AbstractAbout AuthorsReferences
Results of studies and developments concerning the use of a mono-mineral binder, quick lime, for hydration structure formation of artificial Portlandite stone and production of clinkerless composites on its base are presented. It is shown that for producing the durable artificial Portlandite stone it is necessary to separate the stage of formation of individual crystals Са(ОН)2 from the stage of their aggregate formation. Technological options of the lime hydration under different conditions with the purpose to obtain individual micro- and nano-size crystals of Portlandite with non-equilibrium energy state are presented. The formation of artificial stone from individual crystals of Portlandite is made by compaction into the aggregates of a contact-condensation type. A possibility to obtain Portlandite, Portlandite-calcium carbonate, and Portlandite -aluminum silicate cementless contact-condensation systems of hardening which are able to harden directly under the forced compaction of nano- and micro-disperse particles of initial alkali and acid oxides and their hydrates endowed or purposefully endowed with the non-equilibrium energy state is shown.
E.M. CHERNYSHOV, Doctor of Sciences (Engineering), Academician of RAAСS (This email address is being protected from spambots. You need JavaScript enabled to view it.)
N.D. POTAMOSHNEVA, Candidate of Sciences (Engineering)
O.V. ARTAMONOVA, Candidate of Sciences (Chemistry) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
N.D. POTAMOSHNEVA, Candidate of Sciences (Engineering)
O.V. ARTAMONOVA, Candidate of Sciences (Chemistry) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
Voronezh State University of Architecture and Civil Engineering (84, 20-letiya Oktyabrya Street, 394006, Voronezh, Russian Federation)
1. Chernyshov E.M., Potamoshneva N.D. Artificial stone on the basis of crystallization portlandite. Modern problems of building materials. Future directions in the theory and practice of mineral binders and related materials: Materials academic readings RAASN. International scientific and technical conference. Samara. 1995. Part 1, pp. 20–21. (In Russian).
2. Belov N.V. Protsessy real’nogo kristalloobrazovaniya. [The process of real crystal formation]. Moscow: Nauka. 1977. 235 p.
3. Volmer M. Kinetika obrazovaniya novoi fazy. [Kinetics of formation of a new phase]. Moscow: Nauka. 1986. 208 p.
4. Kozlova O.G. Rost i morfologiya kristallov. [Growth and morphology of crystals]. Moscow: Publishing house of the Moscow University. 1980. 368 p.
5. Camski E.V. Kristallizatsiya v khimicheskoi promyshlennosti. [Crystallization in the chemical industry]. Moscow: Chemistry. 1969. 344 p.
6. Lodiz R., Parker R. Rost monokristallov. [Single crystal growth]. Moscow: Mir. 1974. 540 p.
7. Logginov G.I., Rebinder P.A., Sukhov V.P. Research hydration hardening quicklime. DAN SSSR. 1954. Vol. 99. No. 4, pp. 569–572. (In Russian).
8. Osin B.V., Ulyanov V.A., Volkov V.V. Terms high hydration hardening lime. Izvestiya vysshikh uchebnykh zavedenii. Stroitel’stvo i arkhitektura. 1973. No. 10, pp. 73–76. (In Russian).
9. Chernyshov E.M., Potamoshneva N.D. Development of research on pattern formation portlanditovogo stone. Actual problems of building materials: Materials of All-Russian scientific and technical conference. Tomsk. 1998, pp. 4–7. (In Russian).
10. Glukhov V.D., Runova R.F., Maksunov S.E. Vyazhushchie i kompozitsionnye materialy kontaktnogo tverdeniya. [Cementing composites and contact hardening]. Kiev: Vishcha school. 1991. 243 p.
11. Chernyshov E.M., Potamoshneva N.D. Features of structure formation portlanditovogo stone condensation contact-hardening. Modern problems of building materials: Materials of VI Academic readings RAACS. Ivanovo. 2000, pp. 581–584. (In Russian).
12. Chernyshov E.M., Potamoshneva N.D. Identification of the characteristics of the structure of artificial stone portlandite condensation contact-hardening. Modern problems of building materials: Materials of VI Academic readings RAACS. Voronezh. 1999, pp. 547–550. (In Russian).
13. Pomazkov V.V. Issledovaniya po tsementnym i silikatnym betonam. [Research on cement and silicate concrete]. Voronezh: Publishing house of the Voronezh State University. Vol. 1. 1964, pp. 59.
