AbstractAbout AuthorsReferences
The basic demands of impregnating-bridging compositions to inhibit the alkali-silicate reactions and to prevent deformations of concrete and destruction of constructions are identified in the paper based on analysis of the impregnation kinetics of capillary-porous body. The results of studies of changes in properties of solution of lithium nitrate and lithium carbonate from them concentration, kind and amount of surface-active substance are presented. Assessment of efficiency of studied impregnating-bridging compositions was performed by calculation of complex parameter. Selection of the optimal content of the compositions was made. The most effective composition is Li2CO3 (c=1.25%) with 0.0001% nonionic surfactant ALM-7s.
E.V. KOROLEV1, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.), director, scientific and educational center «Nanomaterials and Nanotechnology»
M.I. VDOVIN2, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.I. AL’BAKASOV3, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.S. INOZEMTCEV1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
M.I. VDOVIN2, Engineer (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.I. AL’BAKASOV3, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
A.S. INOZEMTCEV1, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
1 Moscow State University of Civil Engineering (26, Yaroslavskoe Highway, Moscow, 129337, Russian Federation)
2 «OrenburgRemDorStroy» GUP (1/1, 60 let Oktyabrya Street, Orenburg 460021, Russian Federation)
1. Brykov A.S., Voronkov M.Ye. Alkali-silica reactions, alkaline corrosion of Portland cement concretes and pozzolanic additives – corrosion inhibitors. Tsement i ego primenenie. 2014. No. 5, pp. 87–94. (In Russian).
2. Stanton Т.Е. Expansion of concrete through reaction between cement and aggregate. Proc. Amer. Soc. Civil Engineers. 1940. Vol. 66. No. 10, pp. 1781–1811.
3. Bogue R.H. The chemistry of Portland cement. NY.: Reinhold publishing corporation, 1947. 572 p.
4. Kühl H. Zement-Chemie. В. 3., 1951.
5. Stark J., Freyburg E., Seyfarth K., Giebson C., Erfurt D. 70 Jahre AKR und keine Ende in Sicht. International Baustofftagung IBAUSIL. Weimar, 2009.
6. Moskvin V.M., Ivanov F.M., Alekseev S.N., Guzeev E.A. Korroziya betona i zhelezobetona, metody ikh zashchity [Corrosion of concrete and reinforced concrete, methods of protection]. Moscow: Stroiizdat. 1980. 536 p.
7. Rozental’ N.K., Chekhnii G.V., Lyubarskaya G.V., Rozental’ A.N. Protection of concrete on the reactive aggregate against internal corrosion // Stroitel’nye Materialy [Construction Materials]. 2009. No. 3, pp. 68–71. (In Russian).
8. Helmuth R., Stark D., Diamond S., Moranville-Regourd M. Alkali-Silica Reactivity: An Overview of Research. SHRP-C-342: Strategy Highway Research Program. National Research Council, Washington, DC. 1993.
9. Swamy R.N. Alkali-aggregate reaction – the bogeyman of concrete // Concrete technology past, present and future. ACISP-144. 1994, pp. 105–139.
10. Moskvin V. M, Royak G.S. Kompozitsiya dlya antikorrozionnoi zashchity [Corrosion of concrete under the action of alkali cement on silica filler]. Moscow: Gosstroiizdat. 1962. 164 p.
11. Fournier B., Bérubé M.A., Folliard K.J., Thomas M.D.A. Report on the diagnosis, prognosis and mitigation of alkali-silica reaction (ASR) in transportation structures. FHWAHIF-09-004, Federal Highway Administration. 2010.
12. Bérubé M.A., Tremblay C. Chemistry of pore solution expressed under high pressure – influence of various parameters and comparison with hot-water extraction method. 12th International Conference on AAR in Concrete, Beijing, China. 2004, pp. 833–842.
13. Pleau R., Bérubé M.A., Pigeon M., Fournier B., Raphaël S. Mechanical Behavior of Concrete Affected by AAR. 8th International Conference on AAR in Concrete. Kyoto, Japan. 1989, pp. 721–726.
14. Villeneuve, V., Fournier, B. and Duchesne, J. Determination of the damage in concrete affected by ASR – the Damage rating Index (DRI). 14th International Conference on AAR in Concrete, Austin, Texas. 2012.
15. Korolev E.V., Smirnov V.A., Zemlyakov A.N. The identification of tumors caused by alkali-silica reaction. Vestnik MGSU. 2013. No. 6, pp. 109–116. (In Russian).
16. Grishina A.N., Zemlyakov A.N., Korolev E.V., Okhotnikova K.Yu., Smirnov V.A. Identification of the corrosion in cement composites by means of statistical modeling. Vestnik MGSU. 2014. No. 4, pp. 87–97. (In Russian).
