AbstractAbout AuthorsReferences
Abroad, they are actively engaged in “cold” sintering of materials, including ceramic, which is a mechanically and thermally conditioned mass transfer process that allows for low-temperature integration of various materials. The paper presents the results of research on low-temperature sintering and optimization of firing regimes for ceramic materials by introducing a salt complex with a liquidus temperature of 825оC into a charge based on natural and man-made rocks of the Republic of Tyva. The optimal concentrations of salt-containing additives in the ceramic mass, which affect the roasting properties of the resulting materials, have been determined. It was found that the introduction of a complex of salts into the ceramic charge promotes earlier sintering of the shard and the production of high-quality wall ceramics at lower temperatures, which leads to a reduction in energy costs during firing of products.
G.I. STOROZHENKO1, Doctor of Sciences (Engineering) Docent (This email address is being protected from spambots. You need JavaScript enabled to view it.);
T.V. SAPELKINA2, Research Assistant (This email address is being protected from spambots. You need JavaScript enabled to view it.);
Т.Е. SHOEVA1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
I.M. SEBELEV1, Doctor of Sciences (Engineering), Docent (This email address is being protected from spambots. You need JavaScript enabled to view it.)
T.V. SAPELKINA2, Research Assistant (This email address is being protected from spambots. You need JavaScript enabled to view it.);
Т.Е. SHOEVA1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
I.M. SEBELEV1, Doctor of Sciences (Engineering), Docent (This email address is being protected from spambots. You need JavaScript enabled to view it.)
1 Novosibirsk State University of Architecture and Civil Engineering (Sibstrin) (113, Leningradskaya Street, Novosibirsk, 630008, Russian Federation)
2 Tuva Institute of Integrated Development of Natural Resources, Siberian Branch of the Russian Academy of Sciences (117A, Internatsionalnaya Street, Kyzyl, 667007, Tyva Republic, Russian Federation)
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4. Яценко Н.Д., Вильбицкая Н.А., Яценко А.И. Особенности формирования фазового состава и свойств высококальциевой низкоплотной керамики на основе глинистого сырья различного химико-минералогического состава // Известия высших учебных заведений. Северо-Кавказский регион. Сер.: Технические науки. 2021. № 2. С. 75–80. https://doi.org/10.17213/1560-3644-2021-2-75-80
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5. Довженко И.Г. Интенсификация спекания керамического кирпича с применением побочного продукта алюминиевого производства // Фундаменталь-ные исследования. 2011. № 12 (2). С. 341–344. https://fundamental-research.ru/ru/article/view?id=29085
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6. Стороженко Г.И. Технология производства изделий стеновой керамики из активированного глинистого сырья: Дис. … д-ра техн. наук. Томск, 2000. 231 с.
6. Storozhenko G.I. Technology for the production of wall ceramic products from activated clay raw materials. Diss. Doc. (Engineering). Tomsk. 2000. 231 p. (In Russian).
7. Кара-Сал Б.К. Керамические строительные материалы, полученные обжигом при пониженном давлении (технология, структура и свойства): Дис. … д-ра техн. наук. Новосибирск, 2007. 307 с.
7. Kara-Sal B.K. Ceramic building materials obtained by firing at reduced pressure (technology, structure and properties). Diss. Doc. (Engineering). Novosibirsk. 2007. 307 p. (In Russian).