14. Gorshkov V.S., Savelyev V.G., Abakumov A.V. Vyazhushchie, keramika i steklokristallicheskie materialy: Struktura i svoistva. [Cementing, ceramics, and glass-crystalline materials: Structure and properties]. Moscow: Stroyizdat. 1995. 576 p.
15. Jung V. Microconcrete theory and its development. Proceedings VNITI session on the achievements of Soviet science in the field of silicates. Moscow. 1949, pp. 50–53. (In Russian).
16. Zhuravlev V.F. Khimiya vyazhushchikh veshchestv. [Chemical binders]. Moscow: State scientific and technical publishing house of chemical literature. 1951. 205 p.
17. Timashev V.V. Izbrannye trudy. Sintez i gidratatsiya vyazhushchikh materialov. [Selected works. Synthesis and hydration of cementitious materials]. Moscow: Nauka. 1986. 424 p.
18. Belov N.V. Ocherki po strukturnoi mineralogii. [Essays on structural mineralogy]. Moscow: Nedra. 1976. 344 p.
19. Boki G.B. Kristallokhimiya. [Crystal chemistry]. Moscow: Nauka. 1971. 400 p.
20. Palatnik L.S., Papirov I.I. Epitaksial’nye plenki [Epitaxial films]. Moscow: Nauka. 1971. 480 p.
21. Benshteyn Yu.I., Butt Yu.M., Timashev V.V., Kaverin B.S. Crystallization hydrated cement stone growths on carbonate substrate. Silicates: Proceedings MchTI. Iss. LXYIII. Moscow. 1971, pp. 238–242. (In Russian).
22. Ilyukhin V.V. Gidrosilikaty kal’tsiya. Sintez monokristallov i kristallokhimiya. [Calcium silicate. Synthesis of single crystals and crystal]. Moscow: Nauka. 1979. 44 p.
23. Shchukin E.D., Alekhine E.A., Rehbinder P.A. Problemy sovremennoi kristallografii. O srastanii kristallov pri obrazovanii dispersnykh kristallizatsionnykh struktur. [Problems of modern crystallography. Adhesions in the formation of crystals dispersed crystallization structures]. Moscow: Nauka. 1975, pp. 61–71.
24. Glukhov V.D., Tsyrempilov A.D., Runova R.F. Shchelochnye betony na osnove effuzivnykh porod. [Alkaline concrete on the basis of volcanic rocks]. Irkutsk: Publishing House of the Irkutsk University. 1990. 176 p.
25. Sviridov V.L., Ovcharenko G.I. Natural zeolites – minerals for construction materials. Stroitel’nye Materialy [Construction Materials]. 1999. No. 9, pp. 9–11. (In Russian).
26. Vlasov V.V., Barsukov L.G., Krivneva G.G. The chemical activity of natural and technogenic silica-alumina feedstock in the early stages of structure besklinkernyh composite binders. Modern problems of building materials: Materials of the VII Academic readings RAACS. Belgorod. 2001. Part 1, pp. 59–65. (In Russian).
27. Urhanova L.A., Permiakov D.M., Chimitov A.Z. Silicate-based concrete activated binder of substandard lime and volcanic rocks. Stroitel’nye Materialy [Construction Materials]. 2004. No. 8, pp. 40–41. (In Russian).
28. Chernyshov E.M., Potamoshneva N.D., Sergutkina O.R., Kukina O.B. Portlandite-karbonatkaltsievy material with contact-condensation mechanism of structure formation. Current state and prospects of development of building materials: Materials of the international scientific conference. Samara. 2004, pp. 566–570. (In Russian).
29. Chernyshov E.M., Potamoshneva N.D., Kukina O.B., Stepanova M.P. Building composites with nano-contact and condensation, matrix microstructure of artificial portlandite. Modern problems of building materials: Materials XV Academic readings RAACS. International scientific and technical conference. Kazan: KSUAE. 2010, pp. 308–321. (In Russian).
30. Chernyshov E.M., Stepanova M.P., Potamoshneva N.D. Portlandite-aluminosilicate contact-condensing system hardening and composites based on them: possible mechanisms of pattern formation. Stroitel’stvo i arkhitektura: Nauchnyi vestnik Voronezhskogo GASU. 2012. Vol. 3 (12), pp. 86–95. (In Russian).
