AbstractAbout AuthorsReferences
The article studies regularities of the structure changes in the process of modification of network (epoxy) and linear (polyvinylchloride) polymers and composites based on them by sin- gle-wall carbon nanotubes in the field of concentration up to 0.01%. For epoxy polymers the impact of tubes on the conversion degree of epoxy groups and on character of fast fracture is defined. For polyvinylchloride in concentration up to 0.001% it was found out the increase in strength properties with the rise of melt fluidity. Microstructure of epoxy polymer block sample cleavages studied my means of scanning electron microscope. Microstructure of 100 nm film PVC sample cross section is studied by transmission electron microscopy method. Localization of nanotubes in interstructural defect zones of polymers is also presented in the article
V.G. KHOZIN, Doctor of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
R.K. NIZAMOV, Doctor of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.), Rector,
L.A. ABDRAKHMANOVA, Doctor of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
R.K. NIZAMOV, Doctor of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.), Rector,
L.A. ABDRAKHMANOVA, Doctor of Science (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
Kazan State University of Architecture and Engineering (1, Zelenaya Street, Kazan, 420043, Russian Federation)
1. Irzhak V.I. Epoxy composite materials with carbon nanotubes. Uspekhi khimii. 2011. No. 80 (8), pp. 821–840. (In Russian).
2. Khozin V.G., Starovoitova I.A., Maisuradze N.V., Zykova E.S., Khalikova R.A., Korzhenko A.A., Trineeva V.V., Yakovlev G.I. Nanomodification of polymer binders for constructional composites. Stroitel’nye Materialy [Construction Materials]. 2013. No. 2, pp. 4–10. (In Russian).
3. Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov R.K., Khozin V.G. Research of PVC compound with carbon nanotubes. Nanotekhnologii v stroitel’stve: scientific Internet-journal. 2011. No. 3, pp. 13–24. http://www. nanobuild.ru (data of access 16.12.2017). (In Russian).
4. Starovoitova I.A., Khozin V.G., Korzhenko A.A., Khalikova R.A., Zykova E.S. Structure formation in organic-inorganic multiwall carbon nanotubes modified binders. Stroitel’nye Materialy [Construction Materials]. 2014. No. 1–2, pp. 12–20.
5. Khozin V.G., Abdrakhmanova L.A., Nizamov R.K. Common concentration pattern of effects of construction materials nanomodification. Stroitel’nye Materialy [Construction Materials]. 2015. No. 2, pp. 25–33.
6. Burnashev A.I., Abdrakhmanova L.A., Nizamov R.K., Khozin V.G., Kolesnikova I.V., Fakhrutdinova V.Kh. Nanomodified flour wood – effective aggregate for PVC composites. Stroitel’nye Materialy [Construction Materials]. 2011. No. 9, pp. 72–74. (In Russian).
7. Burnashev A.I., Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov R.K. Application of wood-polymer nanomodified PVC in compositions. Izvestiya KGASU. 2013. No. 2 (24), pp. 226–232. (In Russian).
8. Burnashev A.I., Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov R.K. Structure and properties of a modified wood-polymeric composite on the basis of polyvinylchloride. Stroitel’nye Materialy [Construction Materials]. 2014. No. 3, pp. 104–106. (In Russian).
9. Abdrahmanova L.A., Burnashev A.I., Nizamov R.K., Khozin V.G. Nanomodifified wood-polymer composites on the basis of polyvinylchloride. The III International Conference NTC-2011 «Nano-technology for eco-friendly and durable construction. Cairo. 2011, pp. 23–27.
10. Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov, R.K., Khozin V.G. Development of effective ways of introducing nanomodifiers to PVC composites. Materials of RAACS XV workshop. Kazan: KGASU. 2010. Vol. 1, pp. 272–278. (In Russian).
11. Abdrakhmanova L.A., Ashrapov A.Kh., Nizamov R.K., Khozin V.G. Modification of PVC by carbon nanotubes. Materials of XIX All-Russia conference “Structure and Dynamics of Molecular Systems”. Moscow: The Institute of Physical Chemistry and Electrochemistry RAS (IPCE RAS). 2012. р. 3. (In Russian).
12. Badamshina E.R., Gafurova M.P., Estrin Ya.I. Modification of carbon nanotubes and synthesis of polymeric composites involving the nanotubes. Uspekhi khimii. 2010. No. 79 (11), pp. 1027–1063. (In Russian).
13. Badamshina E. R., Estrin Ya. I. Nanomodification of epoxy oligomers: literature review and results of our tests. Abstracts of V international conference on chemistry and physic-chemistry of oligomers. Volgograd: VSTU. 2015. р. 8. (In Russian).
14. Wang C., Guo Z.-X., Fu S., Wu W., Zhu D. Polymers containing fullerene or carbon nanotube structures. Progress in Polymer Science. 2004. Vol. 29, pp. 1079–1141.
15. Wagner H.D. Stress-induced fragmentation of multiwall carbon nanotubes in a polymer matrix. Applied Physics Letters. 1998. Vol. 72, p. 188.
16. Zimin D.E., Tatarintseva O.S., Kychkin A.K. Nanomodification of epoxy binders to get basalt fiber reinforced polymer with better performance. Polzunovskii vestnik. 2013. No. 3, pp. 282–285 (In Russian).
