Gypsum Materials Modified with Complex Additive Based on Nanosilica

Number of journal: 4-2022
Autors:

Batova М.D.,
Zhukova N.S.,
Gordina А.F.,
Yakovlev G.I.,
Shaibadullina A.V.,
Elrefai А.E.М.М.,
Orban Z.

DOI: https://doi.org/10.31659/0585-430X-2022-801-4-64-71
УДК: 666.914

 

AbstractAbout AuthorsReferences
In the article the results of using nanosilica and active mineral admixture for gypsum binder and their effect on structure formation are represented. In order to improve properties of additives nanosilica has been undergo by ultrasonic treatment. It was confirmed that the effect of ultrasonic treatment allowed the usage of nanosilica to be a key component for additives and there was no relation between initial particle size and that effect. The activated complex additive positively influences the mechanical properties of the material and this influence is being observed from hydration process till the hardening. Having used activated complex additive has resulted in 40% increase of compressive strength for gypsum binder. Both Portland cement and nanosilica lead to changes in the matrix composition. The changed matrix is characterized by higher density and compressive strength. This result is due to formation of new growths based on hydrated calcium silicate that may bond together gypsum crystals and fill voids at the same time. New growths based on hydrated calcium silicate had been identified by physical and chemical analysis methods, including IR spectral and differential thermal analysis, scanning electron microscopy, and energy dispersive X-ray spectroscopy.
М.D. BATOVA1, Master student (This email address is being protected from spambots. You need JavaScript enabled to view it.),
N.S. ZHUKOVA1, Engineer (postgraduate) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
A.F. GORDINA1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
G.I. YAKOVLEV1, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
A.V. SHAIBADULLINA1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.);
А.E.М.М. ELREFAI2, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.);
Z. ORBAN3, PhD, Director of Engineering and Smart Technology Institute (This email address is being protected from spambots. You need JavaScript enabled to view it.)

1 Kalashnikov Izhevsk State Technical University (7, Studencheskaya Street, Izhevsk, 426000, Russian Federation)
2 Egyptian-Russian University (11829, Cairo-Suez road, Badr City, Cairo, Egypt)
3 University of Pecs (H-7622 Pécs, Vasvári Pál u. 4)

