AbstractAbout AuthorsReferences
One of the trends in modern construction is the use of highly dispersed additives to produce Ultra-High Performance Concrete in terms of both strength and durability, especially for high-rise construction projects. The durability of concrete is determined by two main parameters – the reactivity of the cement stone components in relation to an aggressive environment and the permeability to an aggressive environment. The article discusses the use of finely dispersed calcium carbonate as an additive that increases the durability of concrete in general, and sulfate resistance in particular. The mechanism of action of calcium carbonate is based on a combination of the effect of a micro filler and chemical interaction with Portland cement minerals. Calcium carbonate interacts with the hydration products of tricalcium aluminate, reducing the amount of C3A available for interaction with gypsum, followed by the formation of the main destructor when exposed to sulfates, ettringite. Calcium carbonate at high dosages reduces the strength of concrete. To correct this negative effect, it is proposed to use nanoscale calcium carbonate along with the already widely used micro-sized CaCO3. The use of nanoscale calcium carbonate increases the total reaction capacity of the introduced additive, while reducing its total amount and, thus, preventing a decrease in concrete strength with a significant increase in its sulfate resistance. Nanoscale calcium carbonate densify the zone of interfacial interaction at the “cement matrix – filler” boundary, forming complex compounds with cement monominerals, which is confirmed by the data of physico-chemical studies. To further enhance the durability of concrete, the combined use of finely dispersed calcium carbonate with silica is proposed in order to bind free lime into low-base calcium hydrosilicates.
K.D. NAFIKOV, Engineer, Postgraduate Student (This email address is being protected from spambots. You need JavaScript enabled to view it.),
T.V. LATYPOVA, Candidate of Sciences (Engineering), Associate Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
E.V. LUTSYK, Candidate of Sciences (Engineering), Associate Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
P.A. FEDOROV, Candidate of Sciences (Engineering), Associate Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
I.V. LUTSYK, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
V.M. LATYPOV, Doctor of Sciences (Engineering), Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.)
T.V. LATYPOVA, Candidate of Sciences (Engineering), Associate Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
E.V. LUTSYK, Candidate of Sciences (Engineering), Associate Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
P.A. FEDOROV, Candidate of Sciences (Engineering), Associate Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
I.V. LUTSYK, Bachelor (This email address is being protected from spambots. You need JavaScript enabled to view it.),
V.M. LATYPOV, Doctor of Sciences (Engineering), Professor (This email address is being protected from spambots. You need JavaScript enabled to view it.)
Ufa State Petroleum Technological University (1, Kosmonavtov Street, Ufa, 450064, Russian Federation)
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https://doi.org/10.21122/2227-1031-2022-21-1-19-27
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https://doi.org/10.3390/ma14216612
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https://doi.org/10.31659/0585-430X-2018-762-8-69-72
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https://doi.org/10.22337/2587-9618-2022-18-2-175-183
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https://doi.org/10.33622/0869-7019.2023.05.52-59
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8. Samchenko S.V., Kaprielov S.S., Dykin I.V. Optimization of the structure and properties of powder-activated concrete by using Portland cements of different dispersion. Tekhnika i Tekhnologiya Silikatov. 2022. Vol. 29. No. 1, pp. 64–74. (In Russian). EDN: VCWLHT
9. Verenitsyn A.I., Kirillova S.A., Almyashev V.I. Influence of nanosized additive based on CaO–SiO2 system on strength properties of Portland cement stone. Khimicheskaya Tekhnologiya. 2020. Vol. 21. No. 7, pp. 309–316. (In Russian). EDN: LDDOFM.
https://doi.org/10.31044/1684-5811-2020-21-7-309-316
10. Krivoborodov Yu.R., Burlov I.Y., Myint T.N. Corrosion-resistant cements. Solid State Phenomena. 2022. Vol. 335, pp. 195–200. EDN: BDMPZO. https://doi.org/10.4028/p-e3x8g2
11. Erofeev V.T., Fedorcov A.P., Fedorcov V.A. Increasing the corrosion resistance of cement composites with active additives. Stroitel’stvo i Rekonstruktsiya. 2020. No. 2 (88), pp. 51–60. (In Russian). EDN: YWSDFP.
