AbstractAbout AuthorsReferences
The study focuses on the mechanical properties and structure of a binder based on natural anhydrite in the presence of an aqueous dispersion of carbon particles: industrial soot and isostatic graphite. Granulometric analysis shows that soot particles have higher dispersion compared to graphite, the main range for soot particles being from 50 to 500 nm. The use of soot in the form of tinting paste and graphite, a production waste, provides an increase in mechanical properties up to 25% with an optimal content of additive of 0.001% and 0.005%, respectively. The analysis of the results of the samples with the addition of soot obtained by differential scanning calorimetry and IR analysis shows the presence of changes in the environment of crystalline hydrate structures. The microstructural analysis has revealed the presence of both homogeneous and heterogeneous parts of the structure of gypsum stone. At the same time, the study has established the presence of orderly accumulation of well-formed and closely packed crystals of calcium sulfate dihydrate, presumably over the surface of soot particles, the presence of crystals with concave surfaces, and the presence of tight contacts between crystals which increase the density of the interfacial surface and the strength of the anhydrite matrix. Adding a plasticizer to the composition of anhydrite binder in an amount of 0.8% along with soot provides an increase of up to 45% in the late stages of hardening and a significant decrease in the early stages of hardening.
Yu.V. TOKAREV, Candidate of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
M.A. VOLKOV, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
A.V. AGEEV, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
N.V. KUZMINA, Engineer (postgraduate) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
V.P. GRAKHOV, Doctor of Science (Economics) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
G.I. YAKOVLEV, Doctor of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
D.R. KHAZEEV, Candidate of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
M.A. VOLKOV, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
A.V. AGEEV, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
N.V. KUZMINA, Engineer (postgraduate) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
V.P. GRAKHOV, Doctor of Science (Economics) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
G.I. YAKOVLEV, Doctor of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
D.R. KHAZEEV, Candidate of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
Kalashnikov Izhevsk State Technical University (7, Studencheskaya Street, Izhevsk, 426069, Russian Federation)
1. Sedaghatdoost A., Behfarnia K. Mechanical properties of Portland cement mortar containing multiwalled carbon nanotubes at elevated temperatures. Construction and Building Materials. 2018. Vol. 176, pp. 482–489. https://doi.org/10.1016/j.conbuildmat.2018.05.095
2. Letenko D.G., Mokrova M.V., Matveeva L.Yu., Tikhonov Yu.M. The influence of the size distribution of nanomodified latex particles on the structure of gypsum materials // Vestnik grazhdanskikh inzhenerov. 2019. No. 4 (75), pp. 95–101. (In Russian).
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5. R.A. e Silva, P. de Castro Guetti, M.S. da Luz, F. Rouxinol, R. Valentim Gelamo. Enhanced properties of cement mortars with multilayer graphene nanoparticles. Construction and Building Materials. 2017. Vol. 149, pp. 378–385. https://doi.org/10.1016/j.conbuildmat.2017.05.146
6. Liu Ji., Fu Ji., Yang Ya., Gu Ch. Study on dispersion, mechanical and microstructure properties of cement paste incorporating graphene sheets. Construction and Building Materials. 2019. Vol. 199, pp. 1–11. https:// doi.org/10.1016/j.conbuildmat.2018.12.006
7. Ho V.D., Ng Ching-Tai, Coghlan C.J., Goodwin A., Mc Guckin C., Ozbakkaloglu T., Losic D. Electrochemically produced graphene with ultra large particles enhances mechanical properties of Portland cement mortar. Construction and Building Materials. 2020. Vol. 234. 117403. https://doi.org/10.1016/j.conbuildmat.2019.117403
8. Zadneprovskii R.P. On the effectiveness and prospects of using nanocarbon microadditives for building mixtures. Stroitel’nye materialy, oborudovanie, tekhnologii XXI veka. 2011. No. 8 (151), pp. 22–25. (In Russian).
9. Gyul’misaryan T.G., Kapustin V.M. Dispersion systems – the main raw material for the production of carbon black. Neftekhimiya. 2016. Vol. 56. No. 4, p. 346. (In Russian).
10. Kozlov A.N., Yurlov A.S. Physico-chemical properties, composition and structure of soot particles. Aktual’nye voprosy sovershenstvovaniya tekhnologii proizvodstva i pererabotki produktsii sel’skogo khozyaistva. 2017. No. 19, pp. 341–346. (In Russian).
11. Bulgakov B.I., Tang V.L., Aleksandrova O.V. The influence of nanosized soot particles on the strength of cement stone at an early age. Vestnik Belgorodskogo gosudarstvennogo tekhnologicheskogo universiteta im. V.G. Shukhova. 2016. No. 11, pp. 18–22. (In Russian).