8. Курносов В.В., Тихонова В.Р. Колпаковая печь – универсальный агрегат для обжига керамики // Строительные материалы. 2023. № 5. С. 48–52. https://doi.org/10.31659/0585-430X-2023-813-5-48-52
8. Kurnosov V.V., Tihonova V.R. Hood furnace – universal unit for burning ceramics. Stroitel’nye Materialy [Construction Materials]. 2023. No. 5, pp. 48–52. (In Russian). https://doi.org/10.31659/0585-430X-2023-813-5-48-52
9. Biesuz M., Saunders T.G., Grasso S., Speranza G., Sorarù G.D., Campostrini R., Sglavo V.M., Reece M.J. Flash joining of conductive ceramics in a few seconds by flash spark plasma sintering. Journal of the European Ceramic Society. 2019. Vol. 39. Iss. 15, pp. 4664–4672 https://doi.org/10.1016/j.jeurceramsoc.2019.07.036
10. Guo J., Floyd R., Lowum S., Maria J.-P., Beauvoir T.H., Seo J.-H., Randall C.A. Cold sintering: progress, challenges, and future opportunities. Annual Review of Materials Research. 2019. Vol. 49. No. 7, pp. 275–295. https://doi.org/10.1146/annurev-matsci-070218-010041
11. Galota A., Sglavo V.M. The cold sintering process: A review on processing features, densification mechanisms and perspectives. Journal of the European Ceramic Society. 2021. Vol. 41. No. 9, pp. 1–17. https://doi.org/10.1016/j.jeurceramsoc.2021.09.024
12. Grasso S., Biesuz M., Zoli L., Taveri G., Duff A.I., Ke D., Jiang A., Reece M.J. A review of cold sintering processes. Advances in Applied Ceramics. 2020. Vol. 119, No. 1, pp. 115–143.
http://dx.doi.org/10.1080/17436753.2019.1706825
13. Guo H., Baker A., Guo J., Randall C.A. Cold sintering process: A novel technique for low-temperature ceramic processing of ferroelectrics. Journal American Ceramic Society. 2016. Vol. 99. No. 11, pp. 3489–3507. https://doi.org/10.1111/jace.14554
14. Rowe J.J., Morey G.W., Zen C.S. The quinary reciprocal salt system Na, K, Mg, Ca/Cl, SO4; a review of the literature with new data. Washington: united states government printing office, 1972. 37 p. https://pubs.usgs.gov/pp/0741/report.pdf
1. On the approval of the Information and Technical Handbook on the best available technologies «Production of ceramic products.» ITS 4-2023. Moscow: GTC. 2023. 368 p. (In Russian).
2. Шишакина О.А., Паламарчук А.А. Применение плавней в производстве керамических материалов // Международный журнал прикладных и фундаментальных исследований. 2019. № 11. С. 105–109.
2. Shishakina O.A., Palamarchuk A.A. Application of fluxes in the production of ceramic materials. Mezhdunarodnyy zhurnal prikladnykh i fundamental’nykh issledovaniy. 2019. No. 11, pp. 105–109. (In Russian).
3. Гурьева В.А., Дубинецкий В.В., Вдовин К М., Бутримова Н.В. Стеновая керамика на основе высококальцинированного сырья Оренбуржья // Строительные материалы. 2016. № 12. С. 55–58.
3. Gurieva V.A., Dubinetskiy V.V., Vdovin K.M., Butrimova N.V. Wall ceramic on the basis of highly calcined raw materials of Orenburzhye. Stroitel’nye materialy [Construction Materials]. 2016. No. 12, pp. 55–58. (In Russian).
4. Яценко Н.Д., Вильбицкая Н.А., Яценко А.И. Особенности формирования фазового состава и свойств высококальциевой низкоплотной керамики на основе глинистого сырья различного химико-минералогического состава // Известия высших учебных заведений. Северо-Кавказский регион. Сер.: Технические науки. 2021. № 2. С. 75–80. https://doi.org/10.17213/1560-3644-2021-2-75-80
4. Yatsenko N.D., Vilbitskaya N.A., Yatsenko A.I. Features of the formation of the phase composition and properties of high-calcium low-density ceramics based on clay raw materials of various chemical and mineralogical composition. Izvestiya of higher educational institutions. North Caucasian region. Series: Technical sciences. 2021. No. 2 (210), pp. 75–80. (In Russian). https://doi.org/10.17213/1560-3644-2021-2-75-80
5. Довженко И.Г. Интенсификация спекания керамического кирпича с применением побочного продукта алюминиевого производства // Фундаменталь-ные исследования. 2011. № 12 (2). С. 341–344. https://fundamental-research.ru/ru/article/view?id=29085
5. Dovzhenko I.G. Intensification of agglomeration of ceramic brick with application of the waste of aluminium manufacture. Fundamental’nye issledovaniya. 2011. No. 12 (2), pp. 341–344. (In Russian). https://fundamental-research.ru/ru/article/view?id=29085
6. Стороженко Г.И. Технология производства изделий стеновой керамики из активированного глинистого сырья: Дис. … д-ра техн. наук. Томск, 2000. 231 с.
