction and Building Materials. 2020. Vol. 251. 119094. https://doi.org/10.1016/j.conbuildmat.2020.119094
24. Li Z., Li S. Carbonation resistance of fly ash and blast furnace slag based geopolymer concrete. Construction and Building Materials. 2018. Vol. 163, pp. 668–680. https://doi.org/10.1016/j.conbuildmat.2017.12.127
25. Федоров П.А., Анваров Б.Р., Латыпова Т.В., Анваров А.Р., Латыпов В.М. О математической зависимости, описывающей процесс нейтрализации бетона. Вестник Южно-Уральского государственного университета. Сер.: Строительство и архитектура. 2010. Т. 15. № 191. C. 13–15. EDN: MNJOHT
25. Fedorov P.A., Anvarov B.R., Latypova T.V., Anvarov A.R., Latypov V.M. About the mathematical relationship describing the process of neutralization of concrete. Vestnik of the South Ural State University. Series: Construction and architecture. 2010. Vol. 15. No. 191, pp. 13–15. (In Russian). EDN: MNJOHT
26. Bernal S.A., Provis J.L., Walkley B., San Nicolas R., Gehman J.D., Brice D.G., Kilcullen A.R., Duxson P., Van Deventer J.S.J. Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accelerated carbonation. Cement and Concrete Research. 2013. Vol. 53, pp. 127–144. https://doi.org/10.1016/j.cemconres.2013.06.007
2. Рахимова Н.Р., Рахимов Р.З. XVI Международный конгресс по химии цемента «Дальнейшая декарбонизация и циркуляционное производство и применение цемента и бетона» // Строительные материалы. 2024. № 1–2. C. 95–99. https://doi.org/10.31659/0585-430X-2024-821-1-2-95-99
2. Rakhimova N.R., Rakhimov R.Z. XVI International Congress on Cement Chemistry – “Further Decarbonization and Circular Production and the Use of Cement and Concrete”. Stroitel’nye Materialy [Construction Materials]. 2024. No. 1–2, pp. 95–99. (In Russian). https://doi.org/10.31659/0585-430X-2024-821-1-2-95-99
3. Гаркави М.С., Артамонов А.В., Колодежная Е.В., Дергунов С.А., Сериков С.В. Формирование нано-систем при твердении композиционных цементов центробежно-ударного измельчения // Строительные материалы. 2023. № 3. С. 39–42. https://doi.org/10.31659/0585-430X-2023-811-3-39-42
3. Garkavi M.S., Artamonov A.V., Kolodezhnaya E.V., Dergunov S.A., Serikov S.V. Formation of nanosystems during hardening of composite cements of centrifugal-impact grinding. Stroitel’nye Materialy [Construction Materials]. 2023. No. 3, pp. 39–42. (In Russian). https://doi.org/10.31659/0585-430X-2023-811-3-39-42
4. Саламанова М.Ш., Исмаилова З.Х. Промышлен-ный опыт внедрения бесклинкерных вяжущих щелочной активации // Вестник Дагестанского государственного технического университета. Технические науки. 2021. Т. 48. № 3. C. 106–116. https://doi.org/10.21822/2073-6185-2021-48-3-106-116
4. Salamanova M.Sh., Ismailova Z.Kh. Industrial experience in the implementation of clinker-free binders of alkaline activation. Vestnik of Dagestan State Technical University. Technical Sciences. 2021. Vol. 48. No. 3, pp. 106–116. (In Russian). https://doi.org/10.21822/2073-6185-2021-48-3-106-116
5. Luo Z., Yang X., Ji H., Zhang C. Carbonation model and prediction of polyvinyl alcohol fiber concrete with fiber length and content effects. International Journal of Concrete Structures and Materials. 2022. Vol. 16. No. 1. https://doi.org/10.1186/s40069-022-00503-1
6. Штарк И., Вихт Б. Долговечность бетона. Киев: Оранта, 2004. 301 с.