https://doi.org/10.33979/2073-7416-2020-88-2-51-60
12. Lutsyk E.V. Development of methods to ensure durability of reinforced concrete under the influence of atmospheric carbon dioxide. Dis. ... Candidate of Sciences (Engineering). Ufa. 2005. 160 p. (In Russian). EDN: NNHLOB
13. Kurshpel A.V., Kurshpel V.Kh. About the mechanism of destruction of the protective layer of concrete due to reinforcement corrosion. Stroitel’nye Materialy [Construction Materials]. 2021. No. 12, pp. 55–60. (In Russian).
https://doi.org/10.31659/0585-430X-2021-798-12-55-60
14. Molodin V.V., Leonovich S.N. Adhesion of restoration concrete to a corrosion-degraded reinforced concrete structure. Nauka i Tekhnika. 2022. Vol. 21. No. 1, pp. 36–41. (In Russian). EDN: OGZJFD.
https://doi.org/10.21122/2227-1031-2022-21-1-36-41
15. Terekhov I.A. Criteria for assessing the technical condition of reinforced concrete slabs during reinforcement corrosion. Stroitel’stvo i Rekonstruktsiya. 2022. No. 6 (104), pp. 128–139. (In Russian). EDN: YGOOMW.
https://doi.org/10.33979/2073-7416-2022-104-6-128-139
16. Rakhimbaev Sh.M., Tolypina N.M. Povysheniye korrozionnoy stoykosti betonov putem ratsional’nogo vybora vyazhushchego i zapolniteley [Increasing the corrosion resistance of concrete by rational selection of binders and fillers]. Belgorod: Publishing house of BSTU. 2015. 322 p. (In Russian). EDN: WJRENJ
17. Jamal A. Abdalla, Blessen Skariah Thomas, Rami A. Hawileh, Jian Yang, Bharat Bhushan Jindal, Erandi Ariyachandra. Influence of nano-TiO2, nano-Fe2O3, nanoclay and nano-CaCO3 on the properties of cement/geopolymer concrete. Cleaner Materials. Vol. 4. 2022. 100061. https://doi.org/10.1016/j.clema.2022.100061
18. Zhang M., Ma D., He J., Han Y. Sulfate corrosion resistance of foundation сoncrete with nano-particles. Magazine of Civil Engineering. 2023. 119 (3). 11901. EDN: NLKDWE. https://doi.org/10.34910/MCE.119.1
19. Hu Y., Chonggen P., Qu S., Li Q., Han S. Research progress in mechanisms and properties of nano-modified interface transition zone of Marine concrete. European Journal of Environmental and Civil Engineering. 2024. Vol. 28 (15), pp. 3517–3541. https://doi.org/10.1080/19648189.2024.2349916
20. Ghabban A.A., Al Zubaidi A.B., Jafar M., Fakhri Z. Effect of nano SiO2 and nano CaCO3 on the mechanical properties, durability and flowability of concrete. International Conference on Materials Engineering and Science. 2018. Vol. 454. 012016. https://doi.org/10.1088/1757-899X/454/1/012016
21. Sato T., Beaudoin J.J. The effect of nano-sized CaCO3 addition on the hydration of cement paste containing high volumes of fly ash. Proceedings of the 12th International Congress on the Chemistry of Cement. 2007, pp. 1–12. https://doi.org/10.1617/2351580028.077
22. Lukpanov R., Dyussembinov D., Altynbekova A., Zhantlesova Z. Research on the effect of microsilica on the properties of the cement–sand mixture. Technobius. 2022. Vol. 2. No. 4. EDN: EOMVIQ. https://doi.org/10.54355/tbus/2.4.2022.0027
https://doi.org/10.21122/2227-1031-2022-21-1-19-27
2. Blikharskyy Y., Selejdak J., Kopiika N., Vashkevych R. Study of concrete under combined action of aggressive environment and long-term loading. Materials. 2021. Vol. 14. No. 21. 6612. EDN: OVZRNP.