31. Chernyshov E.M., Stepanova M.P., Potamoshneva N.D. Portlandite-aluminosilicate contact-condensing system hardening and composites based on them: optimization of conditions and factors determining technology. Stroitel’stvo i arkhitektura: Nauchnyi vestnik Voronezhskogo GASU. 2012. Vol. 3 (12), pp. 96–105. (In Russian).
32. Chernyshov E.M., Artamonov O.V., Korotkih D.N., et al. Applications of nanochemistry in solid-phase technology of building materials: scientific and engineering problems, directions and examples. Stroitel’nye Materialy [Construction Materials]. 2008. No. 2, pp. 32–36. (In Russian).
2. Belov N.V. Protsessy real’nogo kristalloobrazovaniya. [The process of real crystal formation]. Moscow: Nauka. 1977. 235 p.
3. Volmer M. Kinetika obrazovaniya novoi fazy. [Kinetics of formation of a new phase]. Moscow: Nauka. 1986. 208 p.
4. Kozlova O.G. Rost i morfologiya kristallov. [Growth and morphology of crystals]. Moscow: Publishing house of the Moscow University. 1980. 368 p.
5. Camski E.V. Kristallizatsiya v khimicheskoi promyshlennosti. [Crystallization in the chemical industry]. Moscow: Chemistry. 1969. 344 p.
6. Lodiz R., Parker R. Rost monokristallov. [Single crystal growth]. Moscow: Mir. 1974. 540 p.
7. Logginov G.I., Rebinder P.A., Sukhov V.P. Research hydration hardening quicklime. DAN SSSR. 1954. Vol. 99. No. 4, pp. 569–572. (In Russian).
8. Osin B.V., Ulyanov V.A., Volkov V.V. Terms high hydration hardening lime. Izvestiya vysshikh uchebnykh zavedenii. Stroitel’stvo i arkhitektura. 1973. No. 10, pp. 73–76. (In Russian).
9. Chernyshov E.M., Potamoshneva N.D. Development of research on pattern formation portlanditovogo stone. Actual problems of building materials: Materials of All-Russian scientific and technical conference. Tomsk. 1998, pp. 4–7. (In Russian).
10. Glukhov V.D., Runova R.F., Maksunov S.E. Vyazhushchie i kompozitsionnye materialy kontaktnogo tverdeniya. [Cementing composites and contact hardening]. Kiev: Vishcha school. 1991. 243 p.
11. Chernyshov E.M., Potamoshneva N.D. Features of structure formation portlanditovogo stone condensation contact-hardening. Modern problems of building materials: Materials of VI Academic readings RAACS. Ivanovo. 2000, pp. 581–584. (In Russian).
12. Chernyshov E.M., Potamoshneva N.D. Identification of the characteristics of the structure of artificial stone portlandite condensation contact-hardening. Modern problems of building materials: Materials of VI Academic readings RAACS. Voronezh. 1999, pp. 547–550. (In Russian).
13. Pomazkov V.V. Issledovaniya po tsementnym i silikatnym betonam. [Research on cement and silicate concrete]. Voronezh: Publishing house of the Voronezh State University. Vol. 1. 1964, pp. 59.
14. Gorshkov V.S., Savelyev V.G., Abakumov A.V. Vyazhushchie, keramika i steklokristallicheskie materialy: Struktura i svoistva. [Cementing, ceramics, and glass-crystalline materials: Structure and properties]. Moscow: Stroyizdat. 1995. 576 p.
15. Jung V. Microconcrete theory and its development. Proceedings VNITI session on the achievements of Soviet science in the field of silicates. Moscow. 1949, pp. 50–53. (In Russian).
16. Zhuravlev V.F. Khimiya vyazhushchikh veshchestv. [Chemical binders]. Moscow: State scientific and technical publishing house of chemical literature. 1951. 205 p.
17. Timashev V.V. Izbrannye trudy. Sintez i gidratatsiya vyazhushchikh materialov. [Selected works. Synthesis and hydration of cementitious materials]. Moscow: Nauka. 1986. 424 p.