12. Ignatova O.A., Makarova N.V. The effect of ultrafine soot pigment additives on the properties of gypsum-cementpozzolanic binder. Izvestiya vysshikh uchebnykh zavedenii. Stroitel’stvo. 2017. No. 11–12 (707–708), pp. 31–41. (In Russian).
13. Yakovlev G.I., Pervushin G.N., Gordina A.F., Shaibadulina A.V., Saidova Z.S., Protod’yakonova T.L., Bur’yanov A.F., Nikitina S.V. Modification of the structure and properties of gypsum binder by dispersion of technical soot. Intellektual’nye sistemy v proizvodstve. 2019. Vol. 17. No. 1, pp. 138–143. (In Russian).
14. Sultanova V.M., Pudov I.A. Study of the effect of graphite on the properties of gypsum binder. Nauka, obrazovanie i kul’tura. 2019. No. 5 (39), pp. 5–9. (In Russian).
15. M. del Mar Barbero-Barrera, N. Flores-Medina, V. Perez-Villar. Assessment of thermal performance of gypsum-based composites with revalorized graphite filler. Construction and Building Materials. 2017. Vol. 142, pp. 83–91. https://doi.org/10.1016/j.conbuildmat.2017.03.060
16. Medina N.F., Barbero-Barrera M.M., Bustamante R. Improvement of the properties of gypsum-based composites with recycled isostatic graphite powder from the milling production of molds for Electrical Discharge Machining (EDM) used as a new filler. Construction and Building Materials. 2016. Vol. 107. 2016, pp. 17–27. DOI: 10.1016/j.conbuildmat.2015.12.194
17. Barbero-Barrera M.M., Medina N.F., GuardiaMartin C. Influence of the addition of waste graphite powder on the physical and microstructural performance of hydraulic lime pastes. Construction and Building Materials. 2017. Vol. 149, pp. 599–611. https://doi.org/10.1016/j.conbuildmat.2017.05.156
18. Medina N.F., Barbero-Barrera M.M., Jove-Sandoval F. Improvement of the mechanical and physical properties of cement pastes and mortars through the addition isostatic graphite. Construction and Building Materials. 2018. Vol. 189, pp. 898–905. https://doi.org/10.1016/j.conbuildmat.2018.09.055
19. Tokarev Yu.V., Ageev A.V., Volkov M.A., Kuzmina N.V., Yakovlev G.I. Properties and structure of anhydrite binder of Ergachinsky deposit in the presence of phosphate activators and aleurolite. Stroitel’nye Materialy [Construction Materials]. 2019. No. 10, pp. 46–52. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-775-10-46-52
20. Yakovlev G.I., Fedorova G.D., Polyanskikh I.S. High strength concrete with dispersed additives. Promyshlennoe i grazhdanskoe stroitel’stvo. 2017. No. 2, pp. 35–42. (In Russian).
21. Levashova A.K., Sycheva L.I. The effect of the nature of the plasticizer on the properties of anhydrite binder. Uspekhi v khimii i khimicheskoi tekhnologii. 2016. Vol. 30. No. 7 (176), pp. 58–60. (In Russian).
2. Letenko D.G., Mokrova M.V., Matveeva L.Yu., Tikhonov Yu.M. The influence of the size distribution of nanomodified latex particles on the structure of gypsum materials // Vestnik grazhdanskikh inzhenerov. 2019. No. 4 (75), pp. 95–101. (In Russian).
3. Derevyanko V.N., Chumak A.G., Vaganov V.E. The effect of nanoparticles on hydration processes of semiaquatic gypsum. Stroitel’nye Materialy [Construction Materials]. 2014. No. 7, pp. 22–24. (In Russian).
4. Alatawna A., Birenboim M., Nadiv R., Buzaglo M., Peretz-Damari S., Peled A., Regev O., Sripada R. The effect of compatibility and dimensionality of carbon nanofillers on cement composites. Construction and Building Materials. 2020. Vol. 232. https: //doi.org/10.1016/j.conbuildmat.2019.117141.
5. R.A. e Silva, P. de Castro Guetti, M.S. da Luz, F. Rouxinol, R. Valentim Gelamo. Enhanced properties of cement mortars with multilayer graphene nanoparticles. Construction and Building Materials. 2017. Vol. 149, pp. 378–385. https://doi.org/10.1016/j.conbuildmat.2017.05.146
6. Liu Ji., Fu Ji., Yang Ya., Gu Ch. Study on dispersion, mechanical and microstructure properties of cement paste incorporating graphene sheets. Construction and Building Materials. 2019. Vol. 199, pp. 1–11. https:// doi.org/10.1016/j.conbuildmat.2018.12.006
7. Ho V.D., Ng Ching-Tai, Coghlan C.J., Goodwin A., Mc Guckin C., Ozbakkaloglu T., Losic D. Electrochemically produced graphene with ultra large particles enhances mechanical properties of Portland cement mortar. Construction and Building Materials. 2020. Vol. 234. 117403. https://doi.org/10.1016/j.conbuildmat.2019.117403
8. Zadneprovskii R.P. On the effectiveness and prospects of using nanocarbon microadditives for building mixtures. Stroitel’nye materialy, oborudovanie, tekhnologii XXI veka. 2011. No. 8 (151), pp. 22–25. (In Russian).