6. Shtark I., Viht B. Dolgovechnost’ betona [Durability of concrete]. Kyiv: Oranta. 2004. 301 p.
7. Von Greve-Dierfeld S., Lothenbach B., Vollpracht A. et al. Understanding the carbonation of concrete with supplementary cementitious materials: a critical review by RILEM TC 281-CCC. Materials and Structures. 2020. Vol. 53. No. 6. 136. https://doi.org/10.1617/s11527-020-01558-w
8. Zhao C., Li Z., Peng S., Liu J., Wu Q., Xu X. State-of-the-art review of geopolymer concrete carbonation: From impact analysis to model establishment. Case Studies in Construction Materials. 2024. Vol. 20. e03124. https://doi.org/10.1016/j.cscm.2024.e03124
9. Pasupathy K., Berndt M., Castel A., Sanjayan J., Pathmanathan R. Carbonation of a blended slag-fly ash geopolymer concrete in field conditions after 8 years. Construction and Building Materials. 2016. Vol. 125, pp. 661–669. https://doi.org/10.1016/j.conbuildmat.2016.08.078
10. Новгородский В.И. Основы долговечности железобетонных конструкций. М.: Спутник+. 2015. 362 с.
10. Novgorodskiy V.I. Osnovy dolgovechnosti zhelezobetonnyh konstrukcij [Basics of durability of reinforced concrete structures]. Moscow: Sputnik+ Publishing House. 2015. 362 p.
11. Longhi M.A., Rodríguez E.D., Walkley B., Zhang Z., Kirchheim A.P. Metakaolin-based geopolymers: Relation between formulation, physicochemical properties and efflorescence formation. Composites Part B: Engineering. 2020. Vol. 182. 107671. https://doi.org/10.1016/j.compositesb.2019.107671
12. Beltrame N.Ap.M., Dias R.L., Witzke F.B., Medeiros-Junior R.A. Effect of carbonation curing on the physical, mechanical, and microstructural properties of metakaolin-based geopolymer concrete. Construction and Building Materials. 2023. Vol. 406. 133403. https://doi.org/10.1016/j.conbuildmat.2023.133403
13. Pasupathy K., Sanjayan J., Rajeev P. Evaluation of alkalinity changes and carbonation of geopolymer concrete exposed to wetting and drying. Journal of Building Engineering. 2021. Vol. 35. 102029. https://doi.org/10.1016/j.jobe.2020.102029
14. Bernal S.A., Provis J.L., Brice D.G., Kilcullen A., Duxson P., Van Deventer J.S.J. Accelerated carbonation testing of alkali-activated binders significantly underestimates service life: The role of pore solution chemistry. Cement and Concrete Research. 2012. Vol. 42. No. 10, pp. 1317–1326. https://doi.org/10.1016/j.cemconres.2012.07.002
15. Khan M.S.H., Castel A., Noushini A. Carbonation of a low-calcium fly ash geopolymer concrete. Magazine of Concrete Research. 2017. Vol. 69. No. 1, pp. 24–34. https://doi.org/10.1680/jmacr.15.00486
16. Fedorov P., Sinitsin D. Alkali-Activated Binder Based on Cupola Dust of Mineral Wool Production with Mechanical Activation. Buildings. 2022. Vol. 12. No. 10. 1565. https://doi.org/10.3390/buildings12101565
17. Хвастунов В.Л., Калашников В.И. Минерально-шлаковые вяжущие и бетоны на их основе. Цементы, бетоны, строительные растворы и сухие смеси. Ч. II: Справочник. СПб.: НПО «Про-фессионал», 2009. C. 118–150.
17. Khvastunov V.L., Kalashnikov V.I. Mineral’no-shlakovye vyazhushchie i betony na ikh osnove. Tsementy, betony, stroitel’nye rastvory i sukhie smesi. Chast’ II: Spravochnik. [Mineral-slag binders and concretes based on them. Cements, concretes, mortars and dry mixtures. Part II: Handbook]. St. Petersburg: NPO «Professional». 2009, pp. 118–150.