18. Belov N.V. Ocherki po strukturnoi mineralogii. [Essays on structural mineralogy]. Moscow: Nedra. 1976. 344 p.
19. Boki G.B. Kristallokhimiya. [Crystal chemistry]. Moscow: Nauka. 1971. 400 p.
20. Palatnik L.S., Papirov I.I. Epitaksial’nye plenki [Epitaxial films]. Moscow: Nauka. 1971. 480 p.
21. Benshteyn Yu.I., Butt Yu.M., Timashev V.V., Kaverin B.S. Crystallization hydrated cement stone growths on carbonate substrate. Silicates: Proceedings MchTI. Iss. LXYIII. Moscow. 1971, pp. 238–242. (In Russian).
22. Ilyukhin V.V. Gidrosilikaty kal’tsiya. Sintez monokristallov i kristallokhimiya. [Calcium silicate. Synthesis of single crystals and crystal]. Moscow: Nauka. 1979. 44 p.
23. Shchukin E.D., Alekhine E.A., Rehbinder P.A. Problemy sovremennoi kristallografii. O srastanii kristallov pri obrazovanii dispersnykh kristallizatsionnykh struktur. [Problems of modern crystallography. Adhesions in the formation of crystals dispersed crystallization structures]. Moscow: Nauka. 1975, pp. 61–71.
24. Glukhov V.D., Tsyrempilov A.D., Runova R.F. Shchelochnye betony na osnove effuzivnykh porod. [Alkaline concrete on the basis of volcanic rocks]. Irkutsk: Publishing House of the Irkutsk University. 1990. 176 p.
25. Sviridov V.L., Ovcharenko G.I. Natural zeolites – minerals for construction materials. Stroitel’nye Materialy [Construction Materials]. 1999. No. 9, pp. 9–11. (In Russian).
26. Vlasov V.V., Barsukov L.G., Krivneva G.G. The chemical activity of natural and technogenic silica-alumina feedstock in the early stages of structure besklinkernyh composite binders. Modern problems of building materials: Materials of the VII Academic readings RAACS. Belgorod. 2001. Part 1, pp. 59–65. (In Russian).
27. Urhanova L.A., Permiakov D.M., Chimitov A.Z. Silicate-based concrete activated binder of substandard lime and volcanic rocks. Stroitel’nye Materialy [Construction Materials]. 2004. No. 8, pp. 40–41. (In Russian).
28. Chernyshov E.M., Potamoshneva N.D., Sergutkina O.R., Kukina O.B. Portlandite-karbonatkaltsievy material with contact-condensation mechanism of structure formation. Current state and prospects of development of building materials: Materials of the international scientific conference. Samara. 2004, pp. 566–570. (In Russian).
29. Chernyshov E.M., Potamoshneva N.D., Kukina O.B., Stepanova M.P. Building composites with nano-contact and condensation, matrix microstructure of artificial portlandite. Modern problems of building materials: Materials XV Academic readings RAACS. International scientific and technical conference. Kazan: KSUAE. 2010, pp. 308–321. (In Russian).
30. Chernyshov E.M., Stepanova M.P., Potamoshneva N.D. Portlandite-aluminosilicate contact-condensing system hardening and composites based on them: possible mechanisms of pattern formation. Stroitel’stvo i arkhitektura: Nauchnyi vestnik Voronezhskogo GASU. 2012. Vol. 3 (12), pp. 86–95. (In Russian).
31. Chernyshov E.M., Stepanova M.P., Potamoshneva N.D. Portlandite-aluminosilicate contact-condensing system hardening and composites based on them: optimization of conditions and factors determining technology. Stroitel’stvo i arkhitektura: Nauchnyi vestnik Voronezhskogo GASU. 2012. Vol. 3 (12), pp. 96–105. (In Russian).
32. Chernyshov E.M., Artamonov O.V., Korotkih D.N., et al. Applications of nanochemistry in solid-phase technology of building materials: scientific and engineering problems, directions and examples. Stroitel’nye Materialy [Construction Materials]. 2008. No. 2, pp. 32–36. (In Russian).
For citation: Chernyshov E.M., Potamoshneva N.D., Artamonova O.V. Concepts and Substantiations of Nano-Modification Technology of Building Composites Structures. Part 4. Sol-gel Technology of Nano-, Micro-Disperse Crystals of Portlandite for Contact-Condensation Compaction of Structures of Portlandite Stone and Composites on Its Base. Stroitel’nye Materialy [Construction Materials]. 2015. No. 11, pp. 65-74. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2015-731-11-65-74