https://doi.org/10.3390/ma14216612
3. Chernyshov E.M., Fedosov S.V., Rumyantseva V.E. Development of methods for predicting the durability of building structures based on the development of the theory and models of concrete corrosion taking into account the phenomena of heat and mass transfer and the formation of gradient states. Academia. Arkhitektura i Stroitel’stvo. 2023. No. 1, pp. 89–100. (In Russian). EDN: LUOBRF. https://doi.org/10.22337/2077-9038-2023-1-89-100
4. Stepanova V.F., Rozental N.K., Chekhniy G.V., Baev S.M. Determination of corrosion resistance of shotcrete as a protective coating for concrete and reinforced concrete structures. Stroitel’nye Materialy [Construction Materials]. 2018. No. 8, pp. 69–73. (In Russian). EDN: UZLDLW.
https://doi.org/10.31659/0585-430X-2018-762-8-69-72
5. Bezgodov I.M., Kaprielov S.S., Sheynfeld A.V. Relationship between strength and deformation characteristics of high-strength self-compacting concrete. International Journal for Computational Civil and Structural Engineering. 2022. Vol. 18. No. 2, pp. 175–183. EDN: AVEAKR.
https://doi.org/10.22337/2587-9618-2022-18-2-175-183
6. Lam N.Z.T., Samchenko S.V., Shvetsova V.A., Bulgakov B.I. Influence of complex additives on the strength of cement stone at an early age. Promyshlennoye i Grazhdanskoye Stroitel’stvo. 2023. No. 5, pp. 52–59. (In Russian). EDN: PFYHXG.
https://doi.org/10.33622/0869-7019.2023.05.52-59
7. Romanenko I.I., Fadin A.I., Petrovnina I.N., Elichev K.A. Rapid strength gain concretes for monolithic construction. Regional’naya Arkhitektura i Stroitel’stvo. 2023. No. 4 (57), pp. 66–73. (In Russian). EDN: SKOJPF. https://doi.org/10.54734/20722958_2023_4_66
8. Samchenko S.V., Kaprielov S.S., Dykin I.V. Optimization of the structure and properties of powder-activated concrete by using Portland cements of different dispersion. Tekhnika i Tekhnologiya Silikatov. 2022. Vol. 29. No. 1, pp. 64–74. (In Russian). EDN: VCWLHT
9. Verenitsyn A.I., Kirillova S.A., Almyashev V.I. Influence of nanosized additive based on CaO–SiO2 system on strength properties of Portland cement stone. Khimicheskaya Tekhnologiya. 2020. Vol. 21. No. 7, pp. 309–316. (In Russian). EDN: LDDOFM.
https://doi.org/10.31044/1684-5811-2020-21-7-309-316
10. Krivoborodov Yu.R., Burlov I.Y., Myint T.N. Corrosion-resistant cements. Solid State Phenomena. 2022. Vol. 335, pp. 195–200. EDN: BDMPZO. https://doi.org/10.4028/p-e3x8g2
11. Erofeev V.T., Fedorcov A.P., Fedorcov V.A. Increasing the corrosion resistance of cement composites with active additives. Stroitel’stvo i Rekonstruktsiya. 2020. No. 2 (88), pp. 51–60. (In Russian). EDN: YWSDFP.