18. Глуховский В.Д., Пахомов В.А. Шлакощелочные цементы и бетоны. Киев: Будiвельник, 1978. 184 с.
18. Glukhovskiy V.D., Pakhomov V.A. Shlakoshhelochnye cementy i betony [Slag-alkaline cements and concretes]. Kyiv: Budivelnik, 1978. 184 p.
19. Розенталь Н.К. Коррозионная стойкость цементных бетонов низкой и особо низкой проницаемости. М.: ФГУП ЦПП, 2006. 520 с.
19. Rosenthal N.K. Korrozionnaya stoikost’ tsementnykh betonov nizkoi i osobo nizkoi pronitsaemosti [Corrosion resistance of cement concretes of low and especially low permeability]. Moscow: Federal State Unitary Enterprise TsPP. 2006. 520 p.
20. Алексеев С.Н., Розенталь Н.К. Коррозионная стойкость железобетонных конструкций в агрессивной промышленной среде. М.: Стройиздат, 1976. 205 с.
20. Alekseev S.N., Rosenthal N.K. Korrozionnaya stoikost’ zhelezobetonnykh konstruktsii v agressivnoi promyshlennoi srede [Corrosion resistance of reinforced concrete structures in an aggressive industrial environment]. Moscow: Stroyizdat. 1976. 205 p.
21. Новгородский В.И., Гусева М.М., Мерзляков В.Н. Условия защиты арматуры в бетоне на основе шлакосиликатного вяжущего // Бетон и железобетон. 1976. № 3. C. 21–22.
21. Novgorodsky V.I., Guseva M.M., Merzlyakov V.N. Conditions for the protection of reinforcement in concrete based on slag silicate binder. Beton i zhelezobeton. 1976. No. 3, pp. 21–22. (In Russian).
22. Nguyen T.N., Phung Q.T., Frederickx L., Jacques D., Dauzeres A., Elsen J., Pontikes Y. Microstructural evolution and its impact on the mechanical strength of typical alkali-activated slag subjected to accelerated carbonation. Developments in the Built Environment. 2024. Vol. 19. 100519.
https://doi.org/10.1016/j.dibe.2024.100519
23. Hossain M.M., Karim M.R., Elahi M.M.A., Islam M.N., Zain M.F.M. Long-term durability properties of alkali-activated binders containing slag, fly ash, palm oil fuel ash and rice husk ash. Construction and Building Materials. 2020. Vol. 251. 119094. https://doi.org/10.1016/j.conbuildmat.2020.119094
24. Li Z., Li S. Carbonation resistance of fly ash and blast furnace slag based geopolymer concrete. Construction and Building Materials. 2018. Vol. 163, pp. 668–680. https://doi.org/10.1016/j.conbuildmat.2017.12.127
25. Федоров П.А., Анваров Б.Р., Латыпова Т.В., Анваров А.Р., Латыпов В.М. О математической зависимости, описывающей процесс нейтрализации бетона. Вестник Южно-Уральского государственного университета. Сер.: Строительство и архитектура. 2010. Т. 15. № 191. C. 13–15. EDN: MNJOHT
25. Fedorov P.A., Anvarov B.R., Latypova T.V., Anvarov A.R., Latypov V.M. About the mathematical relationship describing the process of neutralization of concrete. Vestnik of the South Ural State University. Series: Construction and architecture. 2010. Vol. 15. No. 191, pp. 13–15. (In Russian). EDN: MNJOHT
26. Bernal S.A., Provis J.L., Walkley B., San Nicolas R., Gehman J.D., Brice D.G., Kilcullen A.R., Duxson P., Van Deventer J.S.J. Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accelerated carbonation. Cement and Concrete Research. 2013. Vol. 53, pp. 127–144. https://doi.org/10.1016/j.cemconres.2013.06.007
For citation: Fedorov P.A. Features of accelerated carbonization of concrete based on alkaline-alkaline earth binders. Stroitel'nye Materialy [Construction Materials]. 2024. No. 11, pp. 40–47. (In Russian). https://doi.org/10.31659/0585-430X-2024-830-11-40-47