AbstractAbout the AuthorReferences
Modification of petroleum road bitumen with a copolymer of ethylene with vinyl acetate (CEV) and 3-glycidyloxypropyltrimethoxysilane (epoxy silane) has been implemented. Epoxy silane, being a heterofunctional substance, sews the bitumen with CEV which makes it possible to obtain a non-stratified polymeric-bitumen binder. To optimize the concentrations of epoxy silane and sevylene as well as the time of the combination of components, a three-factor rotatable experimental plan has been realized. As a result, it is established that the optimal content of sevylene is 12 pts. wt., epoxy silane – 3 pts. wt., duration of combination – 4 hr. An optimal BPB (polymeric-bitumen binder) has the following properties: softening temperature is 66°C, penetration at 25°C – 50; penetration index – 2.15, brittleness temperature – 22°C. Stratification is significantly reduced. The NMR spectroscopy method made it possible to establish that the sewing of the polymeric-bitumen binder doesn’t influence on its molecular mobility.
Yu.N.HAKIMULLIN1,Doctor of Sciences (Engineering);
D.A. AYUPOV2, Candidate of Sciences (Engineering),
V.I. SUNDUKOV2, Candidate of Sciences (Physics and Mathematics),
R.I. KAZAKULOV2, Engineer;
B.I. GIZATULLIN3, Candidate of Sciences (Physics and Mathematics)
D.A. AYUPOV2, Candidate of Sciences (Engineering),
V.I. SUNDUKOV2, Candidate of Sciences (Physics and Mathematics),
R.I. KAZAKULOV2, Engineer;
B.I. GIZATULLIN3, Candidate of Sciences (Physics and Mathematics)
1 Kazan National Research Technological University (72, Karl Marx Street, 420015, Kazan, Russian Federation)
2 Kazan State University of Architecture and Engineering (1, Zelenaya Street, 420043, Kazan, Russian Federation)
3 Kazan (Volga region) Federal University (16a, Kremlevskaya Street, 420111, Kazan Russian Federation)
1. Vysotskaya M.A., Kuznetsov D.A., Barabash D.E. Nanostructured road-building materials based on organic binders. Stroitel’nye Materialy [Construction Materials]. 2013. No. 12, pp. 63–64. (In Russian).
2. Belyaev P.S., Malikov O.G., Merkulov S.A., Polushkin D.L., Frolov V.A. Solution of polymer waste utilization problem by using them in the process of road binder modifying. Stroitel’nye Materialy [Construction Materials]. 2013. No. 10, pp. 38–41. (In Russian).
3. Murafa A.V., Makarov D.B., Nuriev M.A., Khozin V.G. Bitumen-latex emulsion mastics of waterproofing and sealing purpose. Klei. Germetiki. Tekhnologii. 2012. No. 8, pp. 18–21. (In Russian).
4. Kalinina M.O. The application of innovative materials in road construction. Modern technologies: current issues, achievements and innovations: a collection of articles by the winners of the III International Scientific and Practical Conference. Penza: PSUAC. 2016, pp. 19–22. (In Russian).
5. Kindeev O.N., Vysotskaya M.A., Shekhovtsova S.Yu. The influence of the plasticizer type on bitumen and polymer-bituminous binders properties. Vestnik Belgorodskogo Gosudarstvennogo Tekhnologicheskogo Universiteta im. V.G. Shukhova. 2016. No. 1, pp. 26–30. (In Russian).
6. Shekhovtsova S.Yu., Vysotskaya M.A. The effect of carbon nanotubes on the PMB and asphalt concrete properties. Vestnik MGSU. 2015. No. 11, pp. 110–119. (In Russian).
7. Bespalov V.L. Bitumen-polymer binders and asphalt polymer concrete, modified by Elvaloy AM and butadiene methyl styrene rubber SKMS-30. Sovremennoe Promyshlennoe i Grazhdanskoe Stroitel’stvo. 2015. Vol. 11. No. 1, pp. 27–33. (In Russian).
8. Smolyakova K.R., Sharova A.I., Agapkina N.A., Baskakova A.G., Safina G.F. Synthesis of polymer-bitumen binders for road construction and study of their commercial characteristics. Science of SUSU: materials of the 66th scientific conference. A series of natural sciences sections. Chelyabinsk: SUSU. 2014, pp. 369–374. (In Russian).
9. Zolotarev V.A., Galkin A.V., Kishchinskii S.V. Polymer modified bitumens storage stability estimation. Nauka iTekhnika v Dorozhnoi Otrasli. 2006. No. 2, pp. 18–21. (In Russian).
10. Zolotarev V.A. Bitumen modified by polymers and asphalt- polymer concrete. Dorozhnaya Tekhnika. 2009, pp. 16–23. (In Russian).
11. Zakieva R.R., Gussamov I.I., Gadel’shin R.M., Petrov S.M., Ibragimova D.A., Fakhrutdinov R.Z. The influence of modifying by ethylene-vinyl acetate copolymer on the performance properties of binder and asphaltbased concrete. Khimiya i Tekhnologiya Topliv i Masel. 2015. No. 5 (591), pp. 36–39. (In Russian).