17. Stark D. Handbook for the Identification of Alkali-Silica Reactivity in Highway Structures. SHRP-C-315, TRB National Research Council. 1991. 49 p.
18. Patent RF 2258725. Kompozitsiya dlya antikorrozionnoi zashchity [The composition for corrosion protection]. Babakova O.K., Ogorodnikova T.V., Kochetkov V.M., Timofeev V.S., Declared 09.10.2003. Published 20.08.2005. (In Russian).
19. Patent WO 1993012052. Improvements in and relating to treatments for concrete. PAGE, Christopher, Lyndon, Declared 17.12.1992. Published 24.06.1993.
20. Patent WO 2013006662. Lithium-based concrete admixtures for controlling alkali-silica reactions with enhanced set-time control / STOKES, David B, Declared 05.07.2012. Published 10.01.2013.
21. Patent WO 1994029496. Cathodic protection of reinforced concrete / PAGE, Christopher, Lyndon, Declared 22.12.1994. Published 22.12.1994.
22. Patent WO 2004089844. Product for treating reinforced concrete constructions / LUTZ, Theophil, Markus, CHEVRET, Christian, Declared 30.03.2004. Published 21.10.2004.
23. Patent WO 1993012052. Improvements in and relating to treatments for concrete / PAGE, Christopher, Lyndon, Declared 17.12.1992. Published 24.06.1993.
24. Stokes D.B., Wang H.H., Diamond S. A lithium-based admixture for ASR control that does not increase the pore solution pH. Proceedings of the 5th CANMET/ACI Int. Conf. on Superplasticizers and Other Chemical Admixtures in Concrete, ACI SP-173, American Concrete Institute, Detroit. 1997, pp. 855–867.
25. Feng X., Thomas M.D.A., Bremner T.W., Balcom B.J., Folliard K.J. Studies on lithium salts to mitigate ASR-induced expansion in new concrete: a critical review. Cement and Concrete Research. 2005. Vol. 35, pp. 1789–1796.
26. Fournier B., Nkinamubanzi P-C., Chevrier R. comparative field and laboratory investigations on the use of supplementary cementing materials to control alkali-silica reaction in concrete. Proceedings of the 12th International Conference on Alkali-Aggregate Reaction in Concrete. Beijing, China. 2004. Vol. 1, pp. 528–537.
27. Thomas M.D.A. Field studies of fly ash concrete structures containing reactive aggregates. Magazine of Concrete Research. 1996. Vol. 48 (177), pp. 265–279.
28. Kirovskaya I.A. Khimicheskaya termodinamika. Rastvory. [Chemical thermodynamics. Solutions] Omsk: OmGTU. 2009. 236 p.
29. Kharned G., Ouen B. Fizicheskaya khimiya rastvorov elektrolitov [Physical chemistry of electrolyte solutions]. M.: Izdatinlit. 1952. 628 p.
2. Stanton Т.Е. Expansion of concrete through reaction between cement and aggregate. Proc. Amer. Soc. Civil Engineers. 1940. Vol. 66. No. 10, pp. 1781–1811.
3. Bogue R.H. The chemistry of Portland cement. NY.: Reinhold publishing corporation, 1947. 572 p.
4. Kühl H. Zement-Chemie. В. 3., 1951.
5. Stark J., Freyburg E., Seyfarth K., Giebson C., Erfurt D. 70 Jahre AKR und keine Ende in Sicht. International Baustofftagung IBAUSIL. Weimar, 2009.
6. Moskvin V.M., Ivanov F.M., Alekseev S.N., Guzeev E.A. Korroziya betona i zhelezobetona, metody ikh zashchity [Corrosion of concrete and reinforced concrete, methods of protection]. Moscow: Stroiizdat. 1980. 536 p.
7. Rozental’ N.K., Chekhnii G.V., Lyubarskaya G.V., Rozental’ A.N. Protection of concrete on the reactive aggregate against internal corrosion // Stroitel’nye Materialy [Construction Materials]. 2009. No. 3, pp. 68–71. (In Russian).
8. Helmuth R., Stark D., Diamond S., Moranville-Regourd M. Alkali-Silica Reactivity: An Overview of Research. SHRP-C-342: Strategy Highway Research Program. National Research Council, Washington, DC. 1993.
9. Swamy R.N. Alkali-aggregate reaction – the bogeyman of concrete // Concrete technology past, present and future. ACISP-144. 1994, pp. 105–139.
10. Moskvin V. M, Royak G.S. Kompozitsiya dlya antikorrozionnoi zashchity [Corrosion of concrete under the action of alkali cement on silica filler]. Moscow: Gosstroiizdat. 1962. 164 p.
