Features of Chemical Composition of Subsidence Products of Sodium Hydrosilicates

Number of journal: №11-2016
Autors:

A.N. GRISHINA
E.V. KOROLEV

DOI: https://doi.org/10.31659/0585-430X-2016-743-11-37-40
УДК: 666.972.16: 54.666.9.015.424

 

AbstractAbout AuthorsReferences
Data on the analysis of crystalline products of the subsidence of sodium hydrosilicate solutions with the solutions of salts of various metals are presented. Features of the chemical composition of subsidence crystalline products are shown: when using the salts of alkali-earth metals, the formation of a metal carbonate is observed that’s why in the course of the synthesis of hydrosilicates of alkali metals, it is reasonable to avoid the intensive agitation of the mix and air-entrainment ; when using amphoteric metals, the carbonization is not observed and the chemical composition of products is determined by the type of the metal used. The pH value of the synthesis medium when using amphoteric metals don’t influence on the degree of crystalliness of hydrosilicates obtained, but crystalline products with different content of combination water are formed. Conducting the synthesis at acid values of pH makes it possible to obtain a large amount of the product and synthesize the substance not containing sodium.
A.N. GRISHINA, Candidate of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.),
E.V. KOROLEV, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)

National Research Moscow State University of Civil Engineering (26, Yaroslavskoe Highway, Moscow, 129337, Russian Federation)

1. Usherov-Marshak A.V. Modern concrete and its technologies. Beton i zhelezobeton. 2009. No. 2, pp. 20–25. (In Russian).
2. Arkhipov V.P., Vernigorova V.N., Gakshteter G.V., Gorshkova L.V., Elesin M.A., Ermakov D.A. and all. Effektivnye vysokoprochnye i obychnye betony [Effective high-strength and usual concrete] / Edited by V.I. Kalashnikov. Penza: Privolzhskii Dom znanii. 2015. 148 p.
3. Rakhimov R.Z. Ways of decrease in amount of cement in construction products. Populyarnoe betonovedenie. 2008. No. 7 (21), pp. 24–28. (In Russian).
4. Bazhenov Yu.M., Alimov L.A., Voronin V.V. Ctruktura i svoistva betonov s nanomodifikatorami na osnove tekhnogennykh otkhodov [Structure and properties of concrete with nanomodifiers on the basis of technogenic waste]. Moscow: MGSU. 2013. 204 p.
5. Lesovik V.S., Zagorodnyuk L.Kh., Shakhova L.D. Tekhnogennye produkty v proizvodstve sukhikh stroitel’nykh smesei [Technological products in production of dry construction mixes]. Belgorod: BGTU. 2010. 168 p.
6. Satyukov A. B. The nanomodified composite astringent for special construction solutions. Cand. Diss. (Engineering). Moscow. 2015. 228 p. (In Russian).
7. Loganina V.I., Makarova L.V., Sergeeva K.A. Use of additive on the basis of calcium hydrosilicates in dry construction mixes. Sukhie stroitel’nye smesi. 2012. No. 1, pp. 16–17. (In Russian).
8. Loganina V.I., Kislitsyna S.N., Zhernovskiy I.V., Sadovnikova M.A. Structure and properties of synthesised alumosilicates. Stroitel’nye Materialy [Construction Materials]. 2014. No. 4, pp. 87–89.
9. Gordienko P.S., Yarusova C.B., Suponina A.P., Krysenko G.F., Bulanova S.B., Kolzunov V.A., Barinov N.N. Hydrochemical synthesis of hydrosilicates of calcium in the systems CaCl2–Na2SiO3–H2O, CaSO4•2H2O– Na2SiO3–H2O, CaSO4•2H2O–SiO2–H2O–KOH. Structure, structure, properties. Vestnik DVO RAN. 2009. No. 2, pp. 30–33. (In Russian).
10. Loganina V.I., Pyshkina I.S. Limy composite binder with use of the synthesized calcium hydrosilicates. Bestnik BGTU im. V.G. Shukhova. 2014. No. 6, pp. 29–32. (In Russian).
11. Sadovnikova M.A., Zhegera K.V. Use of synthetic zeolites as the modifying additive in a compounding of cement and limy dry construction mixes. Regional’naya arkhitektura i stroitel’stvo. 2016. No. 1, pp. 68–73. (In Russian).
12. Loganina V.I., Kislitsyna S.N., Makarova L.V., Sadovnikova M.A. Rheological properties limy composite with use of synthetic zeolites. Izvestiya VUZov. Stroitel’stvo. 2013. No. 4, pp. 37–42. (In Russian).
13. Ilyasov A.G., Medvedeva I.N., Korneev V.I. Hydration of a cement in the presence of additive of amorphous hydroxide of aluminum. Zhurnal prikladnoi khimii. 2006. Vol. 79. No. 2, pp. 347–348. (In Russian).

For citation: 


Print   Email