12. Gadel’shin R.M., Ibragimova D.A., Zakieva R.R., Abdel’salyam Ya.I., Petrov S.M. Modification of oxidized bitumens with oxygen-containing compounds. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2014. Vol. 17. No. 14, pp. 451–453. (In Russian).
13. Fang C., Zhou S., Zhang M., Zhao S., Wang X., Zheng C. Optimization of the modification technologies of asphalt by using waste EVA from packaging. Journal of Vinyl and Additive Technology. 2009. Vol. 15. No. 3, pp. 199–203.
14. Upadhyay S., Mallikarjunan V., Subbaraj V.K., Varughese S. Swelling and diffusion characteristics of polar and nonpolar polymers in asphalt. Journal of Applied Polymer Science. 2008. Vol. 109. No. 1, pp. 135–143.
15. Belyaev P.S., Polushkin D.L., Makeev P.V., Frolov V.A. Modification of oil road bitumen with polymeric materials for production of asphalt-concrete coatings with enhanced performance characteristics. Vestnik Tambovskogo Gosudarstvennogo Tekhnicheskogo Universiteta. 2016. Vol. 22. No. 2, pp. 264–271. (In Russian).
16. Ayupov D.A., Murafa A.V., Potapova L.I., Yagund E.M., Makarov D.B., Kazakulov R.I., Khakimullin Yu.N. Epoxidized silane as crosslinking agent between bitumen and polymer modifier. Izvestiya KGASU. 2015. No. 4, pp. 253–358. (In Russian).
17. Tonevitskii Yu.V., Mognonov D.M., Ayurova O.Zh., Kuznetsov Yu.N. Modification of road bitumen by production waste. Stroitel’nye Materialy [Construction Materials]. 2016. No. 11, pp. 59–62. (In Russian).
18. Ayupov D.A., Potapova L.I., Murafa A.V., Fakhrutdinova V.Kh., Khakimullin Yu.N., Khozin V.G. The peculiarities of bitumens and polymers interaction investigation. Izvestiya KGASU. 2011. No. 1 (15), pp. 140–146. (In Russian).
19. Rusanova S.N., Stoyanov O.V., Remizov A.B., Yanaeva A.O., Gerasimov V.K., Chalykh A.E. The IR spectroscopic study of the ethylene copolymers silanol modification. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2010. No. 9, pp. 346–352. (In Russian).
20. Rusanova S.N., Stoyanov O.V., Remizov A.B., Yanaeva A.O., Gerasimov V.K., Chalykh A.E. The IR spectroscopic study of the ethylsilicate and ethylene with acrylates copolymers interaction. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2010. No. 9, pp. 318–328. (In Russian).
21. Rusanova S.N., Temnikova N.E., Mukhamedzyanova E.R., Stoyanov O.V. The modification of ethylene and aminotrialkoxysilane copolymers. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2010. No. 9, pp. 353–355. (In Russian).
22. Tusar M., Avsenik L. Increasing the rate of recycled asphalt: an experimental study. Transport Problems. 2014. Vol. 9. No. 3, pp. 31–42.
23. Sheina T.V. Samokhina A.A. Interrelation of the fractional composition, supramolecular structure and operational parameters of road bitumen. Part II. Gradostroitel’stvo i Arkhitektura. 2015. No. 4 (21), pp. 108–114. (In Russian).
2. Belyaev P.S., Malikov O.G., Merkulov S.A., Polushkin D.L., Frolov V.A. Solution of polymer waste utilization problem by using them in the process of road binder modifying. Stroitel’nye Materialy [Construction Materials]. 2013. No. 10, pp. 38–41. (In Russian).
3. Murafa A.V., Makarov D.B., Nuriev M.A., Khozin V.G. Bitumen-latex emulsion mastics of waterproofing and sealing purpose. Klei. Germetiki. Tekhnologii. 2012. No. 8, pp. 18–21. (In Russian).
4. Kalinina M.O. The application of innovative materials in road construction. Modern technologies: current issues, achievements and innovations: a collection of articles by the winners of the III International Scientific and Practical Conference. Penza: PSUAC. 2016, pp. 19–22. (In Russian).
5. Kindeev O.N., Vysotskaya M.A., Shekhovtsova S.Yu. The influence of the plasticizer type on bitumen and polymer-bituminous binders properties. Vestnik Belgorodskogo Gosudarstvennogo Tekhnologicheskogo Universiteta im. V.G. Shukhova. 2016. No. 1, pp. 26–30. (In Russian).
6. Shekhovtsova S.Yu., Vysotskaya M.A. The effect of carbon nanotubes on the PMB and asphalt concrete properties. Vestnik MGSU. 2015. No. 11, pp. 110–119. (In Russian).
7. Bespalov V.L. Bitumen-polymer binders and asphalt polymer concrete, modified by Elvaloy AM and butadiene methyl styrene rubber SKMS-30. Sovremennoe Promyshlennoe i Grazhdanskoe Stroitel’stvo. 2015. Vol. 11. No. 1, pp. 27–33. (In Russian).