11. Fournier B., Bérubé M.A., Folliard K.J., Thomas M.D.A. Report on the diagnosis, prognosis and mitigation of alkali-silica reaction (ASR) in transportation structures. FHWAHIF-09-004, Federal Highway Administration. 2010.
12. Bérubé M.A., Tremblay C. Chemistry of pore solution expressed under high pressure – influence of various parameters and comparison with hot-water extraction method. 12th International Conference on AAR in Concrete, Beijing, China. 2004, pp. 833–842.
13. Pleau R., Bérubé M.A., Pigeon M., Fournier B., Raphaël S. Mechanical Behavior of Concrete Affected by AAR. 8th International Conference on AAR in Concrete. Kyoto, Japan. 1989, pp. 721–726.
14. Villeneuve, V., Fournier, B. and Duchesne, J. Determination of the damage in concrete affected by ASR – the Damage rating Index (DRI). 14th International Conference on AAR in Concrete, Austin, Texas. 2012.
15. Korolev E.V., Smirnov V.A., Zemlyakov A.N. The identification of tumors caused by alkali-silica reaction. Vestnik MGSU. 2013. No. 6, pp. 109–116. (In Russian).
16. Grishina A.N., Zemlyakov A.N., Korolev E.V., Okhotnikova K.Yu., Smirnov V.A. Identification of the corrosion in cement composites by means of statistical modeling. Vestnik MGSU. 2014. No. 4, pp. 87–97. (In Russian).
17. Stark D. Handbook for the Identification of Alkali-Silica Reactivity in Highway Structures. SHRP-C-315, TRB National Research Council. 1991. 49 p.
18. Patent RF 2258725. Kompozitsiya dlya antikorrozionnoi zashchity [The composition for corrosion protection]. Babakova O.K., Ogorodnikova T.V., Kochetkov V.M., Timofeev V.S., Declared 09.10.2003. Published 20.08.2005. (In Russian).
19. Patent WO 1993012052. Improvements in and relating to treatments for concrete. PAGE, Christopher, Lyndon, Declared 17.12.1992. Published 24.06.1993.
20. Patent WO 2013006662. Lithium-based concrete admixtures for controlling alkali-silica reactions with enhanced set-time control / STOKES, David B, Declared 05.07.2012. Published 10.01.2013.
21. Patent WO 1994029496. Cathodic protection of reinforced concrete / PAGE, Christopher, Lyndon, Declared 22.12.1994. Published 22.12.1994.
22. Patent WO 2004089844. Product for treating reinforced concrete constructions / LUTZ, Theophil, Markus, CHEVRET, Christian, Declared 30.03.2004. Published 21.10.2004.
23. Patent WO 1993012052. Improvements in and relating to treatments for concrete / PAGE, Christopher, Lyndon, Declared 17.12.1992. Published 24.06.1993.
24. Stokes D.B., Wang H.H., Diamond S. A lithium-based admixture for ASR control that does not increase the pore solution pH. Proceedings of the 5th CANMET/ACI Int. Conf. on Superplasticizers and Other Chemical Admixtures in Concrete, ACI SP-173, American Concrete Institute, Detroit. 1997, pp. 855–867.
25. Feng X., Thomas M.D.A., Bremner T.W., Balcom B.J., Folliard K.J. Studies on lithium salts to mitigate ASR-induced expansion in new concrete: a critical review. Cement and Concrete Research. 2005. Vol. 35, pp. 1789–1796.
26. Fournier B., Nkinamubanzi P-C., Chevrier R. comparative field and laboratory investigations on the use of supplementary cementing materials to control alkali-silica reaction in concrete. Proceedings of the 12th International Conference on Alkali-Aggregate Reaction in Concrete. Beijing, China. 2004. Vol. 1, pp. 528–537.
27. Thomas M.D.A. Field studies of fly ash concrete structures containing reactive aggregates. Magazine of Concrete Research. 1996. Vol. 48 (177), pp. 265–279.
28. Kirovskaya I.A. Khimicheskaya termodinamika. Rastvory. [Chemical thermodynamics. Solutions] Omsk: OmGTU. 2009. 236 p.
29. Kharned G., Ouen B. Fizicheskaya khimiya rastvorov elektrolitov [Physical chemistry of electrolyte solutions]. M.: Izdatinlit. 1952. 628 p.
For citation: Korolev E.V., Vdovin M.I., Al’bakasov A.I., Inozemtcev A.S. Basic Properties of Impregnating-Bridging Compositions to Inhibit the Alkali-Silicate Reactions. Stroitel’nye Materialy [Construction Materials]. 2015. No. 7, pp. 24-29. DOI: https://doi.org/10.31659/0585-430X-2015-727-7-24-29