17. Patent RF 500706. Sposob dispergirovaniya nanochastits v epoksidnoi smole [Ways of dispergating of nano-particles in epoxy resin]. Vermel V.D., Dotsenko A.M., Titov S.A. Declared 17.04.2012. Published 10.12.2013. Bulletin No. 34. (In Russian).
18. Khozin V.G. Usilenie epoksidnykh polimerov [Strengthening epoxy polymers]. Kazan: Dom Pechati. 2004. 446 p.
2. Khozin V.G., Starovoitova I.A., Maisuradze N.V., Zykova E.S., Khalikova R.A., Korzhenko A.A., Trineeva V.V., Yakovlev G.I. Nanomodification of polymer binders for constructional composites. Stroitel’nye Materialy [Construction Materials]. 2013. No. 2, pp. 4–10. (In Russian).
3. Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov R.K., Khozin V.G. Research of PVC compound with carbon nanotubes. Nanotekhnologii v stroitel’stve: scientific Internet-journal. 2011. No. 3, pp. 13–24. http://www. nanobuild.ru (data of access 16.12.2017). (In Russian).
4. Starovoitova I.A., Khozin V.G., Korzhenko A.A., Khalikova R.A., Zykova E.S. Structure formation in organic-inorganic multiwall carbon nanotubes modified binders. Stroitel’nye Materialy [Construction Materials]. 2014. No. 1–2, pp. 12–20.
5. Khozin V.G., Abdrakhmanova L.A., Nizamov R.K. Common concentration pattern of effects of construction materials nanomodification. Stroitel’nye Materialy [Construction Materials]. 2015. No. 2, pp. 25–33.
6. Burnashev A.I., Abdrakhmanova L.A., Nizamov R.K., Khozin V.G., Kolesnikova I.V., Fakhrutdinova V.Kh. Nanomodified flour wood – effective aggregate for PVC composites. Stroitel’nye Materialy [Construction Materials]. 2011. No. 9, pp. 72–74. (In Russian).
7. Burnashev A.I., Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov R.K. Application of wood-polymer nanomodified PVC in compositions. Izvestiya KGASU. 2013. No. 2 (24), pp. 226–232. (In Russian).
8. Burnashev A.I., Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov R.K. Structure and properties of a modified wood-polymeric composite on the basis of polyvinylchloride. Stroitel’nye Materialy [Construction Materials]. 2014. No. 3, pp. 104–106. (In Russian).
9. Abdrahmanova L.A., Burnashev A.I., Nizamov R.K., Khozin V.G. Nanomodifified wood-polymer composites on the basis of polyvinylchloride. The III International Conference NTC-2011 «Nano-technology for eco-friendly and durable construction. Cairo. 2011, pp. 23–27.
10. Ashrapov A.Kh., Abdrakhmanova L.A., Nizamov, R.K., Khozin V.G. Development of effective ways of introducing nanomodifiers to PVC composites. Materials of RAACS XV workshop. Kazan: KGASU. 2010. Vol. 1, pp. 272–278. (In Russian).
11. Abdrakhmanova L.A., Ashrapov A.Kh., Nizamov R.K., Khozin V.G. Modification of PVC by carbon nanotubes. Materials of XIX All-Russia conference “Structure and Dynamics of Molecular Systems”. Moscow: The Institute of Physical Chemistry and Electrochemistry RAS (IPCE RAS). 2012. р. 3. (In Russian).
12. Badamshina E.R., Gafurova M.P., Estrin Ya.I. Modification of carbon nanotubes and synthesis of polymeric composites involving the nanotubes. Uspekhi khimii. 2010. No. 79 (11), pp. 1027–1063. (In Russian).
13. Badamshina E. R., Estrin Ya. I. Nanomodification of epoxy oligomers: literature review and results of our tests. Abstracts of V international conference on chemistry and physic-chemistry of oligomers. Volgograd: VSTU. 2015. р. 8. (In Russian).
14. Wang C., Guo Z.-X., Fu S., Wu W., Zhu D. Polymers containing fullerene or carbon nanotube structures. Progress in Polymer Science. 2004. Vol. 29, pp. 1079–1141.
15. Wagner H.D. Stress-induced fragmentation of multiwall carbon nanotubes in a polymer matrix. Applied Physics Letters. 1998. Vol. 72, p. 188.
16. Zimin D.E., Tatarintseva O.S., Kychkin A.K. Nanomodification of epoxy binders to get basalt fiber reinforced polymer with better performance. Polzunovskii vestnik. 2013. No. 3, pp. 282–285 (In Russian).
17. Patent RF 500706. Sposob dispergirovaniya nanochastits v epoksidnoi smole [Ways of dispergating of nano-particles in epoxy resin]. Vermel V.D., Dotsenko A.M., Titov S.A. Declared 17.04.2012. Published 10.12.2013. Bulletin No. 34. (In Russian).
18. Khozin V.G. Usilenie epoksidnykh polimerov [Strengthening epoxy polymers]. Kazan: Dom Pechati. 2004. 446 p.
For citation: Strokova V.V., Netsvet D.D., Nelubova V.V., Serenkov I.V. Properties of composite binder based on nanostructured suspension. Stroitel’nye Materialy [Construction materi- als]. 2017. No. 1–2, pp. 50–54. DOI: https://doi.org/10.31659/0585-430X-2017-745-1-2-55-61. (In Russian).