1. Gaitova A.R., Akhmadulina I.I., Pechenkina T.V., Pudovkin A.N., Nedoseko I.V. Nanostructural aspects of hydration and hardening of gypsum and gypsum slag compositions based on two-water gypsum. Stroitel’nye Materialy [Construction Materials]. 2014. No. 1–2, pp. 46–51. (In Russian).
2. Morsy M.S., Alsayed S.H., Salloum Y.A. Development of eco-friendly binder using metakaolin-fly ash-lime-anhydrous gypsum. Construction and Building Materials. 2012. No. 35. DOI: https://doi.org/10.1016/j.conbuildmat.2012.04.142.
3. Katulskaya A.S., Parfenova L.M. Complex mineral additive based on industrial waste for gypsum binder. Vestnik Polotskogo gosudarstvennogo universiteta. 2019. No. 16, pp. 24–29. (In Russian).
4. Starostina I.V., Efremov R.O., Porozhnyuk E.V. [and others]. Use of silica-containing industrial wastes in the technology of composite gypsum binders. Vestnik Tekhnologicheskogo universiteta. 2016. Vol. 19. No. 13, pp. 178–181. (In Russian).
5. Khaliullin M.I., Rakhimov R.Z., Gayfullin A.R. The composition and structure of the stone of the composite gypsum binder with lime additives and ground ceramite dust. Vestnik MGSU. 2013. No. 12, pp. 109–117. (In Russian).
6. Escalante-Garcia J.I., Martínez-Aguilar O.A., Gomez-Zamorano L.Y. Calcium sulphate anhydrite based composite binders; effect of Portland cement and four pozzolans on the hydration and strength. Cement and Concrete Composites. 2017. No. 82, pp. 227–233. DOI: https://doi.org/10.1016/j.cemconcomp.2017.05.012
7. Kondratieva N., Barre M., Goutenoire F., Sanytsky M. Study of modified gypsum binder. Construction and Building Materials. 2017. No. 149, pp. 535–542. DOI: https://doi.org/10.1016/j.conbuildmat.2017.05.140
8. Salamanova M.Sh., Okueva P.Kh., Movsulov M.M., Magomadov Kh.A. Development of the formulation of gypsum compositions based on mineral silica additive. Ustoichivoe razvitie nauki i obrazovaniya. 2017. No. 8. pp. 131–135. (In Russian).
9. Voitovich E.V., Cherevatova A.V. Nanostructured composite plaster binder – a new generation binder. Vestnik of Belgorod State Technical University named after V.G. Shukhova. 2010. No. 3, pp. 32–34. (In Russian).
10. Berdov G.I., Mashkin N.A. Promising directions of improvement of compositions and technology of building materials based on mineral binders. Izvestiya vysshikh uchebnykh zavedenii. Stroitel’stvo. 2015. No. 4 (676), pp. 45–57. (In Russian).
11. Tobón J.I., Payá J., Restrepo O.J. Study of durability of Portland cement mortars blended with silica nanoparticles. Construction and Building Materials. 2015. No. 80. pp. 92–97. DOI: https://doi.org/10.1016/j.conbuildmat.2014.12.074
12. Stucchi N.M.E., Tesser E., Zaccariello G., Antonelli F., Benedetti A. Evaluating two nanosilica dimensional range for the consolidation of degraded silicate stones. Construction and Building Materials. 2022. No. 329. 127191. DOI: https://doi.org/10.1016/j.conbuildmat.2022.127191
13. Munkhtuvshin D., Balabanov V.B., Putsenko K.N. Experience in the use of micro- and nanosilicon additives from silicon waste in concrete technologies. Izvestiya vuzov. Investitsii. Stroitel’stvo. Nedvizhimost’. 2017. Vol. 7. No. 3 (22), pp. 107–115. (In Russian).
14. Raheem A.A., Abdulwahab R., Kareem M.A. Incorporation of metakaolin and nanosilica in blended cement mortar and concrete- A review. Journal of Cleaner Production. 2021. No. 290. 125852. DOI: https://doi.org/10.1016/j.jclepro.2021.125852
15. Varisha, Zaheer M.M., Hasan S.D. Mechanical and durability performance of carbon nanotubes (CNTs) and nanosilica (NS) admixed cement mortar. Materials Today: Proceedings. 2021. No. 42, pp. 1422–1431. DOI: https://doi.org/10.1016/j.matpr.2021.01.151
16. Baldi-Sevilla A., Montero M.L., Aguiar J.P., Loría L.G. Influence of nanosilica and diatomite on the physicochemical and mechanical properties of binder at unaged and oxidized conditions. Construction and Building Materials. 2016. No. 127, pp. 176–182. DOI: https://doi.org/10.1016/j.conbuildmat.2016.09.140
17. Ezzat H., El-Badawy S., Gabr A., Zaki E.-S.I., Breakah T. Evaluation of asphalt binders modified with nanoclay and nanosilica. Procedia Engineering. 2016. No. 143, pp. 1260–1267. DOI: https://doi.org/10.1016/j.proeng.2016.06.119
18. Chen P., Ma B., Tan H., Su Y., Jin Z., Liu X., Wu L. Effect of tricalcium aluminate and nano silica on performance of hemihydrate gypsum. Construction and Building Materials. 2022. No. 321. 126362. DOI: https://doi.org/10.1016/j.conbuildmat.2022.126362
19. Potapov V.V., Gorev D.S. Comparative results of increasing the strength of concrete by introducing nanosilicon and microsilicon. Sovremennye naukoemkie tekhnologii. 2018. No. 9, pp. 98–102. (In Russian).
20. Sagdatullin D.G. High-strength gypsum cement-puzzolan binder Diss… Candidate of Sciences (Engineering). Kazan. 2010. 120 p. (In Russian).
21. Isotov V.S., Mukhametrakhimov R.Kh., Galautdi-nov A.R. Study of the effect of active mineral additives on the rheological and physical-mechanical properties of gypsum-cement-puzzolan binder. Stroitel’nye Materialy [Construction Materials]. 2015. No. 5, pp. 20–23. (In Russian).
22. Batova M.D., Semenova Yu.A., Gordina A.F. Modification of calcium sulphate-based binders with fine mineral additives. Collection of materials of the XXIX Republican Exhibition-Session of Student Innovation Projects and the Forum of Scientific and Technical Creativity of Youth OA «IEMZ «Kupol» «Innovation Exhibition – 2020 (spring session)». 2020, pp. 58–61. (In Russian).
23. Batova М.D., Semenova Yu.А., Gordina А.F., Yakovlev G.I., Elrefai А.E.М.М., Saidova Z.S., Khazeev D.R. Сomplex mineral additives for the modification of calcium sulphate based materials. Stroitel’nye Materialy [Construction Materials]. 2021. No. 1–2, pp. 13–21. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2021-788-1-2-13-21

For citation: Batova М.D., Zhukova N.S., Gordina А.F., Yakovlev G.I., Shaibadullina A.V., Elrefai А.E.М.М., Orban Z. Gypsum materials modified with complex additive based on nanosilica. Stroitel’nye Materialy [Construction Materials]. 2022. No. 4, pp. 64–71. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2022-801-4-64-71


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