The Effect of Technological Additives on the Structure of Foam Glass

Number of journal: 4-2022
Autors:

Grushko I.S.

DOI: https://doi.org/10.31659/0585-430X-2022-801-4-44-48
УДК: 666.189.3

 

AbstractAbout AuthorsReferences
The set of properties of foam glass provides the possibility of its use in many sectors of the national economy. Despite a fairly large number of publications devoted to foam glass, the issues of its structure have not been sufficiently studied. The issues of the kinetics of the foaming process of foam glass, the charge compositions of which are differently predisposed to crystallization, as well as the creation of foam glass with specified properties, depending on the conditions of its synthesis, are little studied. The purpose of this work is to study the effect of technological additives on the structure of foam glass. 9 compositions of foam glass, the main components of which are cullet, ash-slag mixture, are considered. Sodium tetraborate, technical chalk were used as technological additives; chromium oxide, zirconium dioxide, magnesium oxide were used as initiators of crystallization, anthracite was used as a gas–forming agent. The synthesized samples were studied using microtomographic analysis, the calculation and analysis of microtomographic porosity was carried out, the total and closed porosity, histograms of the distribution of the pure volume by quantity were calculated, the distribution patterns of the substance, the densest inclusions and pores in the volume are visualized. The mechanism of volumetric crystallization of glass, characterized by chemical differentiation of glass, causing heterogeneity of its structure, is shown. The results are a sequential stage in a series of studies aimed at solving the problem of developing a technology for designing building materials with the use of ash and slag waste from various thermal power plants.
I.S. GRUSHKO1,2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 Don State Technical University (1, 344000, Gagarina Square., Rostov-on-Don, Russian Federation)
2 Platov South-Russian State Polytechnic University (132, Prosvjaschenija Street, Novocherkassk, 346428, Russian Federation)

1. Lebullenger R., Chenu S., Rocherullé J. et al. Glass foams for environmental applications. Journal of Non-Crystalline Solids. 2010. Vol. 356. Iss. 44–49, pp. 2562–2568. https://doi.org/10.1016/j.jnoncrysol.2010.04.050
2. Taurino R., Lancellotti I., Barbieri L., Leonelli C. Glass-ceramic foams from borosilicate glass waste. International Journal of Applied Glass Science. 2014. Vol. 5. Iss. 2, pp. 136–145. https://doi.org/10.1111/ijag.12069
3. Xu B., Liang K. M., Cao J. W., Li Y. H. Preparation of foam glass ceramics from phosphorus slag. Advanced Materials Research. 6th China International Conference on HighPerformance Ceramics, CICC-6. Harbin, China. 2009. Vol. 105–106. Iss. 1. 2010, pp. 600–603.
4. Puchka O.V., Sergeev S.V., Weisser S.S., Kalashnikov N.V. Highly efficient heat-insulating materials based on technogenic raw materials. Vestnik BSTU named after V.G. Shuhov. 2013. No. 2, pp. 51–55. (In Russian).
5. Kazmina O.V., Kuznetsova N.A. Obtaining a highly efficient heat-insulating building material based on ash and slag waste of thermal power plants. Ogneupory i tehnicheskaja keramika. 2012. No. 1–2, pp. 78–82. (In Russian).
6. Rawlings R.D., Wu J.P., Boccaccini A.R. Glass-ceamics: Their production from wastes-A Review. Journal of Materials Science. 2006. Vol. 41, Iss. 3, pp. 733–761. https://doi.org/10.1007/s10853-006-6554-3
7. Kolekova A.V., Rachinskaya M.P. Foam glass and its use in Russia. Sovremennie nauchnie issledovanija i innovacii. 2012. No. 5 (13), p.  8. (In Russian).
8. Minko N.I., Puchka O.V., Evtushenko E.I., Nartsev V.M., Sergeev S.V. Foam glass – a modern effective inorganic thermal insulation material. Fundamental’nie issledovanija. 2013. No. 64, pp. 849–854. (In Russian).
9. Fedosov S.V., Bakanov M.O., Nikishov S.N. The main principles of the technology for producing heat-insulating foam glass, modeling approaches. Collection “Effective building composites” Scientific and practical conference dedicated to the 85th anniversary of the Honored Scientist of the Russian Federation, Academician of the RAACS, Doctor of Technical Sciences Yury Mikhailovich Bazhenov. Belgorod. 2015, pp. 690–699. (In Russian).
10. Qu Y.-N. et al. Lightweight and high-strength glass foams prepared by a novel green spheres hollowing technique. Ceramics International. 2016. Vol. 42. Iss. 2, pp. 2370–2377. doi: 10.1016/j.ceramint.2015.10.034
11. Damdinova D.R., Pavlov V.E., Khardaev P.K., Druzhinin D.K., Vtorushin N.S., Batorova I.Yu. Composition influence on the structure and properties of foam glass using ash and slag waste from thermal power plants. Nauchnoe obozrenie. 2016. No. 10, pp. 47–55. (In Russian).
12. Puchka O.V., Lesovik V.S., Weisser S.S. Use of glass composites for construction in the Arctic. Intelligent building composites for green building: collection of reports of the international scientific and practical conference dedicated to the 70th anniversary of V.S. Lesovik: in 3 parts. Belgorod. 2016, pp. 29–36. (In Russian).
13. Grushko I., Skibin G., Druzhinina E. Substantiation and design of compositions of heat-insulating material (foam glass) using recyclable resources. Stroitel’stvo i tekhnogennaja bezopasnost’. 2019. No. 15 (67), pp. 87–100. (In Russian).
14. Lázár M., Hnatko M., Sedláček J., Čarnogurská M., Brestovič T. Upgrading the glassy slag from waste disposal by thermal plasma treatment. Waste Management. 2018. Vol. 78, pp. 173–182. DOI: 10.1016/j.wasman.2018.05.042
15. Li J., Zhuang X., Querol X., Font O., Moreno N. A review on the applications of coal combustion products in China. International Geology Review. 2018. Vol. 60. Iss. 5–6, pp. 671–716. https://doi.org/10.1080/00206814.2017.1309997

For citation: Grushko I.S. The effect of technological additives on the structure of foam glass. Stroitel’nye Materialy [Construction Materials]. 2022. No. 4, pp. 44–48. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2022-801-4-44-48


Print   Email