https://doi.org/10.33979/2073-7416-2020-88-2-51-60
12. Lutsyk E.V. Development of methods to ensure durability of reinforced concrete under the influence of atmospheric carbon dioxide. Dis. ... Candidate of Sciences (Engineering). Ufa. 2005. 160 p. (In Russian). EDN: NNHLOB
13. Kurshpel A.V., Kurshpel V.Kh. About the mechanism of destruction of the protective layer of concrete due to reinforcement corrosion. Stroitel’nye Materialy [Construction Materials]. 2021. No. 12, pp. 55–60. (In Russian).
https://doi.org/10.31659/0585-430X-2021-798-12-55-60
14. Molodin V.V., Leonovich S.N. Adhesion of restoration concrete to a corrosion-degraded reinforced concrete structure. Nauka i Tekhnika. 2022. Vol. 21. No. 1, pp. 36–41. (In Russian). EDN: OGZJFD.
https://doi.org/10.21122/2227-1031-2022-21-1-36-41
15. Terekhov I.A. Criteria for assessing the technical condition of reinforced concrete slabs during reinforcement corrosion. Stroitel’stvo i Rekonstruktsiya. 2022. No. 6 (104), pp. 128–139. (In Russian). EDN: YGOOMW.
https://doi.org/10.33979/2073-7416-2022-104-6-128-139
16. Rakhimbaev Sh.M., Tolypina N.M. Povysheniye korrozionnoy stoykosti betonov putem ratsional’nogo vybora vyazhushchego i zapolniteley [Increasing the corrosion resistance of concrete by rational selection of binders and fillers]. Belgorod: Publishing house of BSTU. 2015. 322 p. (In Russian). EDN: WJRENJ
17. Jamal A. Abdalla, Blessen Skariah Thomas, Rami A. Hawileh, Jian Yang, Bharat Bhushan Jindal, Erandi Ariyachandra. Influence of nano-TiO2, nano-Fe2O3, nanoclay and nano-CaCO3 on the properties of cement/geopolymer concrete. Cleaner Materials. Vol. 4. 2022. 100061. https://doi.org/10.1016/j.clema.2022.100061
18. Zhang M., Ma D., He J., Han Y. Sulfate corrosion resistance of foundation сoncrete with nano-particles. Magazine of Civil Engineering. 2023. 119 (3). 11901. EDN: NLKDWE. https://doi.org/10.34910/MCE.119.1
19. Hu Y., Chonggen P., Qu S., Li Q., Han S. Research progress in mechanisms and properties of nano-modified interface transition zone of Marine concrete. European Journal of Environmental and Civil Engineering. 2024. Vol. 28 (15), pp. 3517–3541. https://doi.org/10.1080/19648189.2024.2349916
20. Ghabban A.A., Al Zubaidi A.B., Jafar M., Fakhri Z. Effect of nano SiO2 and nano CaCO3 on the mechanical properties, durability and flowability of concrete. International Conference on Materials Engineering and Science. 2018. Vol. 454. 012016. https://doi.org/10.1088/1757-899X/454/1/012016
21. Sato T., Beaudoin J.J. The effect of nano-sized CaCO3 addition on the hydration of cement paste containing high volumes of fly ash. Proceedings of the 12th International Congress on the Chemistry of Cement. 2007, pp. 1–12. https://doi.org/10.1617/2351580028.077
22. Lukpanov R., Dyussembinov D., Altynbekova A., Zhantlesova Z. Research on the effect of microsilica on the properties of the cement–sand mixture. Technobius. 2022. Vol. 2. No. 4. EDN: EOMVIQ. https://doi.org/10.54355/tbus/2.4.2022.0027
For citation: Nafikov K.D., Latypova T.V., Lutsyk E.V., Fedorov P.A., Lutsyk I.V., Latypov V.M. About the mechanism of increasing the sulfate resistance of concrete with the addition of finely dispersed calcium carbonate. Stroitel'nye Materialy [Construction Materials]. 2025. No. 1–2, pp. 33–38. (In Russian). https://doi.org/10.31659/0585-430X-2025-832-1-2-33-38