6. Storozhenko G.I. Technology for the production of wall ceramic products from activated clay raw materials. Diss. Doc. (Engineering). Tomsk. 2000. 231 p. (In Russian).
7. Кара-Сал Б.К. Керамические строительные материалы, полученные обжигом при пониженном давлении (технология, структура и свойства): Дис. … д-ра техн. наук. Новосибирск, 2007. 307 с.
7. Kara-Sal B.K. Ceramic building materials obtained by firing at reduced pressure (technology, structure and properties). Diss. Doc. (Engineering). Novosibirsk. 2007. 307 p. (In Russian).
8. Курносов В.В., Тихонова В.Р. Колпаковая печь – универсальный агрегат для обжига керамики // Строительные материалы. 2023. № 5. С. 48–52. https://doi.org/10.31659/0585-430X-2023-813-5-48-52
8. Kurnosov V.V., Tihonova V.R. Hood furnace – universal unit for burning ceramics. Stroitel’nye Materialy [Construction Materials]. 2023. No. 5, pp. 48–52. (In Russian). https://doi.org/10.31659/0585-430X-2023-813-5-48-52
9. Biesuz M., Saunders T.G., Grasso S., Speranza G., Sorarù G.D., Campostrini R., Sglavo V.M., Reece M.J. Flash joining of conductive ceramics in a few seconds by flash spark plasma sintering. Journal of the European Ceramic Society. 2019. Vol. 39. Iss. 15, pp. 4664–4672 https://doi.org/10.1016/j.jeurceramsoc.2019.07.036
10. Guo J., Floyd R., Lowum S., Maria J.-P., Beauvoir T.H., Seo J.-H., Randall C.A. Cold sintering: progress, challenges, and future opportunities. Annual Review of Materials Research. 2019. Vol. 49. No. 7, pp. 275–295. https://doi.org/10.1146/annurev-matsci-070218-010041
11. Galota A., Sglavo V.M. The cold sintering process: A review on processing features, densification mechanisms and perspectives. Journal of the European Ceramic Society. 2021. Vol. 41. No. 9, pp. 1–17. https://doi.org/10.1016/j.jeurceramsoc.2021.09.024
12. Grasso S., Biesuz M., Zoli L., Taveri G., Duff A.I., Ke D., Jiang A., Reece M.J. A review of cold sintering processes. Advances in Applied Ceramics. 2020. Vol. 119, No. 1, pp. 115–143.
http://dx.doi.org/10.1080/17436753.2019.1706825
13. Guo H., Baker A., Guo J., Randall C.A. Cold sintering process: A novel technique for low-temperature ceramic processing of ferroelectrics. Journal American Ceramic Society. 2016. Vol. 99. No. 11, pp. 3489–3507. https://doi.org/10.1111/jace.14554
14. Rowe J.J., Morey G.W., Zen C.S. The quinary reciprocal salt system Na, K, Mg, Ca/Cl, SO4; a review of the literature with new data. Washington: united states government printing office, 1972. 37 p. https://pubs.usgs.gov/pp/0741/report.pdf
For citation: Storozhenko G.I., Sapelkina T.V., Shoeva T.E., Sebelev I.M. Ceramic materials of low-temperature sintering from natural and technogenic rocks of the Tuva Republic. Stroitel'nye Materialy [Construction Materials]. 2024. No. 9, pp. 11–15. (In Russian). https://doi.org/10.31659/0585-430X-2024-828-9-11-15