8. Smolyakova K.R., Sharova A.I., Agapkina N.A., Baskakova A.G., Safina G.F. Synthesis of polymer-bitumen binders for road construction and study of their commercial characteristics. Science of SUSU: materials of the 66th scientific conference. A series of natural sciences sections. Chelyabinsk: SUSU. 2014, pp. 369–374. (In Russian).
9. Zolotarev V.A., Galkin A.V., Kishchinskii S.V. Polymer modified bitumens storage stability estimation. Nauka iTekhnika v Dorozhnoi Otrasli. 2006. No. 2, pp. 18–21. (In Russian).
10. Zolotarev V.A. Bitumen modified by polymers and asphalt- polymer concrete. Dorozhnaya Tekhnika. 2009, pp. 16–23. (In Russian).
11. Zakieva R.R., Gussamov I.I., Gadel’shin R.M., Petrov S.M., Ibragimova D.A., Fakhrutdinov R.Z. The influence of modifying by ethylene-vinyl acetate copolymer on the performance properties of binder and asphaltbased concrete. Khimiya i Tekhnologiya Topliv i Masel. 2015. No. 5 (591), pp. 36–39. (In Russian).
12. Gadel’shin R.M., Ibragimova D.A., Zakieva R.R., Abdel’salyam Ya.I., Petrov S.M. Modification of oxidized bitumens with oxygen-containing compounds. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2014. Vol. 17. No. 14, pp. 451–453. (In Russian).
13. Fang C., Zhou S., Zhang M., Zhao S., Wang X., Zheng C. Optimization of the modification technologies of asphalt by using waste EVA from packaging. Journal of Vinyl and Additive Technology. 2009. Vol. 15. No. 3, pp. 199–203.
14. Upadhyay S., Mallikarjunan V., Subbaraj V.K., Varughese S. Swelling and diffusion characteristics of polar and nonpolar polymers in asphalt. Journal of Applied Polymer Science. 2008. Vol. 109. No. 1, pp. 135–143.
15. Belyaev P.S., Polushkin D.L., Makeev P.V., Frolov V.A. Modification of oil road bitumen with polymeric materials for production of asphalt-concrete coatings with enhanced performance characteristics. Vestnik Tambovskogo Gosudarstvennogo Tekhnicheskogo Universiteta. 2016. Vol. 22. No. 2, pp. 264–271. (In Russian).
16. Ayupov D.A., Murafa A.V., Potapova L.I., Yagund E.M., Makarov D.B., Kazakulov R.I., Khakimullin Yu.N. Epoxidized silane as crosslinking agent between bitumen and polymer modifier. Izvestiya KGASU. 2015. No. 4, pp. 253–358. (In Russian).
17. Tonevitskii Yu.V., Mognonov D.M., Ayurova O.Zh., Kuznetsov Yu.N. Modification of road bitumen by production waste. Stroitel’nye Materialy [Construction Materials]. 2016. No. 11, pp. 59–62. (In Russian).
18. Ayupov D.A., Potapova L.I., Murafa A.V., Fakhrutdinova V.Kh., Khakimullin Yu.N., Khozin V.G. The peculiarities of bitumens and polymers interaction investigation. Izvestiya KGASU. 2011. No. 1 (15), pp. 140–146. (In Russian).
19. Rusanova S.N., Stoyanov O.V., Remizov A.B., Yanaeva A.O., Gerasimov V.K., Chalykh A.E. The IR spectroscopic study of the ethylene copolymers silanol modification. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2010. No. 9, pp. 346–352. (In Russian).
20. Rusanova S.N., Stoyanov O.V., Remizov A.B., Yanaeva A.O., Gerasimov V.K., Chalykh A.E. The IR spectroscopic study of the ethylsilicate and ethylene with acrylates copolymers interaction. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2010. No. 9, pp. 318–328. (In Russian).
21. Rusanova S.N., Temnikova N.E., Mukhamedzyanova E.R., Stoyanov O.V. The modification of ethylene and aminotrialkoxysilane copolymers. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2010. No. 9, pp. 353–355. (In Russian).
22. Tusar M., Avsenik L. Increasing the rate of recycled asphalt: an experimental study. Transport Problems. 2014. Vol. 9. No. 3, pp. 31–42.
23. Sheina T.V. Samokhina A.A. Interrelation of the fractional composition, supramolecular structure and operational parameters of road bitumen. Part II. Gradostroitel’stvo i Arkhitektura. 2015. No. 4 (21), pp. 108–114. (In Russian).
For citation: Hakimullin Yu.N., Ayupov D.A., Sundukov V.I., Kazakulov R.I., Gizatullin B.I. Non-stratified three-component polymeric-bitumen binders. Stroitel’nye Materialy [Construction Materials]. 2017. No. 10, pp. 51–55. DOI: https://doi.org/10.31659/0585-430X-2017-753-10-51-55. (In Russian).