9. Gyul’misaryan T.G., Kapustin V.M. Dispersion systems – the main raw material for the production of carbon black. Neftekhimiya. 2016. Vol. 56. No. 4, p. 346. (In Russian).
10. Kozlov A.N., Yurlov A.S. Physico-chemical properties, composition and structure of soot particles. Aktual’nye voprosy sovershenstvovaniya tekhnologii proizvodstva i pererabotki produktsii sel’skogo khozyaistva. 2017. No. 19, pp. 341–346. (In Russian).
11. Bulgakov B.I., Tang V.L., Aleksandrova O.V. The influence of nanosized soot particles on the strength of cement stone at an early age. Vestnik Belgorodskogo gosudarstvennogo tekhnologicheskogo universiteta im. V.G. Shukhova. 2016. No. 11, pp. 18–22. (In Russian).
12. Ignatova O.A., Makarova N.V. The effect of ultrafine soot pigment additives on the properties of gypsum-cementpozzolanic binder. Izvestiya vysshikh uchebnykh zavedenii. Stroitel’stvo. 2017. No. 11–12 (707–708), pp. 31–41. (In Russian).
13. Yakovlev G.I., Pervushin G.N., Gordina A.F., Shaibadulina A.V., Saidova Z.S., Protod’yakonova T.L., Bur’yanov A.F., Nikitina S.V. Modification of the structure and properties of gypsum binder by dispersion of technical soot. Intellektual’nye sistemy v proizvodstve. 2019. Vol. 17. No. 1, pp. 138–143. (In Russian).
14. Sultanova V.M., Pudov I.A. Study of the effect of graphite on the properties of gypsum binder. Nauka, obrazovanie i kul’tura. 2019. No. 5 (39), pp. 5–9. (In Russian).
15. M. del Mar Barbero-Barrera, N. Flores-Medina, V. Perez-Villar. Assessment of thermal performance of gypsum-based composites with revalorized graphite filler. Construction and Building Materials. 2017. Vol. 142, pp. 83–91. https://doi.org/10.1016/j.conbuildmat.2017.03.060
16. Medina N.F., Barbero-Barrera M.M., Bustamante R. Improvement of the properties of gypsum-based composites with recycled isostatic graphite powder from the milling production of molds for Electrical Discharge Machining (EDM) used as a new filler. Construction and Building Materials. 2016. Vol. 107. 2016, pp. 17–27. DOI: 10.1016/j.conbuildmat.2015.12.194
17. Barbero-Barrera M.M., Medina N.F., GuardiaMartin C. Influence of the addition of waste graphite powder on the physical and microstructural performance of hydraulic lime pastes. Construction and Building Materials. 2017. Vol. 149, pp. 599–611. https://doi.org/10.1016/j.conbuildmat.2017.05.156
18. Medina N.F., Barbero-Barrera M.M., Jove-Sandoval F. Improvement of the mechanical and physical properties of cement pastes and mortars through the addition isostatic graphite. Construction and Building Materials. 2018. Vol. 189, pp. 898–905. https://doi.org/10.1016/j.conbuildmat.2018.09.055
19. Tokarev Yu.V., Ageev A.V., Volkov M.A., Kuzmina N.V., Yakovlev G.I. Properties and structure of anhydrite binder of Ergachinsky deposit in the presence of phosphate activators and aleurolite. Stroitel’nye Materialy [Construction Materials]. 2019. No. 10, pp. 46–52. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-775-10-46-52
20. Yakovlev G.I., Fedorova G.D., Polyanskikh I.S. High strength concrete with dispersed additives. Promyshlennoe i grazhdanskoe stroitel’stvo. 2017. No. 2, pp. 35–42. (In Russian).
21. Levashova A.K., Sycheva L.I. The effect of the nature of the plasticizer on the properties of anhydrite binder. Uspekhi v khimii i khimicheskoi tekhnologii. 2016. Vol. 30. No. 7 (176), pp. 58–60. (In Russian).
For citation: Tokarev Yu.V., Volkov M.A., Ageev A.V., Kuzmina N.V., Grakhov V.P., Yakovlev G.I., Khazeev D.R. Estimation of efficiency of applying aqueous dispersion of carbon particles in anhydrite binder. Stroitel’nye Materialy [Construction Materials]. 2020. No. 1–2, pp. 24–35. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2020-778-1-2-24-35